Production of dyeings by the inkjet printing technique on modified fiber materials using anionic textile dyes

Claim 2

A process for dyeing a sheetlike fiber material with anionic dyes, which comprises applying an alkali-free aqueous solution of the anionic dye by the inkjet printing spray technique to a fiber material which has been pretreated and modified with a compound that contains one or more primary, secondary or tertiary amino groups or quaternary ammonium groups, which amino or ammonium groups are optionally part of a heterocycle.

Claim 3

The process of claim 1, wherein the sheetlike fiber material is made of or containing cellulose fibers.

Claim 4

The process of claim 1, wherein the anionic dye has a fibre-reactive group.

Claim 5

The process of claim 1, wherein the alkali-free solution of the anionic dye is low-electrolyte or completely electrolyte-free.

Claim 6

The process of claim 1, wherein the compound with which the fiber material was pretreated and modified is a compound of the formula (1) or (2) ##STR58## where M is a hydrogen or an alkali metal, k is 1 or 2, R A is hydrogen or alkyl of 1 to 3 carbon atoms which are optionally substituted by hydroxy or a group of the formula (5a) or (5b) ##STR59## where R 1 is hydrogen, methyl or ethyl, R 2 is hydrogen, methyl or ethyl, and R 3 is hydrogen, methyl or ethyl, or R 1 and R 2 together with the nitrogen atom are a saturated heterocyclic radical formed from an alkylene of up to 8 carbon atoms or two alkylenes of 1 to 4 carbon atoms and an oxygen atom or an amino group of the formula --NH--, and Z.sup.(-) is an anion, R B has one of the meanings specified for R A , and X is --O-- or --NH--,

Claim 7

The process of claim 1, wherein the compound with which the fiber material was pretreated and modified is a compound of the formula (3a) or (3b) ##STR60## where ER is an ester group, A and N together with 1 or 2 alkylene groups of 1 to 4 carbon atoms form the bivalent radical of a heterocyclic ring in which A is an oxygen atom or a group of the formula ##STR61## where R is a hydrogen atom, an amino group, an alkyl group of 1 to 6 carbon atoms which may be substituted by 1 or 2 substituents selected from the group consisting of amino, sulfo, hydroxy , sulfato, phosphato and carboxy, or an alkyl group of 3 to 8 carbon atoms which is interrupted by 1 or 2 hereto groups selected from --O-- and --NH-- and are optionally substituted by an amino, sulfo, hydroxy, sulfato or carboxy group, R 3 is hydrogen, methyl or ethyl, R 4 is hydrogen, methyl or ethyl, and Z.sup.(-) is an anion, B is an amino group of the formula H 2 N-- or an amino or ammonium group of the formula (d) or (e) ##STR62## in which R 3 , R 4 and Z.sup.(-) are each as defined above, R 5 is methyl or ethyl, and R 6 is hydrogen, methyl or ethyl, p is 1 or 2, alkylen is a straight-chain or branched alkylene of 2 to 6 carbon atoms which are optionally substituted by 1 or 2 hydroxy groups, or a straight-chain or branched alkylene of 3 to 8 carbon atoms which is interrupted by 1 or 2 hereto groups selected from --O-- and --NH--, alk is a straight-chain or branched alkylene or 2 to 6 carbon atoms or a straight chain or branched alkylene of 3 to 8 carbon atoms which is interrupted by 1 or 2 hetero groups selected from --O-- and --NH--, m is 1 or 2, n is from 1 to 4, and the amino, hydroxy and ester groups can be attached to a primary, secondary or tertiary carbon atom of the alkylene radical.

