US5370919A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Fluorochemical water- and oil-repellant treating compositions
Assignee: 3M Co
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Filing: 1992-11-06
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Granted: 1994-12-06
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Expires: 2012-11-06
Abstract
Abstract This invention relates to a treating composition containing 0.3 to 30% by weight of a fluoroaliphatic radical containing poly(oxyalkylene) compound, 0.3 to 30% by weight of an anti-soiling agent and 0 to 60% by weight of an environmentally acceptable water-miscible organic solvent and water for the use for imparting excellent water- and oil repellency, stain resistance and dry soil resistance to textiles, carpets, concrete, paper, leather and wool.
Inventors
- 👤 Franceska Fieuws
- 👤 Kathy Allewaert
- 👤 Dirk Coppens
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 01:29
CPC Classifications
C; C04; C04B; C04B41/00; C04B41/009; C04B41/45; C04B41/46; C04B41/48; C04B41/4838; C04B41/4842; C04B41/60; C04B41/61; C04B41/62; C04B41/63; C08; C08L; C08L97/00; C08L97/02; D; D06; D06M; D06M11/00; D06M11/32; D06M11/36; D06M11/45; D06M11/77; D06M11/79; D06M15/00; D06M15/01; D06M15/03; D06M15/05; D06M15/19; D06M15/21; D06M15/227; D06M15/233; D06M15/263; D06M15/277; D06M15/37; D06M15/39; D06M15/423; D06M15/53; D06M23/00; D06M23/10; D06N; D06N3/00; D06N3/04; D06N3/047; B; B27; B27K; B27K2240/00; B27K2240/70; B27K3/00; B27K3/02; B27K3/15; B27K3/153; B27K3/16; B27K3/30; C04B2111/00; C04B2111/20; C04B2111/203; C04B2111/27; C08L33/00; C08L33/04; C08L33/14; C08L33/16; C08L59/00; Y; Y10; Y10T; Y10T428/00; Y10T428/23907; Y10T428/23986; Y10T428/29; Y10T428/2904; Y10T428/2907; Y10T428/2913; Y10T428/2933; Y10T428/31504; Y10T428/3154; Y10T428/31971; Y10T428/31993; Y10T442/00; Y10T442/20; Y10T442/2164; Y10T442/2172; Y10T442/2279; Y10T442/2287
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
198 words
A process for providing a fibrous substrate with water- and oil-repellency, stain resistance and dry soil resistance comprising the steps of (a) contacting said fibrous substrate which is a textile fiber or filament, or a finished or fabricated fibrous article, with an aqueous treating solution comprising a) 0.3 to 30% by weight of a water soluble or dispersible fluoroaliphatic radical-containing poly(oxyalkylene) compound, or a composition comprising a mixture or such poly(oxyalkylene) compounds having one or more monovalent fluoroaliphatic radicals and one or more poly(oxyalkylene) moieties, said fluoroaliphatic radicals and poly(oxyalkylene) moieties being bonded together by hetero atom-containing groups or organic linking groups or combinations of such groups; b) 0.3 to 30% by weight of solid, non-tacky, water-soluble or water dispersible anti-soiling agent which is a brittle polymeric resin, colloidal alumina or colloidal silica and which, upon drying of the composition at ambient temperature, is capable of rendering the substrate non-tacky and resistant to soiling; and c) water, with the proviso that the ratio of component (a) to component (b) be 1:20 to 20:1. by spraying, dipping, coating, padding, foam or roller coating application or a combination thereof and (b) allowing the treated substrate to dry at ambient temperature.
Claim 2
Dependent Claim
198 words
A process for providing a fibrous substrate with water- and oil-repellency, stain resistance and dry soil resistance comprising the steps of (a) contacting said fibrous substrate which is a textile fiber or filament, or a finished or fabricated fibrous article, with an aqueous treating solution comprising a) 0.3 to 30% by weight of a water soluble or dispersible fluoroaliphatic radical-containing poly(oxyalkylene) compound, or a composition comprising a mixture or such poly(oxyalkylene) compounds having one or more monovalent fluoroaliphatic radicals and one or more poly(oxyalkylene) moieties, said fluoroaliphatic radicals and poly(oxyalkylene) moieties being bonded together by hetero atom-containing groups or organic linking groups or combinations of such groups; b) 0.3 to 30% by weight of solid, non-tacky, water-soluble or water dispersible anti-soiling agent which is a brittle polymeric resin, colloidal alumina or colloidal silica and which, upon drying of the composition at ambient temperature, is capable of rendering the substrate non-tacky and resistant to soiling; and c) water, with the proviso that the ratio of component (a) to component (b) be 1:20 to 20:1. by spraying, dipping, coating, padding, foam or roller coating application or a combination thereof and (b) allowing the treated substrate to dry at ambient temperature.
