Negative birefringent polyimide films

Claim 2

A non-stretched homopolymer polyimide film, soluble in the imide form, for use in negative birefringence layers in liquid crystal displays, the film having a negative birefringence of 0.001 to 0.2, the film having been prepared from solutions of soluble polyimides of the type having an aromatic dianhydride of general formula (I): ##STR88## and an aromatic diamine of formula (III) ##STR89## wherein each R is a substituent selected independently from the group consisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl of from 1 to 20 carbons; F is selected from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously, and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic ester, and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; and p and q are integers from 1 to 3 and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and wherein the negative birefringence of the film is determined by control of the degree of in-plane orientation of the polyimide by the selection of R, F and A, and the values of n, p and q, which affects the polyimide backbone chain rigidity and linearity, the higher the rigidity and linearity of the polyimide backbone, the larger the value of the negative birefringence of the polyimide film.

Claim 3

The film of claim 1 wherein the aromatic dianhydride is a 3,6-disubstituted pyromelletic dianhydride selected from the group consisting of 3,6-diphenylpyromellitic dianhydride, 3,6-bis(trifluoromethyl)pyromellitic dianhydride, 3,6-bis(methyl)pyromellitic dianhydride, 3,6-diiodopyromellitic dianhydride, 3,6-dibromopyromellitic dianhydride and 3,6-dichloropyromellitic dianhydride.

Claim 4

The film of claim 1 wherein the aromatic diamine is selected from the group consisting of o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 1,4-diamino-2-methoxybenzene, 1,4-diamino-2-phenylbenzene, 1,3-diamino-4-chlorobenzene, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylmethane, 2,2-bis(4-aminophenyl)propane, 2,2-bis(4-aminophenyl)-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 1,3-bis(3-aminophenoxy)benzene, 1,3-bis(4-aminophenoxy)benzene, 1,4-bis(4-aminophenoxy)benzene, 4,4'-bis(4-aminophenoxy)biphenyl, 4,4'-bis(3-aminophenoxy)biphenyl, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl thioether, 4,4'-diaminodiphenyl sulfone, 2,2'-diaminobenzophenone, 3,3'-diaminobenzophenone, 1,8-diaminonaphthalene, 1,5-diminonaphthalene, 2,6-diaminopyridine, 2,4-diaminopyrimidine, 2,4-diamino-s-triazine, 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl, 2,2'-dibromo-4,4'-diaminobiphenyl, 2,2'-dicyano-4,4'-diaminobiphenyl, 2,2'-dichloro-6,6'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dimethyl-4,4'-diaminobiphenyl, 3,3'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dicarboalkoxy-4,4'-diaminobiphenyl and 2,2'-dicarboalkoxy-6,6'-dimethyl-4,4'-diaminobiphenyl.

Claim 5

A non-stretched homopolymer polyimide film, soluble in the imide form, for use in negative birefringence layers in liquid crystal displays, the film having a negative birefringence of 0.001 to 0.2, the film having been prepared from solutions of soluble polyimides of the type having an aromatic dianhydride of general formula (II): ##STR90## and a polyaromatic diamine of formula (III) ##STR91## where F and G are selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group were X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is a substituent selected independently from the group consisting of H, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons, and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; and p and q are integers from 0 to 3 and 1 to 3 respectively, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and wherein the negative birefringence of the film is determined by controlling the degree of in-plane orientation of the polyimide by the selection of G, F, and A, and the values of n, p and q, which affects the polyimide backbone chain rigidity and linearity, the higher the rigidity and linearity of the polyimide backbone, the larger the value of the negative birefringence of the polyimide film.

Claim 6

A non-stretched homopolymer polyimide film, soluble in the imide form, for use in negative birefringence layers in liquid crystal displays, the film having a negative birefringence of 0.001 to 0.2, the film having been prepared from solutions of soluble polyimides of the type having an aromatic dianhydride of general formula (II): ##STR90## and a polyaromatic diamine of formula (III) ##STR91## where F and G are selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group were X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is a substituent selected independently from the group consisting of H, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons, and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; and p and q are integers from 0 to 3 and 1 to 3 respectively, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and wherein the negative birefringence of the film is determined by controlling the degree of in-plane orientation of the polyimide by the selection of G, F, and A, and the values of n, p and q, which affects the polyimide backbone chain rigidity and linearity, the higher the rigidity and linearity of the polyimide backbone, the larger the value of the negative birefringence of the polyimide film.

Claim 7

The film of claim 4 wherein the aromatic dianhydride is selected from the group consisting of 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride, 2,3,3',4'-benzophenonetetracarboxylic acid dianhydride, 2,2',3,3'-benzophenone tetracarboxylic acid dianhydride, 3,3',4,4'-biphenyltetracarboxylic acid dianhydride, bis(2,3-dicarboxyphenyl)methane dianhydride, bis(2,5,6-trifluoro-3,4-dicarboxyphenyl)methane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)propane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride, bis(3,4-dicarboxyphenyl)ether dianhydride, bis(3,4-dicarboxyphenyl)sulfone dianhydride, 4,4'-[4,4'-isopropylidene-di(p-phenyleneoxy)]bis(phthalic anhydride), N,N-(3,4-dicarboxyphenyl)-N-methylamine dianhydride, bis(3,4-dicarboxyphenyl)diethylsilane dianhydride, 2,3,6,7-napthalene-tetracarboxylic acid dianhydride, 1,2,5,6-naphthalene-tetracarboxylic acid dianhydride, 2,6-dichloronaphthalene-1,4,5,8-tetracarboxylic acid dianhydride, thiophene-2,3,4,5-tetracarboxylic acid dianhydride, pyrazine-2,3,5,6-tetracarboxylic acid dianhydride and pyridine-2,3,5,6-tetracarboxylic acid dianhydride.

