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US5358793A Expired / Lapsed US ⏱️ 0.0 years remaining

PTC device

Assignee: Daito Communication Apparatus Co Ltd
•
Filing: 1992-05-07
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Granted: 1994-10-25
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Expires: 2012-05-07
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Abstract

Abstract A PTC device has two electrodes affixed to opposed surfaces. The electrodes consist of a metal foil having a conductive layer on their surfaces that contact the PTC material. The conductive layer has a thermal coefficient of expansion intermediate between the thermal coefficients of expansion of the metal foil and the PTC material. The intermediate value of the thermal coefficient of expansion of the conductive layer prevents peeling of the electrodes off the PTC element due to the variation of the temperature of the PTC device resulting from repeated voltage applications. In addition, improved adhesion of the electrodes to the PTC material reduces resistance changes after repeated temperature cycling.

Inventors

  • 👤 Toshiyuki Hanada
  • 👤 Mayumi Takata
  • 👤 Naoki Yamazaki
  • 👤 Isao Morooka
  • 👤 Kazuhiko Harazaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 10:55
CPC Classifications
H; H01; H01C; H01C17/00; H01C17/28; H01C17/281; H01C1/00; H01C1/14; H01C1/1406; H01C7/00; H01C7/02; H01C7/027; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12014; Y10T428/12028; Y10T428/12049; Y10T428/12056; Y10T428/12063; Y10T428/12069; Y10T428/12104; Y10T428/12111

