US5367470A
Expired / Lapsed
US
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Method for fuel flow determination and improving thermal efficiency in a fossil-fired power plant
Assignee: NOT EXERGET Inc
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Filing: 1992-02-12
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Granted: 1994-11-22
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Expires: 2012-02-12
Abstract
Abstract A method for determining fuel flow rate, pollutant flow rates, and boiler efficiency for a fossil-fired steam generator system from an analysis of the composition of the dry fuel base and composition of the combustion effluents.
Inventors
- 👤 Fred D. Lang
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 18:22
CPC Classifications
F; F23; F23N; F23N5/00; F23N5/18; F23N5/003; F23N2005/185; F23N2221/00; F23N2221/10; F23N2225/00; F23N2225/22; F23N2239/00; F23N2239/02
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
241 words
A method for improving thermal efficiency of a fossil-fired power plant system comprising a boiler cycle in which a fossil fuel is supplied at a flow rate to be combusted to heat a working fluid, the combustion of the fuel producing effluents in an exhaust, and a turbine cycle in which the working fluid does work, the method comprising the following steps: analyzing the fuel for its dry base chemical composition, measuring at a gas exit boundary of the power plant system, in the exhaust of the combustion process, the temperature, concentrations of CO 2 and H 2 O effluents to an accuracy of at least ±0.5% molar, and concentrations of O 2 with an accuracy at least comparable to zirconium oxide detection, measuring the net energy deposition to the working fluid being heated by the combustion process, determining, independently of the fuel flow rate, a combustion efficiency based on a stoichiometric balance of a combustion equation and a boiler absorption efficiency based on determination of non-stack losses, combining the combustion efficiency and the boiler absorption efficiency to obtain a boiler efficiency, determining an efficiency of the turbine cycle, combining the boiler efficiency and the turbine cycle efficiency to obtain the power plant system efficiency, determining in response to obtaining the boiler efficiency and the power plant system efficiency if either is degraded from predetermined parameters, and adjusting operation of the system to improve its boiler efficiency and/or its system efficiency.
Claim 2
Independent Claim
241 words
A method for improving thermal efficiency of a fossil-fired power plant system comprising a boiler cycle in which a fossil fuel is supplied at a flow rate to be combusted to heat a working fluid, the combustion of the fuel producing effluents in an exhaust, and a turbine cycle in which the working fluid does work, the method comprising the following steps: analyzing the fuel for its dry base chemical composition, measuring at a gas exit boundary of the power plant system, in the exhaust of the combustion process, the temperature, concentrations of CO 2 and H 2 O effluents to an accuracy of at least ±0.5% molar, and concentrations of O 2 with an accuracy at least comparable to zirconium oxide detection, measuring the net energy deposition to the working fluid being heated by the combustion process, determining, independently of the fuel flow rate, a combustion efficiency based on a stoichiometric balance of a combustion equation and a boiler absorption efficiency based on determination of non-stack losses, combining the combustion efficiency and the boiler absorption efficiency to obtain a boiler efficiency, determining an efficiency of the turbine cycle, combining the boiler efficiency and the turbine cycle efficiency to obtain the power plant system efficiency, determining in response to obtaining the boiler efficiency and the power plant system efficiency if either is degraded from predetermined parameters, and adjusting operation of the system to improve its boiler efficiency and/or its system efficiency.
Claim 3
Dependent Claim
64 words
The method of claim 1 including the steps of repetitiously adjusting an assumed water concentration in the fuel until consistency is obtained between the measured CO 2 and H 2 O effluents and computed CO 2 and H 2 O effluents determined by stoichiometrics based on the chemical composition of the fuel, thereby establishing the validity of the calculated boiler efficiency and/or system efficiency.
Claim 4
Dependent Claim
22 words
The method of claim 1 wherein the measured CO 2 and H.sub. O effluents are measured by utilizing an emissions spectral radiometer.
Claim 5
Dependent Claim
31 words
The method of claim 1 including determining whether degradations of operation are occurring in the boiler cycle, and whether stack losses are increasing by detecting decreases in iterative combustion efficiency determinations.
