US5364748A
Expired / Lapsed
US
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Silver halide color photographic light-sensitive material
Assignee: Fujifilm Holdings Corp
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Filing: 1993-07-08
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Granted: 1994-11-15
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Expires: 2013-07-08
Abstract
Abstract There is disclosed a silver halide color photo-graphic light-sensitive material capable of providing a dye image having excellent color reproducibility, sharpness and image fastness. The light-sensitive material comprises a support having provided thereon a photographic constituent layer comprising a light-sensitive silver halide emulsion layer containing a yellow dye-forming coupler, a light-sensitive silver halide emulsion layer containing a magenta dye-forming coupler, and a light-sensitive silver halide emulsion layer containing a cyan dye-forming coupler, and non-light-sensitive hydrophilic colloid layers. The above silver halide emulsion layer containing the cyan dye-forming coupler contains at least one cyan dye-forming couplers represented by the following Formula (Ia), and wherein at least one of the non-light-sensitive hydrophilic colloid layers is provided between the support and the silver halide emulsion layer closest to the support and contains a white pigment in a filling rate of 20 weight % or more: ##STR1## wherein Za represents --NH-- or --CH(R 3 )--, and Zb and Zc each represents --C(R 4 )═ or --N═; R 1 , R 2 and R 3 each represents an electron attractive group having a Hammett's substituent constant σ p of 0.20 or more, provided that the sum of the σ p values of R 1 and R 2 is 0.65 or more; R 4 represents a hydrogen atom or a substituent, provided that when two R 4 groups are present in the formula, they may be the same or different; X represents a hydrogen atom or a group capable of splitting off upon a reaction with an oxidation product of an aromatic primary amine color developing agent; the group represented by R 1 , R 2 , R 3 , R 4 or X may become a divalent group and combine with a polymer higher than a dimer and a high molecular chain to form a homopolymer or a copolymer.
Inventors
- 👤 Hiroyuki Yoneyama
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 18:54
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/95; G03C7/00; G03C7/30; G03C7/3003; G03C7/3005; G03C7/3008; G03C7/301; G03C1/005; G03C1/035; G03C1/825; G03C2001/03517; G03C7/3029; Y; Y10; Y10S; Y10S430/00; Y10S430/151
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
242 words
A silver halide color photographic light-sensitive material comprising a support having provided thereon a photographic constituent layer comprising a light-sensitive silver halide emulsion layer containing a yellow dye-forming coupler, a light-sensitive silver halide emulsion containing a magenta dye-forming coupler, and a light-sensitive silver halide emulsion layer containing a cyan dye-forming coupler, and non-light-sensitive hydrophilic colloid layers, wherein the above silver halide emulsion layer containing the cyan dye-forming coupler contains at least one cyan dye-forming coupler represented by the following Formula (IIIa) and wherein at least one of the non-light-sensitive hydrophilic colloid layers is provided between the support and the silver halide emulsion layer closest to the support and contains a white pigment at a density of 20 weight % or more: Formula (IIIa) ##STR102## wherein R 1 and R 2 each represents an electron attractive group having a Hammett's substituent constant σ p of 0.20 or more, provided that the sum of the σ p values of R 1 and R 2 is 0.65 or more; R 4 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of splitting off upon a reaction with an oxidation product of an aromatic primary amine color developing agent; the group represented by R 1 , R 2 , R 4 or X may become a divalent group and combine with a polymer higher than a dimer and a high molecular chain to form a homopolymer or a copolymer.
Claim 2
Dependent Claim
242 words
A silver halide color photographic light-sensitive material comprising a support having provided thereon a photographic constituent layer comprising a light-sensitive silver halide emulsion layer containing a yellow dye-forming coupler, a light-sensitive silver halide emulsion containing a magenta dye-forming coupler, and a light-sensitive silver halide emulsion layer containing a cyan dye-forming coupler, and non-light-sensitive hydrophilic colloid layers, wherein the above silver halide emulsion layer containing the cyan dye-forming coupler contains at least one cyan dye-forming coupler represented by the following Formula (IIIa) and wherein at least one of the non-light-sensitive hydrophilic colloid layers is provided between the support and the silver halide emulsion layer closest to the support and contains a white pigment at a density of 20 weight % or more: Formula (IIIa) ##STR102## wherein R 1 and R 2 each represents an electron attractive group having a Hammett's substituent constant σ p of 0.20 or more, provided that the sum of the σ p values of R 1 and R 2 is 0.65 or more; R 4 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of splitting off upon a reaction with an oxidation product of an aromatic primary amine color developing agent; the group represented by R 1 , R 2 , R 4 or X may become a divalent group and combine with a polymer higher than a dimer and a high molecular chain to form a homopolymer or a copolymer.
Claim 3
Dependent Claim
36 words
The light-sensitive material of claim 1, wherein at least one layer of the above light-sensitive emulsion layers and non-light-sensitive hydrophilic colloid layer is a coloring layer capable of being decolored during a color development processing step.
Claim 4
Dependent Claim
22 words
The light-sensitive material of claim 1, wherein the emulsion layer containing the cyan dye-forming coupler is a red-sensitive silver halide emulsion layer.
Claim 5
Dependent Claim
31 words
The light-sensitive material of claim 1, wherein the addition amount of the cyan coupler in the silver halide emulsion layer is 1×10 -3 to 1 mole per mole of silver halide.
Claim 6
Dependent Claim
28 words
The light-sensitive material of claim 1, wherein the coating amount of the cyan coupler is 2.0×10 -6 to 2.0×10 -3 mole per m 2 of the light-sensitive material.
Claim 7
Dependent Claim
24 words
The light-sensitive material of claim 1, wherein the density of the white pigment in the hydrophilic colloid layer is 40 weight % or more.