Claim 8

The film of claim 4 wherein the diamine is selected from the group consisting of o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 1,4-diamino-2-methoxybenzene, 1,4-diamino-2-phenylbenzene, 1,3-diamino-4-chlorobenzene, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylmethane, 2,2-bis(4-aminophenyl)propane, 2,2-bis(4-aminophenyl)-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 1,3-bis(3-aminophenoxy)benzene, 1,3-bis(4-aminophenoxy)benzene, 1,4-bis(4-aminophenoxy)benzene, 4,4'-bis(4-aminophenoxy)biphenyl, 4,4'-bis(3-aminophenoxy)biphenyl, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl thioether, 4,4'-diaminodiphenyl sulfone, 2,2'-diaminobenzophenone, 3,3'-diaminobenzophenone, 1,8-diaminonaphthalene, 1,5-diminonaphthalene, 2,6-diaminopyridine, 2,4-diaminopyrimidine, 2,4-diamino-s-triazine, 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl, 2,2'-dibromo-4,4'-diaminobiphenyl, 2,2'-dicyano-4,4'-diaminobiphenyl, 2,2'-dichloro-6,6'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dimethyl-4,4'-diaminobiphenyl, 3,3'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dicarboalkoxy-4,4'-diaminobiphenyl and 2,2'-dicarboalkoxy-6,6'-dimethyl-4,4'-diaminobiphenyl.

Claim 9

A non-stretched copolyimide film, soluble in the imide form, for use in negative birefringence layers in liquid crystal displays, the film having a negative birefringence of 0.001 to 0.2, the film having been prepared from solutions of soluble polyimides of the type having at least one aromatic dianhydride of general formula (II): ##STR92## and at least one polyaromatic diamine of formula (III) ##STR93## where F and G are substituents selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is a substituent selected from the group consisting of H, phenyl, substituted phenyl, alkyl and substituted alkyl of from 1 to 20 carbons, and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; and p and q are integers from 0 to 3 and 1 to 3 respectively, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; to form a copolyimide of formula (VII) ##STR94## wherein x varies from 100 to 0 while y varies correspondingly from 0 to 100; and wherein the negative birefringence of the film is determined by the control of the degree of in-plane orientation of the copolyimide by the selection of G, F, and A, and the values of n, p, q, x and y, which affects the polyimide backbone chain rigidity and linearity, the higher the rigidity and linearity of the polyimide backbone, the larger the value of the negative birefringence of the polyimide film.

Claim 10

A non-stretched copolyimide film, soluble in the imide form, for use in negative birefringence layers in liquid crystal displays, the film having a negative birefringence of 0.001 to 0.2, the film having been prepared from solutions of soluble polyimides of the type having at least one aromatic dianhydride of general formula (II): ##STR92## and at least one polyaromatic diamine of formula (III) ##STR93## where F and G are substituents selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is a substituent selected from the group consisting of H, phenyl, substituted phenyl, alkyl and substituted alkyl of from 1 to 20 carbons, and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; and p and q are integers from 0 to 3 and 1 to 3 respectively, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; to form a copolyimide of formula (VII) ##STR94## wherein x varies from 100 to 0 while y varies correspondingly from 0 to 100; and wherein the negative birefringence of the film is determined by the control of the degree of in-plane orientation of the copolyimide by the selection of G, F, and A, and the values of n, p, q, x and y, which affects the polyimide backbone chain rigidity and linearity, the higher the rigidity and linearity of the polyimide backbone, the larger the value of the negative birefringence of the polyimide film.

Claim 11

The film of claim 7 wherein the dianhydride is selected from the group consisting of 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride, 2,3,3',4'-benzophenonetetracarboxylic acid dianhydride, 2,2',3,3'-benzophenone tetracarboxylic acid dianhydride, 3,3',4,4'-biphenyltetracarboxylic acid dianhydride, bis(2,3-dicarboxyphenyl)methane dianhydride, bis(2,5,6-trifluoro-3,4-dicarboxyphenyl)methane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)propane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride, bis(3,4-dicarboxyphenyl)ether dianhydride, bis(3,4-dicarboxyphenyl)sulfone dianhydride, 4,4'-[4,4'-isopropylidene-di(p-phenyleneoxy)]bis(phthalic anhydride), N,N-(3,4-dicarboxyphenyl)-N-methylamine dianhydride, bis(3,4-dicarboxyphenyl)diethylsilane dianhydride, 2,3,6,7-napthalene-tetracarboxylic acid dianhydride, 1,2,5,6-naphthalene-tetracarboxylic acid dianhydride, 2,6-dichloronaphthalene-1,4,5,8-tetracarboxylic acid dianhydride, thiophene-2,3,4,5-tetracarboxylic acid dianhydride, pyrazine-2,3,5,6-tetracarboxylic acid dianhydride and pyridine-2,3,5,6-tetracarboxylic acid dianhydride.

