Abstract Graft copolymers having improved phase binding between the graft base and the grafted-on polymer, are prepared from: a) a grafted-on polymer phase containing one or more monomers from the group consisting of (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinyl halides, styrene and styrene derivatives, and b) a peroxy group-containing copolymer phase containing from 0.01 to 20% by weight of an olefinically unsaturated peroxy compound of the general formula I or II ##STR1## where R 1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R 2 and R 3 are an alkyl group having 1 to 4 carbon atoms, R 4 is an alkyl group or an alkyl-substituted phenyl group having 3 to 12 carbon atoms, and R 5 is a cycloalkyl group having 3 to 12 carbon atoms, and from 80 to 99.9% by weight of one or more comonomers from the group consisting of the (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinylaromatic compounds, vinyl halides and/or vinyl ethers. The graft copolymers are useful as binders in the textile industry as heat stable binders, as adhesives in plasters and as binders in emulsion paints.
Inventors
👤 Klaus Kohlhammer
👤 Hermann Petersen
👤 Walter Dobler
Bibliographic Details
Application Number—
JurisdictionUS
Data Sourcegoogle_patents
Last Synchronized2026-10-31 01:09
CPC Classifications
C; C08; C08F; C08F261/00; C08F261/06; C08F293/00
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
155 words
Peroxy group-containing copolymers containing from 0.01 to 20% by weight of peroxy monovinyl esters of the formula I or II ##STR3## wherein R 1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R 2 and R 3 are an alkyl group having 1 to 4 carbon atoms, R 4 is an alkyl group or an alkyl-substituted phenyl group having 1 to 12 carbon atoms or a cycloalkyl group having 3 to 12 carbon atoms, and R 5 is a cycloalkyl group having 3 to 12 carbon atoms and from 80 to 99% by weight of at least one comonomer selected from the group consisting of the (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinylaromatic compounds, vinyl halides and vinyl ethers.
Claim 2
Dependent Claim
155 words
Peroxy group-containing copolymers containing from 0.01 to 20% by weight of peroxy monovinyl esters of the formula I or II ##STR3## wherein R 1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R 2 and R 3 are an alkyl group having 1 to 4 carbon atoms, R 4 is an alkyl group or an alkyl-substituted phenyl group having 1 to 12 carbon atoms or a cycloalkyl group having 3 to 12 carbon atoms, and R 5 is a cycloalkyl group having 3 to 12 carbon atoms and from 80 to 99% by weight of at least one comonomer selected from the group consisting of the (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinylaromatic compounds, vinyl halides and vinyl ethers.
Claim 3
Dependent Claim
57 words
Peroxy group-containing copolymers according to claim 1, wherein the copolymers contain from 0.01 to 20% by weight of peroxy monovinyl esters of the formula I or II and from 80 to 99.9% by weight of at least one comonomer selected from the group consisting of vinyl acetate, isopropenyl acetate, vinyl propionate, vinyl laurate, vinyl chloride and/or ethylene.
Claim 4
Dependent Claim
42 words
Peroxy group containing copolymers according to claim 1 wherein the copolymers are composed of from 0 to 50% by weight of ethylene, from at least 50% by weight of vinyl acetate and from 0.01 to 5% by weight of t-butylperoxy monovinyl adipate.