Claim 6
Dependent Claim
60 words
The method of claim 1 including determining whether degradations of operation are occurring in the boiler cycle due to increased radiation and convection losses, heat content remaining in the coal rejects if the fuel is coal, heat exchanger water/steam leaks, heat exchanger loss of effectiveness, and increases in other non-stack losses by detecting decreases in iterative boiler absorption efficiency determinations.
Claim 7
Independent Claim
338 words
A method for determining and improving thermal efficiency of a fossil-fired power plant system comprising a boiler cycle in which a fossil fuel is supplied at a flow rate to be combusted to heat a working fluid, the combustion of the fuel producing effluents in an exhaust, and a turbine cycle in which the working fluid does work, comprising the following steps: analyzing the fuel for its dry base chemical composition, measuring in the exhaust of the combustion process at the gas exit boundary of the power plant system the temperature, concentrations of CO 2 and H 2 O effluents to at least an accuracy of ±0.5% molar by utilizing an emissions spectral radiometer, and concentrations of O 2 with an accuracy at least comparable to zirconium oxide detection, measuring the net energy deposition to the working fluid being heated by the combustion process, determining, independently of the fuel mass flow rate, both a combustion efficiency as based on a stoichiometric balance of a combustion equation and a boiler absorption efficiency based on determination of non-stack losses, combining combustion efficiency and boiler absorption efficiency to obtain the boiler efficiency, repetitiously adjusting assumed water concentration in the fuel until consistency is obtained between the measured CO 2 and H 2 O effluents and those determined by stoichiometries based on the chemical concentration of the fuel for establishing validity for a calculated fuel mass flow rate and boiler efficiency, determining whether degradations from predetermined parameters are occurring in the fuel-air mixing equipment, the differential boiler fuel flows, the heat content of the fuel, and whether stack losses are increasing by detecting decreases in iterative combustion efficiency calculations, determining whether degradations from predetermined parameters are occurring due to increased radiation and convection losses, heat content remaining in the coal rejects, heat exchanger water/steam leaks, heat exchanger loss of effectiveness, and increases in other non-stack losses by detecting decreases in iterative boiler absorption efficiency calculations, and adjusting operation of the power plant system to improve its thermal efficiency and/or its system efficiency.
Claim 8
Independent Claim
338 words
A method for determining and improving thermal efficiency of a fossil-fired power plant system comprising a boiler cycle in which a fossil fuel is supplied at a flow rate to be combusted to heat a working fluid, the combustion of the fuel producing effluents in an exhaust, and a turbine cycle in which the working fluid does work, comprising the following steps: analyzing the fuel for its dry base chemical composition, measuring in the exhaust of the combustion process at the gas exit boundary of the power plant system the temperature, concentrations of CO 2 and H 2 O effluents to at least an accuracy of ±0.5% molar by utilizing an emissions spectral radiometer, and concentrations of O 2 with an accuracy at least comparable to zirconium oxide detection, measuring the net energy deposition to the working fluid being heated by the combustion process, determining, independently of the fuel mass flow rate, both a combustion efficiency as based on a stoichiometric balance of a combustion equation and a boiler absorption efficiency based on determination of non-stack losses, combining combustion efficiency and boiler absorption efficiency to obtain the boiler efficiency, repetitiously adjusting assumed water concentration in the fuel until consistency is obtained between the measured CO 2 and H 2 O effluents and those determined by stoichiometries based on the chemical concentration of the fuel for establishing validity for a calculated fuel mass flow rate and boiler efficiency, determining whether degradations from predetermined parameters are occurring in the fuel-air mixing equipment, the differential boiler fuel flows, the heat content of the fuel, and whether stack losses are increasing by detecting decreases in iterative combustion efficiency calculations, determining whether degradations from predetermined parameters are occurring due to increased radiation and convection losses, heat content remaining in the coal rejects, heat exchanger water/steam leaks, heat exchanger loss of effectiveness, and increases in other non-stack losses by detecting decreases in iterative boiler absorption efficiency calculations, and adjusting operation of the power plant system to improve its thermal efficiency and/or its system efficiency.