Claim 12

The film of claim 7 wherein the diamine is selected from the group consisting of o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 1,4-diamino-2-methoxybenzene, 1,4-diamino-2-phenylbenzene, 1,3-diamino-4-chlorobenzene, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylmethane, 2,2-bis(4-aminophenyl)propane, 2,2-bis(4-aminophenyl)-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 1,3-bis(3-aminophenoxy)benzene, 1,3-bis(4-aminophenoxy)benzene, 1,4-bis(4-aminophenoxy)benzene, 4,4'-bis(4-aminophenoxy)biphenyl, 4,4'-bis(3-aminophenoxy)biphenyl, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-( 4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl thioether, 4,4'-diaminodiphenyl sulfone, 2,2'-diaminobenzophenone, 3,3'-diaminobenzophenone, 1,8-diaminonaphthalene, 1,5-diminonaphthalene, 2,6-diaminopyridine, 2,4-diaminopyrimidine, 2,4-diamino-s-triazine, 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl, 2,2'-dibromo-4,4'-diaminobiphenyl, 2,2'-dicyano-4,4'-diaminobiphenyl, 2,2'-dichloro-6,6'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dimethyl-4,4'-diaminobiphenyl, 3,3'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dicarboalkoxy-4,4'-diaminobiphenyl and 2,2'-dicarboalkoxy-6,6'-dimethyl-4,4'-diaminobiphenyl.

Claim 13

A non-stretched copolyimide film, soluble in the imide form, for use in negative birefringence layers in liquid crystal displays, the film having a negative birefringence of 0.001 to 0.2, the film having been prepared from solutions of soluble polyimides of the type having at least one aromatic dianhydride of general formula (I): ##STR95## and at least one polyaromatic diamine of formula (III) ##STR96## where each R is a substituent selected independently from the group consisting of H, phenyl, substituted phenyl, alkyl and substituted alkyl of from 1 to 20 carbons; F is a substituent selected from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; and p and q are integers from 1 to 3, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; to form a copolyimide of formula (VI) ##STR97## wherein x varies from 100 to 0 while y varies correspondingly from 0 to 100; and wherein the negative birefringence of the film is determined by the control of the degree of in-plane orientation of the polyimide by the selection of R, F and A, and the values of n, p, q, x and y, which affects the polyimide backbone chain rigidity and linearity, the higher the rigidity and linearity of the polyimide backbone, the larger the value of the negative birefringence of the polyimide film.

Claim 14

A non-stretched copolyimide film, soluble in the imide form, for use in negative birefringence layers in liquid crystal displays, the film having a negative birefringence of 0.001 to 0.2, the film having been prepared from solutions of soluble polyimides of the type having at least one aromatic dianhydride of general formula (I): ##STR95## and at least one polyaromatic diamine of formula (III) ##STR96## where each R is a substituent selected independently from the group consisting of H, phenyl, substituted phenyl, alkyl and substituted alkyl of from 1 to 20 carbons; F is a substituent selected from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; and p and q are integers from 1 to 3, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; to form a copolyimide of formula (VI) ##STR97## wherein x varies from 100 to 0 while y varies correspondingly from 0 to 100; and wherein the negative birefringence of the film is determined by the control of the degree of in-plane orientation of the polyimide by the selection of R, F and A, and the values of n, p, q, x and y, which affects the polyimide backbone chain rigidity and linearity, the higher the rigidity and linearity of the polyimide backbone, the larger the value of the negative birefringence of the polyimide film.

Claim 15

The film of claim 10 wherein the aromatic dianhydride is selected from the group consisting of pyromellitic dianhydride, 3,6-diphenylpyromellitic dianhydride, 3,6-bis(trifluoromethyl)pyromellitic dianhydride, 3,6-bis(methyl)pyromellitic dianhydride, 3,6-diiodopyromellitic dianhydride, 3,6-dibromopyromellitic dianhydride and 3,6-dichloropyromellitic dianhydride.

Claim 16

The film of claim 10 wherein the aromatic diamine is selected from the group consisting of o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 1,4-diamino-2-methoxybenzene, 1,4-diamino-2-phenylbenzene, 1,3-diamino-4-chlorobenzene, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylmethane, 2,2-bis(4-aminophenyl)propane, 2,2-bis(4-aminophenyl)-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 1,3-bis(3-aminophenoxy)benzene, 1,3-bis(4-aminophenoxy)benzene, 1,4-bis(4-aminophenoxy)benzene, 4,4'-bis(4-aminophenoxy)biphenyl, 4,4'-bis(3-aminophenoxy)biphenyl, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl thioether, 4,4'-diaminodiphenyl sulfone, 2,2'-diaminobenzophenone, 3,3'-diaminobenzophenone, 1,8-diaminonaphthalene, 1,5-diminonaphthalene, 2,6-diaminopyridine, 2,4-diaminopyridine, 2,4-diamino-s-triazine, 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl, 2,2'-dibromo-4,4'-diaminobiphenyl, 2,2'-dicyano-4,4'-diaminobiphenyl, 2,2'-dichloro-6,6'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dimethyl-4,4'-diaminobiphenyl, 3,3'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dicarboalkoxy-4,4'-diaminobiphenyl and 2,2'-dicarboalkoxy-6,6'-dimethyl-4,4'-diaminobiphenyl.