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 218 words
A PTC device comprising: a PTC element formed of a PTC composition, including a polymer having conductive particles dispersed therein; said polymer further includes at least one of a high density polyethylene and ethylene-acrylic acid copolymer; two electrodes formed of an electrode composition; said electrode composition including a metal foil having a conductive layer formed of a conductive paste; said conductive paste further comprising a mixture of conductive particles and a binder coated thereon; said conductive particles further comprising at least one conductive material selected from the group consisting of pure metal particles, metal alloy particles, metallic plated metal particles, carbonaceous particles, metallic coated carbonaceous particles, and metallic alloy coated carbonaceous particles; wherein said pure metal particles include at least one selected from the group consisting of Pt, Au, Ag and NI and wherein said metal alloy particles include at least on of PD and Ag-Pd; said binder being mixture of at least one of thermosetting resins and a thermoplastic resin having heat resistant properties capable of withstanding operational temperatures of said PTC device; said two electrodes being affixed to opposed surfaces of said PTC element with said conductive paste contacting said opposed surfaces; and said conductive paste having a thermal coefficient of expansion intermediate between thermal coefficients of expansion of said PTC element and said metal foil.
Claim 2
Dependent Claim 218 words
A PTC device comprising: a PTC element formed of a PTC composition, including a polymer having conductive particles dispersed therein; said polymer further includes at least one of a high density polyethylene and ethylene-acrylic acid copolymer; two electrodes formed of an electrode composition; said electrode composition including a metal foil having a conductive layer formed of a conductive paste; said conductive paste further comprising a mixture of conductive particles and a binder coated thereon; said conductive particles further comprising at least one conductive material selected from the group consisting of pure metal particles, metal alloy particles, metallic plated metal particles, carbonaceous particles, metallic coated carbonaceous particles, and metallic alloy coated carbonaceous particles; wherein said pure metal particles include at least one selected from the group consisting of Pt, Au, Ag and NI and wherein said metal alloy particles include at least on of PD and Ag-Pd; said binder being mixture of at least one of thermosetting resins and a thermoplastic resin having heat resistant properties capable of withstanding operational temperatures of said PTC device; said two electrodes being affixed to opposed surfaces of said PTC element with said conductive paste contacting said opposed surfaces; and said conductive paste having a thermal coefficient of expansion intermediate between thermal coefficients of expansion of said PTC element and said metal foil.
Claim 3
Dependent Claim 14 words
The PTC device according to claim 1, wherein said PTC element is a parallelepiped.
Claim 4
Dependent Claim 19 words
The PTC device according to claim 1, wherein said conductive layer has a rough surface contacting said PTC element.
Claim 5
Dependent Claim 24 words
The PTC device according to claim 3, wherein a metal powder is embedded in said conductive layer so as to create said rough surface.
Claim 6
Dependent Claim 21 words
The PTC device according to claim 4 wherein the metal powder is at least one of nickel, carbonyl nickel, and silver.
Claim 7
Dependent Claim 257 words
A process for producing a PTC device which comprises: forming a PTC element, formed of a PTC composition, including a polymer having conductive particles dispersed therein, having opposing sides; said polymer further including at least one of a high density polyethylene, ethylene-acrylic acid copolymer, and conductive particles, wherein said conductive particles include at least one conductive material selected from the group consisting of pure metal particles, metal alloy particles, metallic plated metal particles, carbonaceous particles, metallic coated carbonaceous particles, and metallic alloy coated carbonaceous particles; wherein said pure metal particles is at least one material selected from the group consisting of Pt, Au, Ag and Ni, and wherein said metal alloy particles are at least one selected from the group consisting of Au-Pd and Ag-Pd; mixing a conductive paste further comprising a mixture of conductive particles and a binder; said binder being mixture of at least one of thermosetting resins and a thermoplastic resin having heat resistant properties capable of withstanding operational temperatures of said PTC device; coating first and second metal foils with said conductive paste; curing said conductive paste to create a conductive layer on each of said first and second metal foils; affixing said conductive layer on said first metal foil to a first surface of said PTC element; and affixing said conductive layer on said second metal foil to an opposed surface of said PTC element, whereby said PTC element is disposed between said first and second metal foils, with said conductive layers interposed between said PTC element and the respective metal foils.
Claim 8
Dependent Claim 257 words
A process for producing a PTC device which comprises: forming a PTC element, formed of a PTC composition, including a polymer having conductive particles dispersed therein, having opposing sides; said polymer further including at least one of a high density polyethylene, ethylene-acrylic acid copolymer, and conductive particles, wherein said conductive particles include at least one conductive material selected from the group consisting of pure metal particles, metal alloy particles, metallic plated metal particles, carbonaceous particles, metallic coated carbonaceous particles, and metallic alloy coated carbonaceous particles; wherein said pure metal particles is at least one material selected from the group consisting of Pt, Au, Ag and Ni, and wherein said metal alloy particles are at least one selected from the group consisting of Au-Pd and Ag-Pd; mixing a conductive paste further comprising a mixture of conductive particles and a binder; said binder being mixture of at least one of thermosetting resins and a thermoplastic resin having heat resistant properties capable of withstanding operational temperatures of said PTC device; coating first and second metal foils with said conductive paste; curing said conductive paste to create a conductive layer on each of said first and second metal foils; affixing said conductive layer on said first metal foil to a first surface of said PTC element; and affixing said conductive layer on said second metal foil to an opposed surface of said PTC element, whereby said PTC element is disposed between said first and second metal foils, with said conductive layers interposed between said PTC element and the respective metal foils.
Claim 9
Dependent Claim 23 words
A process according to claim 6 further comprising roughening surfaces of said conductive paste after curing thereof, and before the step of affixing.
Claim 10
Dependent Claim 19 words
A process according to claim 7 wherein the step of roughening includes exposing the conductive layer to a plasma.
Claim 11
Dependent Claim 20 words
A process according to claim 7 wherein the step of roughening includes exposing the conductive layer to an ultraviolet radiation.
Claim 12
Dependent Claim 23 words
A process according to claim 7 wherein the step of roughening includes embedding a metal powder into a surface of the conductive coating.
Claim 13
Dependent Claim 20 words
A process according to claim 10 wherein the metal powder is at least one of nickel, carbonyl nickel, and silver.
Claim 14
Dependent Claim 72 words
A process according to claim 6 wherein the step of forming the PTC element including a polymer having conductive particles dispersed therein further includes: blending and grinding a mixture of a PTC composition and conductive particles at an elevated temperature; cooling the mixture; grinding the mixture into pieces; forming the pieces into said PTC element; and exposing the PTC element to gamma radiation in order to cross link the resultant PTC element.
Claim 15
Dependent Claim 15 words
The process of claim 7, wherein the step of roughening including sandblasting the conductive layer.

References Cited (Backward Citations)

US4189509A Cited
US4314230A Cited
DE3220362A1 Cited
US4595606A Cited
US5039844A Cited
US4849133A Cited
US4977309A Cited
US5171774A Cited
JPH02281707A Cited
JPH0359985A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-10-24 1998-04-25 1998-10-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-10-24 2002-04-25 2002-10-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-10-24 2006-04-25 2006-10-25 $7700.00 Window Closed / Lapsed

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