Nitrile removal in an etherification process

Claim 1

A method of treating an effluent of a fluid catalytic cracking zone, said effluent comprising isoalkenes and at least one nitrile compound which method comprises the steps of: (a) contacting said effluent with a C 1 -C 5 monohydroxy alcohol in the presence of an etherification catalyst in an etherification zone under etherification conditions to react said isoalkenes with said alcohol to produce an etherification effluent stream comprising an ether; (b) passing at least a portion of said etherification effluent stream to a separation zone to produce an ether-rich stream and a raffinate stream comprising said nitrile compound; (c) passing said raffinate stream to an alcohol recovery zone to produce a hydrocarbon-rich raffinate stream and an alcohol-containing stream; (d) recycling at least a portion of said alcohol-containing stream to said fluid catalytic cracking zone and (e) recycling any remainder of said alcohol-containing stream to etherification zone.

Claim 2

A method of treating an effluent of a fluid catalytic cracking zone, said effluent comprising isoalkenes and at least one nitrile compound which method comprises the steps of: (a) contacting said effluent with a C 1 -C 5 monohydroxy alcohol in the presence of an etherification catalyst in an etherification zone under etherification conditions to react said isoalkenes with said alcohol to produce an etherification effluent stream comprising an ether; (b) passing at least a portion of said etherification effluent stream to a separation zone to produce an ether-rich stream and a raffinate stream comprising said nitrile compound; (c) passing said raffinate stream to an alcohol recovery zone to produce a hydrocarbon-rich raffinate stream and an alcohol-containing stream; (d) recycling at least a portion of said alcohol-containing stream to said fluid catalytic cracking zone and (e) recycling any remainder of said alcohol-containing stream to etherification zone.

Claim 14

A method of treating an effluent of a fluid catalytic cracking zone, said effluent comprising isobutene and at least one nitrile compound which method comprises the steps of: (a) contacting said effluent with methanol in the presence of an etherification catalyst in an etherification zone under etherification conditions to react said isobutene with said methanol to produce an etherification effluent stream which comprises methyl tertiary butyl ether; (b) passing at least a portion of said etherification effluent stream to a distillation zone containing an etherification catalyst and contacting said methanol in the presence of said etherification catalyst in said distillation zone at etherification conditions to produce a methyl tertiary butyl ether-rich stream and an overhead raffinate stream; (c) contacting said raffinate stream with a water-containing stream to produce a hydrocarbon-rich raffinate stream and a methanol-containing stream; (d) monitoring the nitrile concentration of said methanol-containing stream; (e) regulating said nitrile concentration in said methanol-containing stream by recycling at least a portion of said methanol-containing stream to said fluid catalytic cracking zone; and (f) recycling any remainder of said alcohol-containing stream to said etherification zone.

Claim 15

A method of treating an effluent of a fluid catalytic cracking zone, said effluent comprising isobutene and at least one nitrile compound which method comprises the steps of: (a) contacting said effluent with methanol in the presence of an etherification catalyst in an etherification zone under etherification conditions to react said isobutene with said methanol to produce an etherification effluent stream which comprises methyl tertiary butyl ether; (b) passing at least a portion of said etherification effluent stream to a distillation zone containing an etherification catalyst and contacting said methanol in the presence of said etherification catalyst in said distillation zone at etherification conditions to produce a methyl tertiary butyl ether-rich stream and an overhead raffinate stream; (c) contacting said raffinate stream with a water-containing stream to produce a hydrocarbon-rich raffinate stream and a methanol-containing stream; (d) monitoring the nitrile concentration of said methanol-containing stream; (e) regulating said nitrile concentration in said methanol-containing stream by recycling at least a portion of said methanol-containing stream to said fluid catalytic cracking zone; and (f) recycling any remainder of said alcohol-containing stream to said etherification zone.

Claim 22

A method for fluid catalytic cracking of a hydrocarbon feedstock which method comprises the steps of: (a) contacting said hydrocarbon feedstock with a fluid catalytic cracking catalyst in a fluid catalytic cracking zone under fluid catalytic cracking conditions to produce a fluid catalytic cracking effluent stream comprising isobutene; (b) treating said fluid catalytic cracking effluent stream to remove a substantial amount of any sulfur compounds contained therein; (c) contacting said effluent from step (b) with a selective hydrogenation catalyst at selective hydrogenation conditions in a selective hydrogenation zone to selectively saturate diolefins to monoolefins; (d) contacting said effluent from step (c) with methanol in the presence of an etherification catalyst comprising a macroporous acid-form sulfonic ion exchange resin in an etherification zone under etherification conditions to react said isobutene with said methanol to produce an etherification effluent stream which comprises methyl tertiary butyl ether; (e) passing at least a portion of said etherification effluent stream to a distillation zone containing a bed of etherification catalyst comprising a macroporous acid-form sulfonic ion exchange resin and contacting said methanol in said bed of etherification catalyst in said distillation zone at etherification conditions to produce a methyl tertiary butyl ether-rich stream and an overhead raffinate stream comprising isobutane, normal butene, normal butane, methanol and isobutene; (f) contacting said raffinate stream with a water-containing stream to produce a hydrocarbon-rich raffinate stream and a methanol-containing stream; (g) fractionating said methanol-containing stream to produce a methanol-rich stream; (h) monitoring acetonitrile concentration of said methanol-rich stream; (i) regulating said acetonitrile concentration in said methanol-rich stream by recycling at least a portion of said methanol-rich stream to said fluid catalytic cracking zone; and (j) recycling any remainder of said alcohol-containing stream to said etherification zone.

Claim 23

A method for fluid catalytic cracking of a hydrocarbon feedstock which method comprises the steps of: (a) contacting said hydrocarbon feedstock with a fluid catalytic cracking catalyst in a fluid catalytic cracking zone under fluid catalytic cracking conditions to produce a fluid catalytic cracking effluent stream comprising isobutene; (b) treating said fluid catalytic cracking effluent stream to remove a substantial amount of any sulfur compounds contained therein; (c) contacting said effluent from step (b) with a selective hydrogenation catalyst at selective hydrogenation conditions in a selective hydrogenation zone to selectively saturate diolefins to monoolefins; (d) contacting said effluent from step (c) with methanol in the presence of an etherification catalyst comprising a macroporous acid-form sulfonic ion exchange resin in an etherification zone under etherification conditions to react said isobutene with said methanol to produce an etherification effluent stream which comprises methyl tertiary butyl ether; (e) passing at least a portion of said etherification effluent stream to a distillation zone containing a bed of etherification catalyst comprising a macroporous acid-form sulfonic ion exchange resin and contacting said methanol in said bed of etherification catalyst in said distillation zone at etherification conditions to produce a methyl tertiary butyl ether-rich stream and an overhead raffinate stream comprising isobutane, normal butene, normal butane, methanol and isobutene; (f) contacting said raffinate stream with a water-containing stream to produce a hydrocarbon-rich raffinate stream and a methanol-containing stream; (g) fractionating said methanol-containing stream to produce a methanol-rich stream; (h) monitoring acetonitrile concentration of said methanol-rich stream; (i) regulating said acetonitrile concentration in said methanol-rich stream by recycling at least a portion of said methanol-rich stream to said fluid catalytic cracking zone; and (j) recycling any remainder of said alcohol-containing stream to said etherification zone.