Claim 3
Dependent Claim
23 words
The process of claim 1 wherein the treating composition further comprises 60% by weight of at least one environmentally acceptable water-missible organic solvent.
Claim 4
Dependent Claim
213 words
The process of claim 1 wherein the fluoroaliphatic radical containing poly(oxyalkylene) compound of the treating composition has the general formula: (R.sub.f).sub.s Z[(R.sup.3).sub.y Z'B].sub.t II [(R.sub.f).sub.s Z[(R.sup.3).sub.y Z'B'].sub.t ].sub.w III where R F is a fluoroaliphatic radical, Z is a linkage through which R f and (R 3 ) y moieties are covalently bonded together, (R 3 ) y is a poly(oxyalkylene) moiety, R 3 being an oxyalkylene group with 2 to 4 carbon atoms and y is an integer where the above formulas are those of individual compounds or a number where the above formulas are those of mixtures at least 4. B is a hydrogen atom or a monovalent terminal organic radical, B' is B or a valence bond, with the proviso that at least B' is a valence bond interconnecting a Z-bonded R 3 radical to another Z, Z' is a linkage through which B, or B', and R 3 are covalently bonded together, s is an integer or number of at least 1 and can be as high as 25 or higher, t is an integer or number of at least 1, and can be as high as 60 or higher, and w is an integer or number greater than 1, and can be as high as 30 or higher.
Claim 5
Dependent Claim
27 words
The process of claim 1 wherein the fluoroaliphatic radical containing poly(oxyalkylene) compound of the treating composition contains a fluoroalkyl radical having from 3 to 20 carbon atoms.
Claim 6
Dependent Claim
24 words
The process of claim 1 wherein the poly(oxyalkylene) compound of the treating composition contains 4 to 180 ethylene or propylene radicals or combinations thereof.
Claim 7
Dependent Claim
60 words
The process of claim 1 wherein said poly(oxyalkylene) compound of the treating composition is a copolymer of (a) C 8 F 17 SO 2 N(CH 3 )C 2 H 4 OCOCH═CH 2 (b) CH 2 ═C(CH 3 )COO(CH 2 CH 2 O) 90 H and (c) CH 2 ═C(CH 3 )COO(CH 2 CH 2 O) 90 COC(CH 3 )═CH 2
Claim 8
Dependent Claim
15 words
The process of claim 6 wherein the weight ratio a:(b+c) is 1:1, b:c is 3:1.
Claim 9
Dependent Claim
35 words
The process of claim 2 wherein the water-miscible organic solvent is an alcohol, a water-miscible ether, a glycol ether, a lower ester of monoalkyl ether, of ethylene glycol or of propylene glycol, and mixtures thereof.
Claim 10
Dependent Claim
34 words
The process of claim 11 wherein the brittle polymeric resins include styrene-malaic anhydride copolymers and salts thereof, polyvinyl- pyrrolidone, polyacrylate/acrylic acid copolymers, vinyl acetate/maleic anhydride copolymers, carboxymethylcellulose, carboxyl-containing resins and water soluble melamine-formaldehyde condensates.
Claim 11
Dependent Claim
16 words
The process of claim 1 wherein said substrate is a textile fabric, carpet, paper or leather.
Claim 12
Dependent Claim
39 words
A treated fibrous substrate having water- and oil-repellency, stain resistance and dry soil resistance treated according to the process of claim 1 wherein said fibrous substrate is a textile fiber or filament, or a finished or fabricated fibrous article.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-12-05 | 1998-06-06 | 1998-12-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-12-05 | 2002-06-06 | 2002-12-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-12-05 | 2006-06-06 | 2006-12-06 | $7700.00 | Window Closed / Lapsed |