Claim 8
Dependent Claim
41 words
The light-sensitive material of claim 1, wherein at least one light-sensitive silver halide emulsion layer comprises silver bromochloride emulsion containing 1 mole % or less of silver iodide and 90 mole % or more of silver chloride, or silver chloride emulsion.
Claim 9
Dependent Claim
23 words
The light-sensitive material of claim 2, wherein the coloring layer contains a fine powder dye or colloidal silver as a coloring layer component.
Claim 10
Dependent Claim
95 words
The light-sensitive material of claim 1, wherein R 1 is a cyano group; R 2 is a trifluoromethyl group, a cyano group, a straight or branched unsubstituted alkoxycarbonyl group, an alkoxycarbonyl group substituted with a carbonyl group, an ether linkage-containing alkoxycarbonyl group, an unsubstituted aryloxycarbonyl group, or an aryloxycarbonyl group substituted with an alkyl group or an alkoxy group; R 4 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of splitting off upon a reaction with an oxidation product of an aromatic primary amine color developing agent.
Claim 11
Dependent Claim
243 words
The silver halide color photographic light-sensitive material comprising a reflective support covered with a waterproof resin layer and having provided thereon a photographic constituent layer comprising a light-sensitive silver halide emulsion layer containing a yellow dye-forming coupler, a light-sensitive silver halide emulsion layer containing a magenta dye-forming coupler, and a light-sensitive silver halide emulsion layer containing a cyan dye-forming coupler, and at least one non-light-sensitive hydrophilic colloid layer, wherein the above silver halide emulsion layer containing the cyan dye-forming coupler contains at least one cyan dye-forming coupler represented by the following Formula (IIIa) and wherein the above waterproof resin layer provided on the emulsion layer side of the support contains a white pigment at a density of 15 weight % or more: Formula (IIIa) ##STR103## wherein R 1 and R 2 each represents an electron attractive group having a Hammett's substituent constant σ p of 0.20 or more, provided that the sum of the σ p values of R 1 and R 2 is 0.65 or more; R 4 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of splitting off upon a reaction with an oxidation product of an aromatic primary amine color developing agent; the group represented by R 1 , R 2 , R 4 or X may become a divalent group and combine with a polymer higher than a dimer and a high molecular chain to form a homopolymer or a copolymer.
Claim 12
Dependent Claim
243 words
The silver halide color photographic light-sensitive material comprising a reflective support covered with a waterproof resin layer and having provided thereon a photographic constituent layer comprising a light-sensitive silver halide emulsion layer containing a yellow dye-forming coupler, a light-sensitive silver halide emulsion layer containing a magenta dye-forming coupler, and a light-sensitive silver halide emulsion layer containing a cyan dye-forming coupler, and at least one non-light-sensitive hydrophilic colloid layer, wherein the above silver halide emulsion layer containing the cyan dye-forming coupler contains at least one cyan dye-forming coupler represented by the following Formula (IIIa) and wherein the above waterproof resin layer provided on the emulsion layer side of the support contains a white pigment at a density of 15 weight % or more: Formula (IIIa) ##STR103## wherein R 1 and R 2 each represents an electron attractive group having a Hammett's substituent constant σ p of 0.20 or more, provided that the sum of the σ p values of R 1 and R 2 is 0.65 or more; R 4 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of splitting off upon a reaction with an oxidation product of an aromatic primary amine color developing agent; the group represented by R 1 , R 2 , R 4 or X may become a divalent group and combine with a polymer higher than a dimer and a high molecular chain to form a homopolymer or a copolymer.
Claim 13
Dependent Claim
36 words
The light-sensitive material of claim 10, wherein at least one layer of the above light-sensitive emulsion layers and non-light-sensitive hydrophilic colloid layer is a coloring layer capable of being decolored during a color development processing step.
Claim 14
Dependent Claim
22 words
The light-sensitive material of claim 10, wherein the emulsion layer containing the cyan dye-forming coupler is a red-sensitive silver halide emulsion layer.
Claim 15
Dependent Claim
31 words
The light-sensitive material of claim 10, wherein the addition amount of the cyan coupler in the silver halide emulsion layer is 1×10 -3 to 1 mole per mole of silver halide.
Claim 16
Dependent Claim
28 words
The light-sensitive material of claim 10, wherein the coating amount of the cyan coupler is 2.0×10 -6 to 2.0×10 -3 mole per m 2 of the light-sensitive material.
Claim 17
Dependent Claim
20 words
The light-sensitive material of claim 10, further containing a white pigment in at least one non-light sensitive hydrophilic colloid layer.
Claim 18
Dependent Claim
41 words
The light-sensitive material of claim 10, wherein at least one light-sensitive silver halide emulsion layer comprises silver bromochloride emulsion containing 1 mole % or less of silver iodide and 90 mole % or more of silver chloride, or silver chloride emulsion.
Claim 19
Dependent Claim
23 words
The light-sensitive material of claim 11, wherein the coloring layer contains a fine powder dye or colloidal silver as a coloring layer component.
Claim 20
Dependent Claim
95 words
The light-sensitive material of claim 10, wherein R 1 is a cyano group; R 2 is a trifluoromethyl group, a cyano group, a straight or branched unsubstituted alkoxycarbonyl group, an alkoxycarbonyl group substituted with a carbonyl group, an ether linkage-containing alkoxycarbonyl group, an unsubstituted aryloxycarbonyl group, or an aryloxycarbonyl group substituted with an alkyl group or an alkoxy group; R 4 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of splitting off upon a reaction with an oxidation product of an aromatic primary amine color developing agent.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-11-14 | 1998-05-16 | 1998-11-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-11-14 | 2002-05-16 | 2002-11-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-11-14 | 2006-05-16 | 2006-11-15 | $7700.00 | Window Closed / Lapsed |