US5399293A
Expired / Lapsed
US
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Emulsion formation system and mixing device
Assignee: Petróleos de Venezuela SA
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Filing: 1992-11-19
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Granted: 1995-03-21
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Expires: 2012-11-19
Abstract
Abstract A method for preparing oil in water HIPR emulsions includes the steps of providing a Newtonian liquid including a mixture of a viscous hydrocarbon, an emulsifying additive and water; subjecting the Newtonian liquid to a first shear force whereby a substantial portion of the Newtonian liquid is radially displaced and mixed so as to form a non-Newtonian liquid; thereafter subjecting remaining non-radially displaced Newtonian liquid to a second shear force to mix the remaining non-radially displaced Newtonian liquid into the non-Newtonian liquid to form the HIPR emulsion, which emulsion is a stable oil in water emulsion having a droplet size of between about 1 to 30 microns and having a droplet size distribution (x) no greater than about 1, the droplet size distribution being defined as follows: <IMAGE> wherein D90 is a droplet size at least as large as about 90% of all droplets in the oil in water emulsion; D10 is a droplet size at least as large as about 10% of all droplets in the oil in water emulsion; and D50 is a droplet size at least as large as about 50% of all droplets in the oil in water emulsion.
Inventors
- 👤 Gustavo Nunez
- 👤 Roger Marin
- 👤 Maria L. Ventresca
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 05:02
CPC Classifications
B; B01; B01F; B01F23/00; B01F23/40; B01F23/43; B01F27/00; B01F27/50; C; C10; C10L; C10L1/00; C10L1/32; C10L1/328; Y; Y10; Y10S; Y10S516/00; Y10S516/922; Y10S516/923; Y10S516/924; Y10S516/929
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
192 words
A method for forming an oil in water HIPR emulsion, comprising the steps of: forming a Newtonian liquid comprising a mixture of a viscous hydrocarbon, an emulsifying additive and water; subjecting said Newtonian liquid to a first shear force wherein a substantial portion of said Newtonian liquid is radially displaced and mixed so as to form a non-Newtonian liquid; thereafter subjecting remaining non-radially displaced Newtonian liquid to a second shear force to mix said remaining non-radially displaced Newtonian liquid into said non-Newtonian liquid to form said HIPR emulsion comprising a stable oil in water emulsion having a droplet size of between about 1 to 30 microns and having a droplet size distribution (x) no greater than about 1, said droplet size distribution being defined as follows: ##EQU3## wherein D90 is a droplet size wherein about 90% by volume of all droplets in said emulsion are equal to or below; D10 is a droplet size wherein about 10% by volume of all droplets in said emulsion are equal to or below; and D50 is a droplet size wherein about 50% by volume of all droplets in said emulsion are equal to or below.
Claim 2
Independent Claim
192 words
A method for forming an oil in water HIPR emulsion, comprising the steps of: forming a Newtonian liquid comprising a mixture of a viscous hydrocarbon, an emulsifying additive and water; subjecting said Newtonian liquid to a first shear force wherein a substantial portion of said Newtonian liquid is radially displaced and mixed so as to form a non-Newtonian liquid; thereafter subjecting remaining non-radially displaced Newtonian liquid to a second shear force to mix said remaining non-radially displaced Newtonian liquid into said non-Newtonian liquid to form said HIPR emulsion comprising a stable oil in water emulsion having a droplet size of between about 1 to 30 microns and having a droplet size distribution (x) no greater than about 1, said droplet size distribution being defined as follows: ##EQU3## wherein D90 is a droplet size wherein about 90% by volume of all droplets in said emulsion are equal to or below; D10 is a droplet size wherein about 10% by volume of all droplets in said emulsion are equal to or below; and D50 is a droplet size wherein about 50% by volume of all droplets in said emulsion are equal to or below.
Claim 3
Dependent Claim
34 words
A method according to claim 1, further including the step of subjecting said substantial portion of said Newtonian liquid to said second shear force so as to prevent rigid flow of said substantial portion.
Claim 4
Dependent Claim
52 words
A method according to claim 2, wherein said steps of subjecting to a first shear force and a second shear force are carried out in a cylinder having a volume selected so as to provide a residence time for said Newtonian liquid in said cylinder of between about 1 to 5 minutes.
Claim 5
Dependent Claim
111 words
A method according to claim 3, further including the steps of: selecting a cylinder having an inlet for said Newtonian liquid and an outlet for said HIPR emulsion, and having a length (L) and diameter (D), said first and second shear means each having a diameter (d); positioning said first shear means at a distance from said inlet of about 1/3L; positioning said second shear means at a distance from said first shear means of about 1.5d; providing a ratio of cylinder length to cylinder diameter (L/D) of between about 1.5 to 3.0; and providing a ratio of shear means diameter to cylinder diameter (d/D) of between about 0.35 to 0.45.
Claim 6
Dependent Claim
41 words
A method according to claim 1, wherein said step of forming said Newtonian liquid includes the step of mixing said viscous hydrocarbon and said water at a ratio by volume of viscous hydrocarbon to water of between about 80:20 to 95:5.
Claim 7
Dependent Claim
36 words
A method according to claim 5, wherein said step of forming said Newtonian liquid further includes the step of providing a viscous hydrocarbon having an API gravity of between about 5 to 15 at 60° F.
