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US5325219A Expired / Lapsed US ⏱️ 0.0 years remaining

Chiral smectic liquid crystal device having polyimide alignment layer with fluoroalkyl side chain

Assignee: Canon Inc
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Filing: 1992-10-29
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Granted: 1994-06-28
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Expires: 2012-10-29
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Abstract

Abstract A liquid crystal device improved in contrast and freeness from flickering and after image is formed by disposing a liquid crystal between a pair of substrates, at least one of which has an alignment film of a polyimide having a fluoroalkyl chain group as a side chain. The fluoroalkyl chain group may be contained in a diamine-originated moiety or a carboxylic acid-originated moiety of the polyimide.

Inventors

  • 👤 Yukio Hanyu
  • 👤 Masanobu Asaoka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 12:19
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/01; G02F1/13; G02F1/133; G02F1/1333; G02F1/1337; G02F1/133711; G02F1/133723; C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1039; C09; C09K; C09K2323/00; C09K2323/02; C09K2323/027; C09K2323/0271

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 109 words
A liquid crystal device, comprising: a pair of substrates, each of said substrates being provided with a transparent electrode, and a chiral smectic liquid crystal disposed between the substrates; wherein said substrates each have thereon an alignment film comprising a polyimide having as a side chain a fluoroalkyl chain group according to the formula ##STR24## wherein m in an integer of 3-10, and n is 0 or an integer of 1-4, and wherein both alignment films are provided with a uniaxial alignment axis in direction which are generally the same and are (i) parallel to each other or (ii) cross each other at an intersection angle of 2-15 degrees.
Claim 2
Dependent Claim 109 words
A liquid crystal device, comprising: a pair of substrates, each of said substrates being provided with a transparent electrode, and a chiral smectic liquid crystal disposed between the substrates; wherein said substrates each have thereon an alignment film comprising a polyimide having as a side chain a fluoroalkyl chain group according to the formula ##STR24## wherein m in an integer of 3-10, and n is 0 or an integer of 1-4, and wherein both alignment films are provided with a uniaxial alignment axis in direction which are generally the same and are (i) parallel to each other or (ii) cross each other at an intersection angle of 2-15 degrees.
Claim 3
Dependent Claim 35 words
A device according to claim 1, wherein the chiral smectic liquid crystal is disposed in a texture comprising a plurality of bent smectic layers of similar shape each comprising a plurality of liquid crystal molecules.
Claim 4
Dependent Claim 15 words
A device according to claim 1, wherein said uniaxial alignment axis is a rubbing axis.
Claim 5
Dependent Claim 108 words
A liquid crystal device, comprising: a pair of substrates, each of said substrates being provided with a transparent electrode, and a chiral smectic liquid crystal disposed between the substrates; wherein said substrates each have thereon an alignment film comprising a polyimide having as a side chain a fluoroalkyl chain group according to the formula ##STR25## wherein m in an integer of 3-10, and n is 0 or an integer of 1-4, and wherein both alignment films are provided with a uniaxial alignment axis in directions which are generally opposite and are (i) parallel to each other or (ii) cross each other at an intersection angle of 2-15 degrees.
Claim 6
Dependent Claim 108 words
A liquid crystal device, comprising: a pair of substrates, each of said substrates being provided with a transparent electrode, and a chiral smectic liquid crystal disposed between the substrates; wherein said substrates each have thereon an alignment film comprising a polyimide having as a side chain a fluoroalkyl chain group according to the formula ##STR25## wherein m in an integer of 3-10, and n is 0 or an integer of 1-4, and wherein both alignment films are provided with a uniaxial alignment axis in directions which are generally opposite and are (i) parallel to each other or (ii) cross each other at an intersection angle of 2-15 degrees.
Claim 7
Dependent Claim 35 words
A device according to claim 4, wherein the chiral smectic liquid crystal is disposed in a texture comprising a plurality of inclined smectic layers of similar shape each comprising a plurality of liquid crystal molecules.
Claim 8
Dependent Claim 15 words
A device according to claim 4, wherein said uniaxial alignment axis is a rubbing axis.
Claim 9
Dependent Claim 118 words
A liquid crystal device, comprising: a pair of substrates, each of said substrates being provided with a transparent electrode, and a chiral smectic liquid crystal disposed between the substrates; wherein said pair of substrates each have thereon an alignment film comprising a polyamideimide having a fluoroalkyl chain group as a side chain, and both alignment films are provided with a uniaxial alignment axis in directions which are generally opposite and are (i) parallel to each other or (ii) cross each other at an intersection angle of 2-15 degrees, and wherein the chiral smectic liquid crystal is disposed in a texture comprising a plurality of bent smectic layers of similar shape each comprising a plurality of liquid crystal molecules.
Claim 10
Dependent Claim 118 words
A liquid crystal device, comprising: a pair of substrates, each of said substrates being provided with a transparent electrode, and a chiral smectic liquid crystal disposed between the substrates; wherein said pair of substrates each have thereon an alignment film comprising a polyamideimide having a fluoroalkyl chain group as a side chain, and both alignment films are provided with a uniaxial alignment axis in directions which are generally opposite and are (i) parallel to each other or (ii) cross each other at an intersection angle of 2-15 degrees, and wherein the chiral smectic liquid crystal is disposed in a texture comprising a plurality of bent smectic layers of similar shape each comprising a plurality of liquid crystal molecules.
Claim 11
Dependent Claim 82 words
A liquid crystal device, comprising: a pair of substrates each provided with a transparent electrode, and a chiral smectic liquid crystal disposed between the substrates; wherein said pair of substrates each have thereon an alignment film comprising a polyamideimide having a fluoroalkyl chain group as a side chain, and both alignment films are provided with a uniaxial alignment axis in directions which are generally opposite and are parallel to each other or cross each other at an intersection angle of 2-15 degrees.
Claim 12
Dependent Claim 82 words
A liquid crystal device, comprising: a pair of substrates each provided with a transparent electrode, and a chiral smectic liquid crystal disposed between the substrates; wherein said pair of substrates each have thereon an alignment film comprising a polyamideimide having a fluoroalkyl chain group as a side chain, and both alignment films are provided with a uniaxial alignment axis in directions which are generally opposite and are parallel to each other or cross each other at an intersection angle of 2-15 degrees.
Claim 13
Dependent Claim 35 words
A device according to claim 8, wherein the chiral smectic liquid crystal is disposed in a texture comprising a plurality of inclined smectic layers of similar shape each comprising a plurality of liquid crystal molecules.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-06-27 1997-12-27 1998-06-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-06-27 2001-12-27 2002-06-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-06-27 2005-12-27 2006-06-28 $7700.00 Window Closed / Lapsed

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