Claim 17

A non-stretched copolyimide film, soluble in the imide form for use in negative birefringence layers in liquid crystal displays, the film having a negative birefringence of 0.001 to 0.2, the film having been prepared from solutions of soluble polyimides of the type having at least one first aromatic dianhydride of general formula (I) ##STR98## and at least one second aromatic dianhydride of formula (II) ##STR99## and at least one polyaromatic diamine of formula (III) ##STR100## where each R is a substituent selected independently from the group consisting of H, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; F and G are substituents selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic ester and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; and p and q are integers from 0 to 3 and 1 to 3 respectively, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; to form a copolyimide of formula (VIII) ##STR101## wherein x varies from 100 to 0 while y varies correspondingly from 0 to 100; and wherein the negative birefringence of the film is determined by the control of the degree of in-plane orientation of the polyimide by the section of R, G, F, and A, and the values of n, p, q, x and y, which affects the polyimide backbone chain rigidity and linearity, the higher the rigidity and linearity of the polyimide backbone, the larger the value of the negative birefringence of the polyimide film.

Claim 18

A non-stretched copolyimide film, soluble in the imide form for use in negative birefringence layers in liquid crystal displays, the film having a negative birefringence of 0.001 to 0.2, the film having been prepared from solutions of soluble polyimides of the type having at least one first aromatic dianhydride of general formula (I) ##STR98## and at least one second aromatic dianhydride of formula (II) ##STR99## and at least one polyaromatic diamine of formula (III) ##STR100## where each R is a substituent selected independently from the group consisting of H, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; F and G are substituents selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic ester and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; and p and q are integers from 0 to 3 and 1 to 3 respectively, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; to form a copolyimide of formula (VIII) ##STR101## wherein x varies from 100 to 0 while y varies correspondingly from 0 to 100; and wherein the negative birefringence of the film is determined by the control of the degree of in-plane orientation of the polyimide by the section of R, G, F, and A, and the values of n, p, q, x and y, which affects the polyimide backbone chain rigidity and linearity, the higher the rigidity and linearity of the polyimide backbone, the larger the value of the negative birefringence of the polyimide film.

Claim 19

The film of claim 13 wherein the dianhydride is selected from the group consisting of pyromelletic dianhydride, 3,6-diphenylpyromellitic dianhydride, 3,6-bis(trifluoromethyl)pyromellitic dianhydride, 3,6-bis(methyl)pyromellitic dianhydride, 3,6-diiodopyromellitic dianhydride, 3,6-dibromopyromellitic dianhydride and 3,6-dichloropyromellitic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride, 2,3,3',4'-benzophenonetetracarboxylic acid dianhydride, 2,2',3,3'-benzophenone tetracarboxylic acid dianhydride, 3,3',4,4'-biphenyltetracarboxylic acid dianhydride, bis(2,3-dicarboxyphenyl)methane dianhydride, bis(2,5,6-trifluoro-3,4-dicarboxyphenyl)methane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)propane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride, bis(3,4-dicarboxyphenyl)ether dianhydride, bis(3,4-dicarboxyphenyl)sulfone dianhydride, 4,4'-[4,4'-isopropylidene-di(p-phenyleneoxy)]bis(phthalic anhydride), N,N-(3,4-dicarboxyphenyl)-N-methylamine dianhydride, bis(3,4-dicarboxyphenyl)diethylsilane dianhydride, 2,3,6,7-napthalene-tetracarboxylic acid dianhydride, 1,2,5,6-naphthalene-tetracarboxylic acid dianhydride, 2,6-dichloronaphthalene-1,4,5,8-tetracarboxylic acid dianhydride, thiophene-2,3,4,5-tetracarboxylic acid dianhydride, pyrazine-2,3,5,6-tetracarboxylic acid dianhydride and pyridine-2,3,5,6-tetracarboxylic acid dianhydride.

Claim 20

The film of claim 13 wherein the diamine is selected from the group consisting of o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 1,4-diamino-2-methoxybenzene, 1,4-diamino-2-phenylbenzene, 1,3-diamino-4-chlorobenzene, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylmethane, 2,2-bis(4-aminophenyl)propane, 2,2-bis(4-aminophenyl)-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 1,3-bis(3-aminophenoxy)benzene, 1,3-bis(4-aminophenoxy)benzene, 1,4-bis(4-aminophenoxy)benzene, 4,4'-bis(4-aminophenoxy)biphenyl, 4,4'-bis(3-aminophenoxy)biphenyl, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl thioether, 4,4'-diaminodiphenyl sulfone, 2,2'-diaminobenzophenone, 3,3'-diaminobenzophenone, 1,8-diaminonaphthalene, 1,5-diminonaphthalene, 2,6-diaminopyridine, 2,4-diaminopyrimidine, 2,4-diamino-s-triazine, 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl, 2,2'-dibromo-4,4'-diaminobiphenyl, 2,2'-dicyano-4,4'-diaminobiphenyl, 2,2'-dichloro-6,6'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dimethyl-4,4'-diaminobiphenyl, 3,3'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dicarboalkoxy-4,4'-diaminobiphenyl and 2,2'-dicarboalkoxy-6,6'-dimethyl-4,4'-diaminobiphenyl.

