Crosslinked polymer microparticles based on epoxy resin, their preparation and their use

Claim 2

Crosslinked polymer microparticles based on epoxy resin, obtained by polymerization of an aqueous dispersion (A) of a compound containing epoxide groups in the presence of up to 0.2 mol (based on the nitrogen contained in (B)) of a nitrogen-containing organic compound (B) per epoxide equivalent and subsequent isolation.

Claim 3

An aqueous dispersion of crosslinked polymer microparticles based on epoxy resin, obtained by polymerization of an aqueous dispersion (A) of a compound containing epoxide groups in the presence of up to 0.2 mol (based on the nitrogen contained in (B)), of a nitrogen-containing organic compound (B) per epoxide equivalent.

Claim 4

An aqueous dispersion of crosslinked polymer microparticles based on epoxy resin, obtained by polymerization of an aqueous dispersion (A) of a compound containing epoxide groups in the presence of up to 0.2 mol (based on the nitrogen contained in (B)), of a nitrogen-containing organic compound (B) per epoxide equivalent.

Claim 5

An aqueous dispersion as claimed in claim 1, which has an average particle size of not more than 5 μm, and a content of crosslinked polymer microparticles of at least 10% by weight.

Claim 6

An aqueous dispersion as claimed in claim 2, which contains, as the solvent, a glycol, a mono- or diether or -ester of a glycol, an aliphatic alcohol having optionally branched alkyl radicals with 1 to 12 carbon atoms, a cycloaliphatic or araliphatic alcohol, an ester or ketone or an aliphatic, cycloaliphatic and/or aromatic hydrocarbon, individually or as a mixture, in an amount of up to 25% by weight.

Claim 7

An aqueous dispersion as claimed in claim 2, which comprises the other further customary paint additives, such as fillers, pigments, catalysts, flow or thickening agents, defoamers, wetting agents, preservatives, protective colloids.

Claim 8

An aqueous dispersion as claimed in claim 2, wherein the polymer microparticles also contain additional crosslinking-active centers.

Claim 9

An aqueous dispersion as claimed in claim 2, obtained by polymerization in the presence of an aliphatic, cycloaliphatic, araliphatic, aromatic, heterocyclic and/or heteroaromatic compound which contains at least one nitrogen atom which has a free electron pair.

Claim 10

An aqueous dispersion as claimed in claim 2, obtained by reaction in the presence of triethylamine, N,N-dimethyl-ethanolamine, N-methyl-diethanolamine, N,N-dimethyl-benzylamine, piperidine and/or bis(aminopropyl)methylamine.

Claim 11

An aqueous dispersion as claimed in claim 2, wherein the aqueous epoxy resin dispersion (A) employed is one which comprises the following components: (1) 20 to 75% by weight, based on the total dispersion, of an epoxy resin which is a condensation product of a) 50 to 95% by weight of one or more epoxide compounds having on average at least one epoxide group per molecule and an epoxide equivalent weight of 90 to 3000 g/equivalent, and b) 5 to 50% by weight of an aromatic polyol; (2) 3 to 20% by weight, based on the total dispersion, of an emulsifier comprising a) 20 to 100% by weight of a condensation product of an aliphatic polyol having an average molecular weight (Mw) of 200 to 20000 and an epoxide compound having at least two epoxide groups per molecule and an epoxide equivalent weight of 100 to 200 g/equivalent, the ratio of equivalents of OH groups to epoxide groups being 1:0.85 to 1:1.5 and the epoxide equivalent weight of this condensation product being between 5000 and 40000 g/equivalent, b) up to 50% by weight of an organic solvent and c) up to 80% by weight of water; (3) up to 10% by weight, based on the total dispersion, of organic solvents, any solvents present according to (2)b) also being included; (4) water in the amount lacking to make up to 100% by weight, and which is prepared by stirring the epoxy resin (1) first with the emulsifier (2) and optionally an organic solvent according to (3), and then with water (4).

Claim 12

A process for the preparation of an aqueous dispersion of crosslinked polymer microparticles (C) as claimed in claim 2, which comprises first heating the aqueous epoxy resin dispersion (A), under an inert gas atmosphere, to a temperature of 30° to 100° C., while stirring, optionally also adding an organic solvent, subsequently adding the organonitrogen compound (B), dissolved in an organic solvent and/or water, and continuing stirring until the residual epoxide equivalent weight of the reaction mixture is more than 20,000 g/equivalent.

Claim 13

A paint or coating formulation containing as a filler an aqueous dispersion of cross-linked polymer microparticles of claim 1.

Claim 14

A formulation of claim 11 which is an aqueous cataphoresis electrodeposition coating with an aqueous two component epoxide/amine binder system.