Claim 8

The process of claim 1, wherein the compound with which the fiber material was pretreated and modified is a compound of the formula (4 ) ##STR63## where R C is hydrogen, alkoxy of 1 to 8 carbon atoms, halogen, hydroxy, alkoxy of 2 to 4 carbon atoms with alkoxy of 1 to 4 carbon atoms as substituent, N-morpholino, N-imidazolino or a group of the formula (6) ##STR64## R D is a group of the formula (7a) or (7b) ##STR65## where a is zero or 1, b is an integer from zero to 10, c is 1 or 2, c=1 being mandatory when a is zero, R 7 has one of the meanings of R C , R 8 is alkoxy of 1 to 8 carbon atoms with or without alkoxy of 1 to 4 carbon atoms as substituent, alkyl of 1 to 8 carbon atoms, alkenyl of 2 to 8 carbon atoms or phenylene-alkyl where the alkyl radical has 1 to 4 carbon atoms and the phenylene radical is optionally substituted by substituents selected from the group consisting of methyl, ethyl, methoxy, ethoxy, sulfo and carboxy, each of which radicals R 8 is optionally additionally substituted by a group T o f the above meaning, R 9 has one of the meanings of R C or R E , D is alkylene of 1 to 6 carbon atoms which may be substituted by hydroxy, methoxy, ethoxy, sulfo, sulfato or carboxy, or is phenylene unsubstituted or substituted by substituents selected from methoxy, ethoxy, methyl, ethyl, sulfo and carboxy, or is phenylenealkylene, alkylenephenylene, alkylenephenylenealkylene, or phenylenealkylene phenylene, in each of which the alkylene group or groups has or have from 1 to 6 carbon atoms and may be substituted by hydroxy, methoxy, ethoxy, sulfo, sulfato, or carboxy and the phenylene radicals are unsubstituted or substituted by substituents selected from methoxy, ethoxy, methyl, ethyl, sulfo and carboxy, X 1 is for c=1 a group of the formula --S--, --O--, --NH-- or --N(R)--, R being alkyl of 1 to 4 carbon atoms, or for c=2 is a nitrogen atom, E is cycloalkylene of 5 to 8 carbon atoms or alkylene of 1 to 6 carbon atoms which may be substituted by hydroxy, methoxy, ethoxy, sulfato, sulfo or carboxy, or is phenylene unsubstituted or substituted by substituents selected from methoxy, ethoxy, methyl, ethyl, sulfo and carboxy, X 2 is a group of the formula --S--, --O--,--NH--or --N(R)-- where R is as defined above, G is alkylene of 1 to 6 carbon atoms which is optionally substituted by hydroxy, methoxy, ethoxy, sulfo, sulfato or carboxy, or is phenylene unsubstituted or substituted by substituents selected from methoxy, ethoxy, methyl, ethyl, sulfo and carboxy, or is phenylenealkylene, alkylenephenylene, alkylenephenylenealkylene or phenylenealkylenephenylene, in each of which the alkyl group or groups has or have from 1 to 6 carbon atoms and is optionally substituted by hydroxy, methoxy, ethoxy, sulfo, sulfato or carboxy and the phenylene radical or radicals are unsubstituted or substituted by substituents selected from methoxy, ethoxy, methyl, ethyl, sulfo and carboxy, or G can be a direct bond if (a+b) is not zero, T is hydroxy, thiol or a group of the formula (8a) or (8b) ##STR66## where R 10 is hydrogen or alkyl of 1 to 4 carbon atoms which is optionally substituted by phenyl, sulfophenyl, amino, thio or hydroxy, R 11 is hydrogen, phenyl, sulfophenyl or alkyl of 1 to 4 carbon atoms which is optionally substituted by phenyl, sulfophenyl, methoxy, ethoxy, amino, thio or hydroxy, R 12 is hydrogen, alkyl of 1 to 4 carbon atoms which is optionally substituted, or alkenyl of 2 to 6 carbon atoms, and Z.sup.(-) is an anion, K is a radical of the formula (9) ##STR67## where G, X 2 , E, X 1 , D, a and b are each as defined above, R E is hydrogen, alkoxy of 1 to 8 carbon atoms with or without alkoxy of 1 to 4 carbon atoms as substituent, halogen, hydroxyl, alkyl of 1 to 8 carbon atoms, alkenyl of 2 to 8 carbon atoms, alkinyl of 3 to 8 carbon atoms or phenyl or a group of the formula (7a) or (7b), R G has one of the meanings mentioned for R c or R E , and at least one of the substituents attached to the silicon atom is a hydrolyzable substituent selected from the group consisting of hydrogen, halogen, alkoxy, phenoxy, amino and amido.

Claim 9

A sheetlike fiber material dyed as claimed in claim 1.