Claim 9
Independent Claim
209 words
A method for determining the fuel flow rate and pollutant flow rates of a fossil-fired steam generator system having a working fluid by monitoring the operation of the steam generator system and making calculations which are derived from data obtained from the analysis of the chemical composition of the dry component of the fuel, the concentrations of the common pollutants produced from combustion, and the concentrations of CO 2 and superheated water produced from combustion and the fuel, comprising analyzing the fuel for its dry base chemical composition, measuring at a gas exit boundary of the steam generator system in the exhaust of the combustion process the temperature, concentrations of CO 2 and H 2 O effluents to an accuracy of at least ±0.5% molar, and concentrations of O 2 with an accuracy at least comparable to zirconium oxide detection, measuring the net energy deposition to the working fluid being heated by the combustion process, calculating, independently of the fuel flow rate, a combustion efficiency based on the stoichiometric balance of a combustion equation and a boiler absorption efficiency based on determination of non-stack losses, combining the combustion efficiency and the boiler absorption efficiency to obtain a boiler efficiency, and determining the fuel flow rate from the boiler efficiency.
Claim 10
Independent Claim
209 words
A method for determining the fuel flow rate and pollutant flow rates of a fossil-fired steam generator system having a working fluid by monitoring the operation of the steam generator system and making calculations which are derived from data obtained from the analysis of the chemical composition of the dry component of the fuel, the concentrations of the common pollutants produced from combustion, and the concentrations of CO 2 and superheated water produced from combustion and the fuel, comprising analyzing the fuel for its dry base chemical composition, measuring at a gas exit boundary of the steam generator system in the exhaust of the combustion process the temperature, concentrations of CO 2 and H 2 O effluents to an accuracy of at least ±0.5% molar, and concentrations of O 2 with an accuracy at least comparable to zirconium oxide detection, measuring the net energy deposition to the working fluid being heated by the combustion process, calculating, independently of the fuel flow rate, a combustion efficiency based on the stoichiometric balance of a combustion equation and a boiler absorption efficiency based on determination of non-stack losses, combining the combustion efficiency and the boiler absorption efficiency to obtain a boiler efficiency, and determining the fuel flow rate from the boiler efficiency.
Claim 11
Dependent Claim
64 words
The method of claim 7 including the steps of repetitiously changing the assumed value of water concentration in the fuel until consistency is obtained between the measured CO 2 and H 2 O effluents and computed CO 2 and H 2 O effluents determined by stoichiometries based on the chemical composition of the fuel, thereby establishing validity for the calculated fuel mass flow rate.
Claim 12
Dependent Claim
53 words
The method of claim 7 further comprising the following steps: measuring the concentration of the common pollutants in the exhaust of the combustion process with an accuracy comparable to standard industrial practice, and determining the pollutant flow rates from the fuel mass flow rate and knowledge of the concentrations of the common pollutants.
Claim 13
Dependent Claim
17 words
The method of claim 9 wherein the common pollutants are measured by utilizing an emissions spectral radiometer.
Claim 14
Dependent Claim
66 words
The method of claim 9 wherein action is taken to adjust operation of the steam generator system to minimize pollutant concentrations effluent from the steam generator system by lowering the fuel firing rate, by mixing fuels having different sulfur contents for SO 2 and SO 3 control, by lowering the combustion flame temperature for NO x control and other such actions necessary to reduce pollutant concentrations.
Claim 15
Dependent Claim
79 words
The method of claim 9 wherein action is taken to adjust operation of the steam generator system to minimize pollutant effluent flow rates from the steam generator system by lowering the fuel firing rate, by mixing fuels having different sulfur contents for SO 2 and SO 3 control, by lowering the combustion flame temperature for NO x control, by mixing fuels having different nitrogen contents for NO x control, and other such actions necessary to reduce pollutant flow rates.
Claim 16
Dependent Claim
73 words
The method for determining fuel flow rate and pollutant flow rates of claim 9 including the steps of repetitiously changing an assumed value of water concentration in the fuel until consistency is obtained between the measured CO 2 and H 2 O effluents and the computed CO 2 and H 2 O effluents determined by stoichiometries based on the chemical composition of the fuel, thereby establishing validity for the calculated pollutant flow rates.
