N-phenylaminopyrazole derivatives as well as composition and process for the dyeing of hair

Claim 2

N-phenylaminopyrazole compound of the formula (I) ##STR5## wherein R 1 is a substituent group selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms and hydroxyalkyl groups having from two to four carbon atoms; R 2 and R 3 are each a substituent group independently selected from the group consisting of hydrogen, amino groups and alkyl groups having from one to four carbon atoms; and R 4 is a substituent group selected from the group consisting of hydrogen, alxyl groups having from one to four carbon atoms, alkoxy groups having from one to four carbon atoms and halogen; with the proviso that, if said R 1 is a member of the group consisting of hydrogen and alkyl groups having from one to four carbon atoms, at least one of said R 2 and R 3 is one of said amino groups.

Claim 3

N-phenylaminopyrazole compound as defined in claim 1 and consisting of 5-amino-4-(2',4'-diaminophenylamino)-1-methylpyrazole.

Claim 4

N-phenylaminopyrazole compound as defined in claim 1 and consisting of 4-amino-5-(2',4'-diaminophenylamino)-1-methylpyrazole.

Claim 5

N-phenylaminopyrazole compound as defined in claim 1 and consisting of 3-amino-4-(2',4'-diaminophenyylamino)-1-methylpyrazole.

Claim 6

Hair dye composition comprising at least one N-phenylaminopyrazole compound of the formula (I) ##STR6## wherein R 1 is a substituent member selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, hydroxyalkyl groups having from two to four carbon atoms; R 2 and R 3 are each a substituent group independently selected from the group consisting of hydrogen, amino groups and alkyl groups having from one to four carbon atoms; and R 4 is a substituent group selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, alkoxy groups having from one to four carbon atoms and halogen, with the proviso that, if said R 1 member of the group consisting of hydrogen and alkyl groups having from one to four carbon atoms, at least one of said R 2 and R 3 is one of said amino groups; and at least one conventional ingredient for hair dye compositions selected from the group consisting of emollients; preservatives; perfume oils; solvents; anionic, cationic, amphoteric and nonionic surfactants; thickeners; starch derivatives; cellulose derivatives; petrolatum; paraffin oil; fatty acids; conditioners; lanolin derivatives; cholesterol; pantothenic acid and betaines.

Claim 7

Hair dye composition comprising at least one N-phenylaminopyrazole compound of the formula (I) ##STR6## wherein R 1 is a substituent member selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, hydroxyalkyl groups having from two to four carbon atoms; R 2 and R 3 are each a substituent group independently selected from the group consisting of hydrogen, amino groups and alkyl groups having from one to four carbon atoms; and R 4 is a substituent group selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, alkoxy groups having from one to four carbon atoms and halogen, with the proviso that, if said R 1 member of the group consisting of hydrogen and alkyl groups having from one to four carbon atoms, at least one of said R 2 and R 3 is one of said amino groups; and at least one conventional ingredient for hair dye compositions selected from the group consisting of emollients; preservatives; perfume oils; solvents; anionic, cationic, amphoteric and nonionic surfactants; thickeners; starch derivatives; cellulose derivatives; petrolatum; paraffin oil; fatty acids; conditioners; lanolin derivatives; cholesterol; pantothenic acid and betaines.

Claim 8

Hair dye composition as defined in claim 5 and containing 0,001 to 2 percent by weight of said at least one N-phenylaminopyrazole compound of the formula (V).

Claim 9

Hair dye composition as defined in claim 5 and having a pH of from 4 to 11.

Claim 10

Hair dye composition as defined in claim 5 in the form of an aqueous or aqueous-alcoholic solution, an emulsion, a cream or a gel.

Claim 11

Hair dye composition as defined in claim 5, further comprising at least one oxidation hair dye.

Claim 12

Hair dye composition as defined in claim 5, further comprising at least one direct dye for direct absorption on hair to be dyed.

