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US5409766A Expired / Lapsed US ⏱️ 0.0 years remaining

Nonwoven fabric in an electret state and process for its production

Assignee: Mitsui Chemicals Inc
•
Filing: 1993-10-18
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Granted: 1995-04-25
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Expires: 2013-10-18
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Abstract

Abstract The improved nonwoven fabric in an electret state is composed of monofilaments with an average fiber diameter of 0.5-100 μm that are formed of a polymer composition containing no more than 1 mol % of polar groups; the fabric has a weight of 5-100 g/m 2 , a bulk density of 0.05-0.40 g/cm 3 and an average surface charge density of at least 0.1×10 -9 C/cm 2 . This nonwoven fabric is capable of efficient dust collection and its trapping ability is retained for a prolonged time even in a hot and humid condition. Also disclosed are a process for producing this nonwoven fabric, as well as a filtering and an air masking material which are composed of that nonwoven fabric.

Inventors

  • 👤 Haruo Yuasa
  • 👤 Masayuki Mito
  • 👤 Yukihiro Takata
  • 👤 Satoshi Matsuura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 03:38
CPC Classifications
D; D01; D01F; D01F6/00; D01F6/44; D01F6/46; D04; D04H; D04H1/00; D04H1/40; D04H1/42; B; B01; B01D; B01D39/00; B01D39/14; B01D39/16; B01D39/1607; B01D39/1623; D01D; D01D10/00; D01D5/00; D01D5/08; D01D5/098; D01D5/0985; D01F6/28; D01F6/30; D04H1/4282; D04H1/4291; D04H1/54; D04H1/56; D04H3/00; D04H3/005; D04H3/007; D04H3/08; D04H3/16; Y; Y10; Y10S; Y10S428/00; Y10S428/903; Y10S55/00; Y10S55/39; Y10T; Y10T442/00; Y10T442/60; Y10T442/637; Y10T442/68

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 70 words
A nonwoven fabric in an electret state that is composed of monofilaments of a polymer composition that contains no more than 1 mol % of polar groups, said monofilaments having an average fiber diameter of 0.5-100 μm and said nonwoven fabric having a weight of 5-100 g/m 2 , a bulk density of 0.05-0.40 g/cm 3 and an average surface charge density of at least 0.1×10 -9 C/cm 2 .
Claim 2
Dependent Claim 70 words
A nonwoven fabric in an electret state that is composed of monofilaments of a polymer composition that contains no more than 1 mol % of polar groups, said monofilaments having an average fiber diameter of 0.5-100 μm and said nonwoven fabric having a weight of 5-100 g/m 2 , a bulk density of 0.05-0.40 g/cm 3 and an average surface charge density of at least 0.1×10 -9 C/cm 2 .
Claim 3
Dependent Claim 26 words
A nonwoven fabric in an electret state according to claim 1 wherein a content of said polar groups in said polymer composition is 0.03-0.1 mol %.
Claim 4
Dependent Claim 23 words
A nonwoven fabric in an electret state according to claim 1 wherein said polymer composition has an intrinsic viscosity [η] of 0.3-1.5 dl/g.
Claim 5
Dependent Claim 107 words
A nonwoven fabric in an electret state according to claim 1 wherein said polymer composition is at least one member selected from the group consisting of: (A) a copolymer consisting of a monomer having polar groups and a nonpolar monomer; (B) a polymer having polar groups introduced into side chains or the backbone chain of a nonpolar polymer by means of oxidation or halogenation; (C) a graft modified polymer having a polar group containing monomer graft copolymerized onto a nonpolar polymer or said polymer (B); and (D) a mixture of a nonpolar polymer and at least one member selected from among said polymers (A), (B) and (C).
Claim 6
Dependent Claim 38 words
A nonwoven fabric in an electret state according to claim 4 wherein said polar groups are halogen atoms, carbonyl groups, nitro groups and at least one member selected from among the groups represented by the following formulae: ##STR2##
Claim 7
Dependent Claim 26 words
A nonwoven fabric in an electret state according to claim 4 wherein said polymer composition contains both a polar group containing polymer and a nonpolar polymer.
Claim 8
Dependent Claim 30 words
A nonwoven fabric in an electret state according to claim 6 wherein said polar group containing polymer contains polar groups in an amount of no more than 3 mol %.
Claim 9
Dependent Claim 38 words
A nonwoven fabric in an electret state according to claim 1 wherein said polymer composition is a polyolefin that has been modified with at least one modifying monomer as selected from among unsaturated carboxylic acids and derivatives thereof.
Claim 10
Dependent Claim 29 words
A nonwoven fabric in an electret state according to claim 8 wherein said polymer composition contains said modifying monomer in an amount of no more than 1 mol %.
Claim 11
Dependent Claim 19 words
A nonwoven fabric in an electret state according to claim 8 wherein said modified polyolefin is a modified polypropylene.
Claim 12
Dependent Claim 53 words
A nonwoven fabric in an electret state according to claim 8 wherein said modified polyolefin contains 98-40 wt % of polypropylene (a) and 2-60 wt % of an ethylene-α-olefin copolymer (b) having a crystallinity of less than 40% as measured with X-rays, with the sum of (a) and (b) being 100 wt %.
Claim 13
Dependent Claim 45 words
A nonwoven fabric in an electret state according to claim 1 wherein said polymer composition contains not only a polyolefin that has been modified with at least one modifying monomer as selected from among unsaturated carboxylic acids and derivatives thereof but also an unmodified polyolefin.
Claim 14
Dependent Claim 17 words
A nonwoven fabric in an electret state according to claim 12 wherein said unmodified polyolefin is polypropylene.
Claim 15
Dependent Claim 53 words
A nonwoven fabric in an electret state according to claim 12 wherein said unmodified polyolefin contains 98-40 wt % of polypropylene (a) and 2-60 wt % of an ethylene-α-olefin copolymer (b) having a crystallinity of less than 40% as measured with X-rays, with the sum of (a) and (b) being 100 wt %.
Claim 16
Dependent Claim 51 words
A process for producing a nonwoven fabric in an electret state, which comprises the steps of forming a polymer composition containing no more than 1 mol % of polar groups into a nonwoven fabric by a melt-blow method and then applying a DC voltage to the nonwoven fabric to create electrets.
Claim 17
Dependent Claim 51 words
A process for producing a nonwoven fabric in an electret state, which comprises the steps of forming a polymer composition containing no more than 1 mol % of polar groups into a nonwoven fabric by a melt-blow method and then applying a DC voltage to the nonwoven fabric to create electrets.
Claim 18
Dependent Claim 32 words
A process according to claim 15 wherein said polymer composition is a polyolefin that has modified with at least one modifying monomer as selected from among unsaturated carboxylic acids and derivatives thereof.
Claim 19
Dependent Claim 40 words
A process according to claim 15 wherein said polymer composition contains not only a polyolefin that has been modified with at least one modifying monomer as selected from among unsaturated carboxylic acids and derivatives thereof but also an unmodified polyolefin.
Claim 20
Dependent Claim 19 words
A filtering material that is composed of a nonwoven fabric in an electret state as recited in claim 1.
Claim 21
Dependent Claim 20 words
An air masking material that is composed of the nonwoven fabric in an electret state as recited in claim 1.

References Cited (Backward Citations)

JPS5923098A Cited
US4592815A Cited
US4626263A Cited
EP0246811A2 Cited
US4917942A Cited
JPH02197110A Cited
US5206061A Cited
EP0512764A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-04-24 1998-10-24 1999-04-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-04-24 2002-10-24 2003-04-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-04-24 2006-10-24 2007-04-25 $7700.00 Window Closed / Lapsed

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