Claim 17
Dependent Claim
78 words
The method according to claim 7 further comprising the steps of determining a calculated heating value of the fuel based on the dry base chemical composition of the fuel and an assumed water content of the fuel, and repetitiously changing the assumed water concentration in the fuel until consistency is obtained between the measured water concentration in the fuel and the computed water concentration in the fuel, thereby establishing validity for the calculated heating value of the fuel.
Claim 18
Independent Claim
243 words
A method for determining fuel flow, pollutant flow rates, and improving thermal efficiency of a fossil-fired steam generator power plant system comprising a boiler cycle in which a fossil fuel is supplied at a flow rate to be combusted to heat a working fluid, the combustion of the fuel producing effluents in an exhaust, and a turbine cycle in which the working fluid does work, the method comprising the following steps: analyzing the fuel for its dry base chemical composition, measuring at a gas exit boundary of the power plant system, in the exhaust, the temperature, the concentrations of CO 2 and H 2 O effluents to a predetermined accuracy, and O 2 with an accuracy at least comparable to zirconium oxide detection, measuring the net energy deposition to the working fluid being heated by the combustion process, determining, independently of the fuel flow rate, a combustion efficiency based on a stoichiometric balance of a combustion equation and a boiler absorption efficiency based on determination of non-stack losses, combining the combustion efficiency and the boiler absorption efficiency to obtain a boiler efficiency, determining an efficiency of the turbine cycle, combining the boiler efficiency and the turbine cycle efficiency to obtain the power plant system efficiency, determining in response to obtaining the boiler efficiency and the power plant system efficiency if either is degraded from predetermined parameters, and adjusting operation of the power plant system to improve its boiler efficiency and/or its system efficiency.
Claim 19
Independent Claim
243 words
A method for determining fuel flow, pollutant flow rates, and improving thermal efficiency of a fossil-fired steam generator power plant system comprising a boiler cycle in which a fossil fuel is supplied at a flow rate to be combusted to heat a working fluid, the combustion of the fuel producing effluents in an exhaust, and a turbine cycle in which the working fluid does work, the method comprising the following steps: analyzing the fuel for its dry base chemical composition, measuring at a gas exit boundary of the power plant system, in the exhaust, the temperature, the concentrations of CO 2 and H 2 O effluents to a predetermined accuracy, and O 2 with an accuracy at least comparable to zirconium oxide detection, measuring the net energy deposition to the working fluid being heated by the combustion process, determining, independently of the fuel flow rate, a combustion efficiency based on a stoichiometric balance of a combustion equation and a boiler absorption efficiency based on determination of non-stack losses, combining the combustion efficiency and the boiler absorption efficiency to obtain a boiler efficiency, determining an efficiency of the turbine cycle, combining the boiler efficiency and the turbine cycle efficiency to obtain the power plant system efficiency, determining in response to obtaining the boiler efficiency and the power plant system efficiency if either is degraded from predetermined parameters, and adjusting operation of the power plant system to improve its boiler efficiency and/or its system efficiency.
Claim 20
Dependent Claim
29 words
The method according to claim 15 in which the concentrations of CO 2 and H 2 O effluents are measured to a predetermined accuracy of greater than ±5.0% molar.
Claim 21
Dependent Claim
29 words
The method according to claim 15 in which the concentrations of CO 2 and H 2 O effluents are measured to a predetermined accuracy of greater than ±0.5% molar.
Claim 22
Dependent Claim
20 words
The method according to claim 15 further comprising the step of determining the fuel flow rate from the boiler efficiency.
Claim 23
Dependent Claim
54 words
The method according to claim 15 further comprising the steps of measuring the concentration of the common pollutants in the exhaust of the combustion process with an accuracy comparable to standard industrial practice and determining the pollutant flow rates from the fuel mass flow rate and knowledge of the concentrations of the common pollutants.
Claim 24
Dependent Claim
67 words
The method according to claim 15 including the steps of repetitiously adjusting an assumed water concentration in the fuel until consistency is obtained between the measured CO 2 and H 2 O effluents and the CO 2 and H 2 O effluents determined by stoichiometrics based on the chemical composition of the fuel, thereby establishing the validity of the calculated boiler efficiency and/or power plant system efficiency.
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