Claim 21

An improved liquid crystal display of the type having a liquid crystal element, at least two light-transmissive birefringent films, at least one film having a positive birefringence and at least one other film having a negative birefringence, and a polarizing sheet arranged such that the films are held between the liquid crystal elements and the polarizing sheet, wherein the improvement comprises at least one non-stretched negative polyimide thin film, soluble in the imide form, having a negative birefringence, the polyimide film being selected from the group consisting of (a) an organic solvent soluble homopolyimide film, the homopolyimide being selected from the group consisting of formulas (i) and (ii), and ##STR102## (b) an organic solvent soluble copolyimide film, the copolyimide being selected from the group consisting of formulas (i), (ii) and (iii). ##STR103## where each R is a substituent selected independently from the group consisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; E and F are selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; p and q are integers from 1 to 3 when the polyimide is a homopolyimide and are integers from 0 to 3 and 1 to 3 respectively when the polyimide is a copolyimide, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and x, if present varies from 100 to 0 while y, if present, varies correspondingly from 0 to 100.

Claim 22

An improved liquid crystal display of the type having a liquid crystal element, at least two light-transmissive birefringent films, at least one film having a positive birefringence and at least one other film having a negative birefringence, and a polarizing sheet arranged such that the films are held between the liquid crystal elements and the polarizing sheet, wherein the improvement comprises at least one non-stretched negative polyimide thin film, soluble in the imide form, having a negative birefringence, the polyimide film being selected from the group consisting of (a) an organic solvent soluble homopolyimide film, the homopolyimide being selected from the group consisting of formulas (i) and (ii), and ##STR102## (b) an organic solvent soluble copolyimide film, the copolyimide being selected from the group consisting of formulas (i), (ii) and (iii). ##STR103## where each R is a substituent selected independently from the group consisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; E and F are selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; p and q are integers from 1 to 3 when the polyimide is a homopolyimide and are integers from 0 to 3 and 1 to 3 respectively when the polyimide is a copolyimide, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and x, if present varies from 100 to 0 while y, if present, varies correspondingly from 0 to 100.

Claim 23

The film of claim 16 wherein the dianhydride is selected from the group consisting of pyromelletic dianhydride, 3,6-diphenylpyromellitic dianhydride, 3,6-bis(trifluoromethyl)pyromellitic dianhydride, 3,6-bis(methyl)pyromellitic dianhydride, 3,6-diiodopyromellitic dianhydride, 3,6-dibromopyromellitic dianhydride and 3,6-dichloropyromellitic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride, 2,3,3',4'-benzophenonetetracarboxylic acid dianhydride, 2,2',3,3'-benzophenone tetracarboxylic acid dianhydride, 3,3',4,4'-biphenyltetracarboxylic acid dianhydride, bis(2,3-dicarboxyphenyl)methane dianhydride, bis(2,5,6-trifluoro-3,4-dicarboxyphenyl)methane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)propane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride, bis(3,4-dicarboxyphenyl)ether dianhydride, bis(3,4-dicarboxyphenyl)sulfone dianhydride, 4,4'-[4,4'-isopropylidene-di(p-phenyleneoxy)]bis(phthalic anhydride), N,N-(3,4-dicarboxyphenyl)-N-methylamine dianhydride, bis(3,4-dicarboxyphenyl)diethylsilane dianhydride, 2,3,6,7-napthalene-tetracarboxylic acid dianhydride, 1,2,5,6-naphthalene-tetracarboxylic acid dianhydride, 2,6-dichloronaphthalene-1,4,5,8-tetracarboxylic acid dianhydride, thiophene-2,3,4,5-tetracarboxylic acid dianhydride, pyrazine-2,3,5,6-tetracarboxylic acid dianhydride and pyridine-2,3,5,6-tetracarboxylic acid dianhydride.

Claim 24

The film of claim 16 wherein the diamine is selected from the group consisting of o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 1,4-diamino-2-methoxybenzene, 1,4-diamino-2-phenylbenzene, 1,3-diamino-4-chlorobenzene, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylmethane, 2,2'-bis(4-aminophenyl)propane, 2,2-bis(4-aminophenyl)-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 1,3-bis(3-aminophenoxy)benzene, 1,3-bis(4-aminophenoxy)benzene, 1,4-bis(4-aminophenoxy)benzene, 4,4'-bis(4-aminophenoxy)biphenyl, 4,4'-bis(3-aminophenoxy)biphenyl, 2,2'-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl thioether, 4,4'-diaminodiphenyl sulfone, 2,2'-diaminobenzophenone, 3,3'-diaminobenzophenone, 1,8-diaminonaphthalene, 1,5-diminonaphthalene, 2,6-diaminopyridine, 2,4-diaminopyrimidine, 2,4-diamino-s-triazine, 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl, 2,2'-dibromo-4,4'-diaminobiphenyl, 2,2'-dicyano-4,4'-diaminobiphenyl, 2,2'-dichloro-6,6'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dimethyl-4,4'-diaminobiphenyl, 3,3'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dicarboalkoxy-4,4'-diaminobiphenyl and 2,2'-dicarboalkoxy-6,6'-dimethyl-4,4'-diaminobiphenyl.