Claim 8
Dependent Claim
33 words
A method according to claim 6, wherein said step of forming said Newtonian liquid further comprises adding said emulsifying additive to said water at a concentration of no greater than about 3000 ppm.
Claim 9
Dependent Claim
33 words
A method according to claim 7, wherein said step of adding said emulsifying additive further includes the step of selecting said emulsifying additive from a group consisting of cationic, anionic and non-ionic emulsifiers.
Claim 10
Dependent Claim
36 words
A method according to claim 7, wherein said step of adding said emulsifying additive comprises the step of adding a nonylphenol ethoxylate surfactant to said water at a concentration of no greater than about 3000 ppm.
Claim 11
Independent Claim
364 words
An apparatus for forming an oil in water HIPR emulsion from a Newtonian liquid comprising a mixture of a viscous hydrocarbon, an emulsifying additive and water, the apparatus comprising a cylinder defined about a central axis and having an inlet for said Newtonian liquid and an outlet for said HIPR emulsion, a plurality of means for subjecting said Newtonian liquid to shear force positioned serially along a flow path of said Newtonian liquid said plurality of shear means comprising at least a first shear means and a second shear means arranged serially for rotation about said central axis wherein said plurality of shear means being positioned serially within said cylinder along a flow path of said Newtonian liquid, said plurality of shear means each having a diameter (d) and said cylinder having a length (L) and a diameter (D), said first shear means being positioned at a distance from said inlet of about 1/3L, said second shear means being positioned at a distance from said first shear means of about 1.5d, and a ratio of cylinder length to cylinder diameter (L/D) being between about 1.5 to 3.0, and a ratio of shear means diameter to cylinder diameter (d/D) being between about 0.35 and 0.45, so that a substantial portion of said Newtonian liquid is subjected to a first shear force and radially displaced from said first shear means and mixed so as to form a non-Newtonian liquid, and remaining non-radially displaced Newtonian liquid is subjected to a second shear force and mixed into said non-Newtonian liquid to form an HIPR emulsion comprising a stable oil in water emulsion having a droplet size of about 1 to 30 microns and having a droplet size distribution (x) no greater than about 1, said droplet size distribution being defined as follows: ##EQU4## wherein D90 is a droplet size wherein about 90% by volume of all droplets in said emulsion are equal to or below; D10 is a droplet size wherein about 10% by volume of all droplets in said emulsion are equal to or below; and D50 is a droplet size wherein about 50% by volume of all droplets in said emulsion are equal to or below.
Claim 12
Independent Claim
364 words
An apparatus for forming an oil in water HIPR emulsion from a Newtonian liquid comprising a mixture of a viscous hydrocarbon, an emulsifying additive and water, the apparatus comprising a cylinder defined about a central axis and having an inlet for said Newtonian liquid and an outlet for said HIPR emulsion, a plurality of means for subjecting said Newtonian liquid to shear force positioned serially along a flow path of said Newtonian liquid said plurality of shear means comprising at least a first shear means and a second shear means arranged serially for rotation about said central axis wherein said plurality of shear means being positioned serially within said cylinder along a flow path of said Newtonian liquid, said plurality of shear means each having a diameter (d) and said cylinder having a length (L) and a diameter (D), said first shear means being positioned at a distance from said inlet of about 1/3L, said second shear means being positioned at a distance from said first shear means of about 1.5d, and a ratio of cylinder length to cylinder diameter (L/D) being between about 1.5 to 3.0, and a ratio of shear means diameter to cylinder diameter (d/D) being between about 0.35 and 0.45, so that a substantial portion of said Newtonian liquid is subjected to a first shear force and radially displaced from said first shear means and mixed so as to form a non-Newtonian liquid, and remaining non-radially displaced Newtonian liquid is subjected to a second shear force and mixed into said non-Newtonian liquid to form an HIPR emulsion comprising a stable oil in water emulsion having a droplet size of about 1 to 30 microns and having a droplet size distribution (x) no greater than about 1, said droplet size distribution being defined as follows: ##EQU4## wherein D90 is a droplet size wherein about 90% by volume of all droplets in said emulsion are equal to or below; D10 is a droplet size wherein about 10% by volume of all droplets in said emulsion are equal to or below; and D50 is a droplet size wherein about 50% by volume of all droplets in said emulsion are equal to or below.
Claim 13
Dependent Claim
40 words
An apparatus according to claim 10, wherein said cylinder has a volume selected to provide, in conjunction with a flow rate of said mixture, a residence time for said mixture in said cylinder of between about 1 to 5 minutes.
Claim 14
Dependent Claim
27 words
An apparatus according to claim 10, wherein said plurality of shear means comprises a plurality of blades rotatably positioned serially along said flow path of said mixture.
Claim 15
Dependent Claim
23 words
An apparatus according to claim 12, wherein said inlet is positioned substantially concentric with an axis of rotation of said plurality of blades.
Claim 16
Dependent Claim
25 words
An apparatus according to claim 13, wherein said cylinder is positioned substantially vertically and said inlet is disposed in a bottom end of said cylinder.
Claim 17
Dependent Claim
21 words
An apparatus according to claim 10, further comprising means for forming said mixture of a viscous hydrocarbon, emulsifying additive and water.
Claim 18
Dependent Claim
38 words
An apparatus according to claim 15, wherein said means for forming said mixture comprises means for mixing said viscous hydrocarbon and said water at a ratio by volume of hydrocarbon to water of between about 80:20 to 95:5.
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