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US5322800A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and device for safely preserving aqueous field samples using acid or base

Assignee: United States Department of the Interior
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Filing: 1993-08-13
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Granted: 1994-06-21
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Expires: 2013-08-13
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Abstract

Abstract This invention concerns a method and apparatus for collecting and preserving field water samples on site in which a salt solution, contained in a syringe by a rupturable thin film membrane, is injected through a strong acid or base ion exchange filter to produce a required amount of either nitric acid, sulfuric acid or sodium hydroxide for sample collection and preservation.

Inventors

  • 👤 Andrew P. Murphy

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 10:53
CPC Classifications
G; G01; G01N; G01N33/00; G01N33/18; G01N33/1813; G01N1/00; G01N1/28; G01N33/182; G01N33/1826; G01N1/34; G01N1/02; G01N1/10; G01N1/14; G01N2001/1418; G01N2001/1427; G01N1/22; G01N1/24; G01N2001/247; Y; Y10; Y10T; Y10T436/00; Y10T436/25; Y10T436/2525; Y10T436/25375; Y10T436/255

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 184 words
A disposable device for producing required amounts of either an acid or base to a water sample for collection at remote locations consisting essentially of: a syringe having a cylindrical chamber for retaining a measured volume of a salt solution and having a discharge end; a plunger longitudinally movable in said chamber, a thin, plastic, rupturable film membrane disposed at said discharge end for sealing said syringe chamber, a salt solution sealed in said chamber by said plunger and said rupturable membrane therein for retaining said liquid until said plunger is actuated; a cartridge having an inlet end sealingly engaged with said syringe at said discharge end, said cartridge having an outlet end remote from said discharge end of said syringe; and an ion exchange filter in said cartridge adapted to react with said salt solution to produce one of an acid or base, whereby at said remote location said ion exchange filter can be reacted in selected amounts with said salt solution by selective depression of said plunger thereby producing a selected volume of acid or base for preservation of a water sample.
Claim 2
Dependent Claim 184 words
A disposable device for producing required amounts of either an acid or base to a water sample for collection at remote locations consisting essentially of: a syringe having a cylindrical chamber for retaining a measured volume of a salt solution and having a discharge end; a plunger longitudinally movable in said chamber, a thin, plastic, rupturable film membrane disposed at said discharge end for sealing said syringe chamber, a salt solution sealed in said chamber by said plunger and said rupturable membrane therein for retaining said liquid until said plunger is actuated; a cartridge having an inlet end sealingly engaged with said syringe at said discharge end, said cartridge having an outlet end remote from said discharge end of said syringe; and an ion exchange filter in said cartridge adapted to react with said salt solution to produce one of an acid or base, whereby at said remote location said ion exchange filter can be reacted in selected amounts with said salt solution by selective depression of said plunger thereby producing a selected volume of acid or base for preservation of a water sample.
Claim 3
Dependent Claim 56 words
The device as defined in claim 1 wherein said ion exchange filter is a strong acid ion exchange resin so that when said plunger is actuated, a selected amount of said salt solution is reacted with said acid ion exchange resin to produce a selected volume of acid that is added to the collected water sample.
Claim 4
Dependent Claim 56 words
The device as defined in claim 1 wherein said ion exchange filter is a strong base ion exchange resin so that when said plunger is actuated a selected amount of said salt solution is reacted with said base ion exchange resin to produce a selected volume of base that is added to the collected water sample.
Claim 5
Independent Claim 123 words
A method for producing required amounts of an acid or base to add to a water sample for collection at remote locations comprising the steps of: retaining a measured volume of a salt solution in a disposable syringe having a plunger, a cylindrical chamber, and a thin, plastic, rupturable film membrane for sealing said syringe chamber, applying pressure to said plunger and in turn to said salt solution and thereby bursting said film membrane sealing said syringe chamber, passing said salt solution through an ion exchange filter in a cartridge attached to said syringe in the discharge path of said cylindrical chamber to produce a selected volume of liquid, discharging selected amounts of said liquid, and adding said liquid to said water sample.
Claim 6
Independent Claim 123 words
A method for producing required amounts of an acid or base to add to a water sample for collection at remote locations comprising the steps of: retaining a measured volume of a salt solution in a disposable syringe having a plunger, a cylindrical chamber, and a thin, plastic, rupturable film membrane for sealing said syringe chamber, applying pressure to said plunger and in turn to said salt solution and thereby bursting said film membrane sealing said syringe chamber, passing said salt solution through an ion exchange filter in a cartridge attached to said syringe in the discharge path of said cylindrical chamber to produce a selected volume of liquid, discharging selected amounts of said liquid, and adding said liquid to said water sample.
Claim 7
Dependent Claim 27 words
The method of claim 4 wherein said ion exchange filter is a strong acid ion exchange resin and said liquid produced is a selected volume of acid.
Claim 8
Dependent Claim 27 words
The method of claim 4 wherein said ion exchange filter is a strong base ion exchange resin and said liquid produced is a selected volume of base.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-06-20 1997-12-20 1998-06-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-06-20 2001-12-20 2002-06-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-06-20 2005-12-20 2006-06-21 $7700.00 Window Closed / Lapsed

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