Claim 25

An improved liquid crystal display having a polarizer layer, an analyzer layer, a liquid crystal layer disposed between the polarizer layer and the analyzer layer, a first electrode proximate to a first major surface of the liquid crystal layer, a second electrode proximate to a second major surface of the liquid crystal layer, the first and second electrodes being adapted to apply a voltage across the liquid crystal layer when the electrodes are connected to a source of electrical potential, and a multilayer thin film compensator disposed between the polarizer layer and the analyzer layer, including a first plurality of layers, each having a first refractive index and a first thickness, alternating with a second plurality of layers, each having a second refractive index and a second thickness, the values of the first and second refractive indices and thicknesses being such that the phase retardation of the multilayer is equal in magnitude but opposite in sign to the phase retardation of the liquid crystal layer in its homeotropically aligned state over a predetermined range of viewing angles, wherein the improvement comprises at least one non-stretched negative polyimide thin film, soluble in the imide form, within the compensator having a negative birefringence, the polyimide film being selected from the group consisting of (a) an organic solvent soluble homopolyimide film, the homopolyimide being selected from the group consisting of formulas (i) and (ii), and ##STR104## (b) an organic solvent soluble copolyimide film, the copolyimide being selected from the group consisting of formulas (i), (ii) and (iii). ##STR105## where each R is a substituent selected independently from the group consisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; F and G are independently selected from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; p and q are integers from 1 to 3 when the polyimide is a homopolyimide and are integers from 0 to 3 and 1 to 3 respectively when the polyimide is a copolyimide, and wherein when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and x, if present, varies from 100 to 0 while y, if present, varies correspondingly from 0 to 100.

Claim 26

An improved liquid crystal display having a polarizer layer, an analyzer layer, a liquid crystal layer disposed between the polarizer layer and the analyzer layer, a first electrode proximate to a first major surface of the liquid crystal layer, a second electrode proximate to a second major surface of the liquid crystal layer, the first and second electrodes being adapted to apply a voltage across the liquid crystal layer when the electrodes are connected to a source of electrical potential, and a multilayer thin film compensator disposed between the polarizer layer and the analyzer layer, including a first plurality of layers, each having a first refractive index and a first thickness, alternating with a second plurality of layers, each having a second refractive index and a second thickness, the values of the first and second refractive indices and thicknesses being such that the phase retardation of the multilayer is equal in magnitude but opposite in sign to the phase retardation of the liquid crystal layer in its homeotropically aligned state over a predetermined range of viewing angles, wherein the improvement comprises at least one non-stretched negative polyimide thin film, soluble in the imide form, within the compensator having a negative birefringence, the polyimide film being selected from the group consisting of (a) an organic solvent soluble homopolyimide film, the homopolyimide being selected from the group consisting of formulas (i) and (ii), and ##STR104## (b) an organic solvent soluble copolyimide film, the copolyimide being selected from the group consisting of formulas (i), (ii) and (iii). ##STR105## where each R is a substituent selected independently from the group consisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; F and G are independently selected from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; p and q are integers from 1 to 3 when the polyimide is a homopolyimide and are integers from 0 to 3 and 1 to 3 respectively when the polyimide is a copolyimide, and wherein when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and x, if present, varies from 100 to 0 while y, if present, varies correspondingly from 0 to 100.

Claim 27

An improved compensator for use in a liquid crystal display having at least one negative birefringent film layer and at least one positive birefringent film layer, wherein the improvement comprises the inclusion of at least one non-stretched negative polyimide thin film soluble in the imide form, the polyimide film being selected from the group consisting of (a) an organic soluble homopolyimide film, the homopolyimide being selected from the group consisting of formulas (i) and (ii), and ##STR106## (b) an organic solvent soluble copolyimide film, the copolyimide being selected from the group consisting of formulas (i), (ii) and (iii). ##STR107## where each R is a substituent selected independently from the group consisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; E and F are selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; p and q are integers from 1 to 3 when the polyimide is a homopolyimide and are integers from 0 to 3 and 1 to 3 respectively when the polyimide is a copolyimide, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl group is F; and x, if present, varies from 100 to 0 while y, if present, varies correspondingly from 0 to 100.

Claim 28

An improved compensator for use in a liquid crystal display having at least one negative birefringent film layer and at least one positive birefringent film layer, wherein the improvement comprises the inclusion of at least one non-stretched negative polyimide thin film soluble in the imide form, the polyimide film being selected from the group consisting of (a) an organic soluble homopolyimide film, the homopolyimide being selected from the group consisting of formulas (i) and (ii), and ##STR106## (b) an organic solvent soluble copolyimide film, the copolyimide being selected from the group consisting of formulas (i), (ii) and (iii). ##STR107## where each R is a substituent selected independently from the group consisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; E and F are selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; p and q are integers from 1 to 3 when the polyimide is a homopolyimide and are integers from 0 to 3 and 1 to 3 respectively when the polyimide is a copolyimide, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl group is F; and x, if present, varies from 100 to 0 while y, if present, varies correspondingly from 0 to 100.

Claim 29

An improved liquid crystal display comprising a liquid crystal element, at least two birefringent films and a polarizing sheet arranged that said films are held between said liquid crystal element and said polarizing sheet, characterized in that said birefringent films are composed of at least one polymer having a positive intrinsic birefringence and light transmission properties and at least one film having negative intrinsic birefringence and light transmission properties, wherein the improvement comprises at least one non-stretched polyimide film, soluble in the imide form, having a negative birefringence, the polyimide film being selected from the group consisting of: (a) an organic solvent soluble homopolyimide film, the homopolyimide being selected from the group consisting of formulas (i) and (ii), and ##STR108## (b) an organic solvent soluble copolyimide film, the copolyimide being selected from the group consisting of formulas (i), (ii) and (iii). ##STR109## where each R is a substituent selected independently from the group cocsisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; E and F are selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; p and q are integers from 1 to 3 when the polyimide is a homopolyimide and are integers from 0 to 3 and 1 to 3 respectively when the polyimide is a copolyimide, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and x, if present, varies from 100 to 0 while y, if present, varies correspondingly from 0 to 100.