Claim 13

Process for dyeing hair comprising the steps of: a) providing a hair dye composition comprising at least one N-phenylaminopyrazole compound of the formula (v) ##STR7## wherein R 1 is a substituent member selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, hydroxyalkyl groups having from two to four carbon atoms; R 2 and R 3 are each a substituent group independently selected from the group consisting of hydrogen, amino groups and alkyl groups having from one to four carbon atoms; and R 4 is a substituent group selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, alkoxy groups having from one to four carbon atoms and halogen; and at least one conventional ingredient for hair dye compositions selected from the group consisting of emollients; preservatives; perfume oils; solvents; anionic, cationic, amphoteric and nonionic surfactants; thickeners; starch derivatives; cellulose derivatives; petrolatum; paraffin oil; fatty acids; conditioners; lanolin derivatives; cholesterol; pantothenic acid and betaines; b) applying an amount of said hair dye composition to the hair; c) allowing said hair dye composition to act on the hair for from 10 to 30 minutes, and d) subsequent to step c), rinsing said hair dye composition from the hair and drying the hair.

Claim 14

Process for dyeing hair comprising the steps of: a) providing a hair dye composition comprising at least one N-phenylaminopyrazole compound of the formula (v) ##STR7## wherein R 1 is a substituent member selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, hydroxyalkyl groups having from two to four carbon atoms; R 2 and R 3 are each a substituent group independently selected from the group consisting of hydrogen, amino groups and alkyl groups having from one to four carbon atoms; and R 4 is a substituent group selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, alkoxy groups having from one to four carbon atoms and halogen; and at least one conventional ingredient for hair dye compositions selected from the group consisting of emollients; preservatives; perfume oils; solvents; anionic, cationic, amphoteric and nonionic surfactants; thickeners; starch derivatives; cellulose derivatives; petrolatum; paraffin oil; fatty acids; conditioners; lanolin derivatives; cholesterol; pantothenic acid and betaines; b) applying an amount of said hair dye composition to the hair; c) allowing said hair dye composition to act on the hair for from 10 to 30 minutes, and d) subsequent to step c), rinsing said hair dye composition from the hair and drying the hair.

Claim 15

Process for dyeing hair comprising the steps of: a) providing a hair dye composition comprising at least one N-phenylaminopyrazole compound of the formula (V) ##STR8## wherein R 1 is a substituent member selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, hydroxyalkyl groups having from two to four carbon atoms; R 2 and R 3 are each a substituent group independently selected from the group consisting of hydrogen, amino groups and alkyl groups having from one to four carbon atoms; and R 4 is a substituent group selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, alkoxy groups having from one to four carbon atoms and halogen; and at least one conventional ingredient for hair dye compositions selected from the group consisting of emollients; preservatives; perfume oils; solvents; anionic, cationic, amphoteric and nonionic surfactants; thickeners; starch derivatives; cellulose derivatives; petrolatom; paraffin oil; fatty acids; conditioners; 1anolin derivatives; cholesterol; pantothenic acid and betainca; b) prior to applying to hair, mixing an oxidizing agent with an amount of said hair dye composition to form a hair dyeing mixture; c) applying said hair dye mixture to the hair; d) allowing said hair dye mixture to act on the hair for from 10 to 30 minutes, e) subsequent to step d), rinsing said hair dye composition from the hair and drying the hair.

Claim 16

Process for dyeing hair comprising the steps of: a) providing a hair dye composition comprising at least one N-phenylaminopyrazole compound of the formula (V) ##STR8## wherein R 1 is a substituent member selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, hydroxyalkyl groups having from two to four carbon atoms; R 2 and R 3 are each a substituent group independently selected from the group consisting of hydrogen, amino groups and alkyl groups having from one to four carbon atoms; and R 4 is a substituent group selected from the group consisting of hydrogen, alkyl groups having from one to four carbon atoms, alkoxy groups having from one to four carbon atoms and halogen; and at least one conventional ingredient for hair dye compositions selected from the group consisting of emollients; preservatives; perfume oils; solvents; anionic, cationic, amphoteric and nonionic surfactants; thickeners; starch derivatives; cellulose derivatives; petrolatom; paraffin oil; fatty acids; conditioners; 1anolin derivatives; cholesterol; pantothenic acid and betainca; b) prior to applying to hair, mixing an oxidizing agent with an amount of said hair dye composition to form a hair dyeing mixture; c) applying said hair dye mixture to the hair; d) allowing said hair dye mixture to act on the hair for from 10 to 30 minutes, e) subsequent to step d), rinsing said hair dye composition from the hair and drying the hair.