US5416147A
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Hydrosilylative composition and process of hydrosilylation reaction
Assignee: Shin-Etsu Chemical Co Ltd
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Filing: 1993-12-14
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Granted: 1995-05-16
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Expires: 2013-12-14
Abstract
Abstract A blend of (A) an acrylic, polyester or epoxy resin having at least two alkenyl or alkynyl groups in a molecule, (B) an organic silicon compound having at least two hydrogen atoms each directly attached to a silicon atom in a molecule, and (C) a hydrosilylaion catalyst is blended with (D) an organic iron or aluminum compound to form a hydrosilylative composition. Component (D) scavenges a catalyst poison, permitting components (A) and (B) to undergo hydrosilylation reaction with the aid of catalyst (C).
Inventors
- 👤 Mitsuhiro Takarada
- 👤 Yuji Yoshikawa
- 👤 Hiroharu Ohsugi
- 👤 Yoshio Eguchi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 09:24
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/06; C08K; C08K5/00; C08K5/0008; C08K5/0025; C08L101/00; C08L63/00; C08L83/00; C08L83/10
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
62 words
A hydrosilylative composition comprising (A) an acrylic, polyester or epoxy resin having at least two alkenyl or alkynyl groups in a molecule, (B) an organic silicon compound having at least two hydrogen atoms each directly attached to a silicon atom in a molecule, (C) a hydrosilylation catalyst, and (D) at least one of an organic iron compound or an organic aluminum compound.
Claim 2
Dependent Claim
62 words
A hydrosilylative composition comprising (A) an acrylic, polyester or epoxy resin having at least two alkenyl or alkynyl groups in a molecule, (B) an organic silicon compound having at least two hydrogen atoms each directly attached to a silicon atom in a molecule, (C) a hydrosilylation catalyst, and (D) at least one of an organic iron compound or an organic aluminum compound.
Claim 3
Dependent Claim
13 words
The composition of claim 1, wherein component (D) is an organic iron compound.
Claim 4
Dependent Claim
21 words
The composition of claim 2, wherein the organic iron compound is ferric octylate, ferric acetate, ferric propionate, ferric naphthenate or acetylacetanato-iron.
Claim 5
Dependent Claim
13 words
The composition of claim 1, wherein component (D) is an organic aluminum compound.
Claim 6
Dependent Claim
17 words
The composition of claim 4, wherein the organic aluminum compound is an aluminum alkoxide or aluminum chelate.
Claim 7
Dependent Claim
21 words
The composition of claim 1, wherein the acrylic, polyester or epoxy resin has a molecular weight of about 500 to 100,000.
Claim 8
Dependent Claim
13 words
The composition of claim 1, wherein component (B) is an organohydrogensilane or organohydrogensiloxane.
Claim 9
Dependent Claim
45 words
The composition of claim 1, wherein components (A) and (B) are provided in amounts such that the molar ratio of the alkenyl or alkynyl groups in component (A) to the hydrogen atoms attached to a silicon atom in component (B) is from 1:0.5 to 1:50.
Claim 10
Dependent Claim
29 words
The composition of claim 1, wherein the hydrosilylation catalyst (C) is a complex or compound containing a metal selected from the group consisting of platinum, palladium, rhodium and ruthenium.
Claim 11
Dependent Claim
24 words
The composition of claim 9, wherein the amount of component (D) is 10 to 10,000 times the weight of the metal in component (C).
Claim 12
Dependent Claim
81 words
A hydrosilylation reaction process comprising the steps of: subjecting (A) an acrylic, polyester or epoxy resin having at least two alkenyl or alkynyl groups in a molecule and (B) an organic silicon compound having at least two hydrogen atoms each directly attached to a silicon atom in a molecule to a hydrosilylation reaction in the presence of (C) a hydrosilylation catalyst, and adding (D) at least one of an organic iron compound or an organic aluminum compound to the reaction system.
Claim 13
Dependent Claim
81 words
A hydrosilylation reaction process comprising the steps of: subjecting (A) an acrylic, polyester or epoxy resin having at least two alkenyl or alkynyl groups in a molecule and (B) an organic silicon compound having at least two hydrogen atoms each directly attached to a silicon atom in a molecule to a hydrosilylation reaction in the presence of (C) a hydrosilylation catalyst, and adding (D) at least one of an organic iron compound or an organic aluminum compound to the reaction system.
Claim 14
Dependent Claim
45 words
The process of claim 11 wherein the hydrosilylation reaction is effected in a system containing an element selected from the group consisting of N, P, S, Sn and As or in a system in contact with a material containing at least one of said elements.
Claim 15
Dependent Claim
13 words
The process of claim 11, wherein component (D) is an organic iron compound.
Claim 16
Dependent Claim
21 words
The process of claim 13, wherein the organic iron compound is ferric octylate, ferric acetate, ferric propionate, ferric naphthenate or acetylacetanato-iron.
Claim 17
Dependent Claim
13 words
The process of claim 11, wherein component (D) is an organic aluminum compound.
Claim 18
Dependent Claim
17 words
The process of claim 15, wherein the organic aluminum compound is an aluminum alkoxide or aluminum chelate.
References Cited (Backward Citations)
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