Claim 30

An improved liquid crystal display comprising a liquid crystal element, at least two birefringent films and a polarizing sheet arranged that said films are held between said liquid crystal element and said polarizing sheet, characterized in that said birefringent films are composed of at least one polymer having a positive intrinsic birefringence and light transmission properties and at least one film having negative intrinsic birefringence and light transmission properties, wherein the improvement comprises at least one non-stretched polyimide film, soluble in the imide form, having a negative birefringence, the polyimide film being selected from the group consisting of: (a) an organic solvent soluble homopolyimide film, the homopolyimide being selected from the group consisting of formulas (i) and (ii), and ##STR108## (b) an organic solvent soluble copolyimide film, the copolyimide being selected from the group consisting of formulas (i), (ii) and (iii). ##STR109## where each R is a substituent selected independently from the group cocsisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; E and F are selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; p and q are integers from 1 to 3 when the polyimide is a homopolyimide and are integers from 0 to 3 and 1 to 3 respectively when the polyimide is a copolyimide, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and x, if present, varies from 100 to 0 while y, if present, varies correspondingly from 0 to 100.

Claim 31

The display of claim 21 wherein the dianhydride is selected from the group consisting of pyromellitic dianhydride, 3,6-diphenylpyromellitic dianhydride, 3,6-bis(trifluoromethyl)pyromellitic dianhydride, 3,6-bis(methyl)pyromellitic dianhydride, 3,6-diiodopyromellitic dianhydride, 3,6-dibromopyromellitic dianhydride and 3,6-dichloropyromellitic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride, 2,3,3',4'-benzophenonetetracarboxylic acid dianhydride, 2,2',3,3'-benzophenone tetracarboxylic acid dianhydride, 3,3',4,4'-biphenyltetracarboxylic acid dianhydride, bis(2,3-dicarboxyphenyl)methane dianhydride, bis(2,5,6-trifluoro-3,4-dicarboxyphenyl)methane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)propane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride, bis(3,4-dicarboxyphenyl)ether dianhydride, bis(3,4-dicarboxyphenyl)sulfone dianhydride, 4,4'-[4,4'-idopropylidene-di(p-phenyleneoxy)]bis(phthalic anhydride), N,N-(3,4-dicarboxyphenyl)-N-methylamine dianhydride, bis(3,4-dicarboxyphenyl)diethylsilane dianhydride, 2,3,6,7-naphthalene-tetracarboxylic acid dianhydride, 1,2,5,6-naphthalene-tetracarboxylic acid dianhydride, 2,6-dichloronaphthalene-1,4,5,8-tetracarboxylic acid dianhydride, thiophene-2,3,4,5-tetracarboxylic acid dianhydride, pyrazine-2,3,5,6-tetracarboxylic acid dianhydride and pyridine-2,3,5,6-tetracarboxylic acid dianhydride.

Claim 32

The display of claim 21 wherein the diamine is selected from the group consisting of o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 1,4-diamino-2-methoxybenzene, 1,4-diamino-2-phenylbenzene, 1,3-diamino-4-chlorobenzene, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylmethane, 2,2-bis(4-aminophenyl)propane, 2,2-bis(4-aminophenyl)-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 1,3-bis(3-aminophenoxy)benzene, 1,3-bis(4-aminophenoxy)benzene, 1,4-bis(4-aminophenoxy)benzene, 4,4'-bis(4-aminophenoxy)biphenyl, 4,4'-(bis(3-aminophenoxy)biphenyl, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl thioether, 4,4'-diaminodiphenyl sulfone, 2,2'-diaminobenzophenone, 3,3'-diaminobenzophenone, 1,8-diaminonaphthalene, 1,5-diaminonaphthalene, 2,6-diaminopyridine, 2,4-diaminopyrimidine, 2,4-diamino-s-triazine, 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl, 2,2'-dibromo-4,4'-diaminobiphenyl, 2,2'-dicyano-4,4'-diaminobiphenyl, 2,2'-dichloro-6,6'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dimethyl-4,4'-diaminobiphenyl, 3,3'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dicarboalkoxy-4,4'-diaminobiphenyl and 2,2'-dicarboalkoxy-6,6'-dimethyl-4,4'-diaminobiphenyl.

Claim 33

An improved liquid crystal display of the type having a liquid crystal element, at least two light-transmissive birefringent coatings, at least one coating having a positive birefringence and at least one other coating having a negative birefringence, and a polarizing sheet arranged such that the coatings are held between the liquid crystal elements and the polarizing sheet, wherein the improvement comprises at least one non-stretched negative polyimide coating, soluble in the imide form, having a negative birefringence, the polyimide coating being selected from the group consisting of (a) an organic solvent soluble homopolyimide coating, the homopolyimide being selected from the group consisting of formulas (i) and (ii), and ##STR110## (b) an organic solvent soluble copolyimide coating, the copolyimide being selected from the group consisting of formulas (i), (ii) and (iii). ##STR111## where each R is a substituent selected independently from the group consisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; E and F are selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; p and q are integers from 1 to 3 when the polyimide is a homopolyimide and are integers from 0 to 3 and 1 to 3 respectively when the polyimide is a copolyimide, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and x, if present, varies from 100 to 0 while y, if present, varies correspondingly from 0 to 100.

Claim 34

An improved liquid crystal display of the type having a liquid crystal element, at least two light-transmissive birefringent coatings, at least one coating having a positive birefringence and at least one other coating having a negative birefringence, and a polarizing sheet arranged such that the coatings are held between the liquid crystal elements and the polarizing sheet, wherein the improvement comprises at least one non-stretched negative polyimide coating, soluble in the imide form, having a negative birefringence, the polyimide coating being selected from the group consisting of (a) an organic solvent soluble homopolyimide coating, the homopolyimide being selected from the group consisting of formulas (i) and (ii), and ##STR110## (b) an organic solvent soluble copolyimide coating, the copolyimide being selected from the group consisting of formulas (i), (ii) and (iii). ##STR111## where each R is a substituent selected independently from the group consisting of H, halogen, phenyl, substituted phenyl, alkyl and substituted alkyl from 1 to 20 carbons; E and F are selected independently from the group consisting of a covalent bond, a CH 2 group, a C(CH 3 ) 2 group, a C(CX 3 ) 2 group wherein X is a halogen, a CO group, an O atom, a S atom, a SO 2 group, a Si(R) 2 group wherein R is as defined previously and a N(R) group wherein R is as defined previously; A is selected from the group consisting of hydrogen, halogen, alkyl, substituted alkyl, nitro, cyano, thioalkyl, alkoxy, substituted alkoxy, aryl and substituted aryl, aliphatic and aromatic esters and combinations thereof from 1 to 20 carbons; n is an integer from 0 to 4; p and q are integers from 1 to 3 when the polyimide is a homopolyimide and are integers from 0 to 3 and 1 to 3 respectively when the polyimide is a copolyimide, and when p and q are greater than 1, the linking group between benzyl or substituted benzyl groups is F; and x, if present, varies from 100 to 0 while y, if present, varies correspondingly from 0 to 100.

Claim 35

The coating of claim 24 wherein the dianhydride is selected from the group consisting of pyromelletic dianhydride, 3,6-diphenylpyromellitic dianhydride, 3,6-bis(trifluoromethyl)pyromellitic dianhydride, 3,6-bis(methyl)pyromellitic dianhydride, 3,6-diiodopyromellitic dianhydride, 3,6-dibromopyromellitic dianhydride, and 3,6-dichloropyromellitic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride, 2,3,3',4'-benzophenonetetracarboxylic acid dianhydride, 2,2',3,3'-benzophenone tetracarboxylic acid dianhydride, 3,3',4,4'-biphenyltetracarboxylic acid dianhydride, bis(2,3-dicarboxyphenyl)methane dianhydride, bis(2,5,6-trifluoro-3,4-dicarboxyphenyl)methane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)propane dianhydride, 2,2-bis(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride, bis(3,4-dicarboxyphenyl)ether dianhydride, bis(3,4-dicarboxyphenyl)sulfone dianhydride, 4,4'-[4,4'-idopropylidene-di(p-phenyleneoxy)]bis(phthalic anhydride), N,N-(3,4-dicarboxyphenyl)-N-methylamine dianhydride, bis(3,4-dicarboxyphenyl)diethylsilane dianhydride, 2,3,6,7-naphthalene-tetracarboxylic acid dianhydride, 1,2,5,6-naphthalene-tetracarboxylic acid dianhydride, 2,6-dichloronaphthalene-1,4,5,8-tetracarboxylic acid dianhydride, thiophene-2,3,4,5-tetracarboxylic acid dianhydride, pyrazine-2,3,5,6-tetracarboxylic acid dianhydride and pyridine-2,3,5,6-tetracarboxylic acid dianhydride.

Claim 36

The coating of claim 24 wherein the diamine is selected from the group consisting of o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 1,4-diamino-2-methoxybenzene, 1,4-diamino-2-phenylbenzene, 1,3-diamino-4-chlorobenzene, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylmethane, 2,2-bis(4-aminophenyl)propane, 2,2-bis(4-aminophenyl)-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 1,3-bis(3-aminophenoxy)benzene, 1,3-bis(4-aminophenoxy)benzene, 1,4-bis(4-aminophenoxy)benzene, 4,4'-bis(4-aminophenoxy)biphenyl, 4,4'-bis(3-aminophenoxy)biphenyl, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane, 4,4'-diaminodiphenyl thioether, 4,4'-diaminodiphenyl sulfone, 2,2'-diaminobenzophenone, 3,3'-diaminobenzophenone, 1,8-diaminonaphthalene, 1,5-diminonaphthalene, 2,6-diaminopyridine, 2,4-diaminopyrimidine, 2,4-diamino-s-triazine, 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl, 2,2'-dibromo-4,4'-diaminobiphenyl, 2,2'-dicyano-4,4'-diaminobiphenyl, 2,2'-dichloro-6,6'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dimethyl-4,4'-diaminobiphenyl, 3,3'-dimethyl-4,4'-diaminobiphenyl, 2,2'-dicarboalkoxy-4,4'-diaminobiphenyl and 2,2'-dicarboalkoxy-6,6'-dimethyl-4,4'-diaminobiphenyl.