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US5320673A Expired / Lapsed US ⏱️ 0.0 years remaining

Dispersants for pigments in waterborne coatings compositions

Assignee: BASF Farben und Fasern AG
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Filing: 1992-10-19
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Granted: 1994-06-14
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Expires: 2012-10-19
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Abstract

Abstract A compound is described that is useful as a dispersant for inorganic pigments and metallic flake pigments in waterborne coatings. The compound comprises a polymeric backbone having a pigment-interactive substituent and a stabilizing substituent. The pigment-interactive substituent has at least one functionality selected from the group consisting of ##STR1## wherein A 1 , A 2 , A 3 , and A 4 are as defined herein. The stabilizing substituent includes the structure ##STR2## wherein D 1 , D 2 , R 1 , R 2 , R 3 , m, and n are as defined herein.

Inventors

  • 👤 Clint W. Carpenter

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 03:50
CPC Classifications
C; C09; C09C; C09C1/00; C09C1/62; C09C1/64; C09C1/644; C09C1/646; C09C3/00; C09C3/08; C09C3/12; C09D; C09D17/00; C09D17/004; C09D5/00; C09D5/38; C09D7/00; C09D7/40; C09D7/45; C01; C01P; C01P2004/00; C01P2004/20; C01P2004/60; C01P2004/61; C01P2004/80; C01P2004/82; C01P2004/84; C01P2006/00; C01P2006/12; C01P2006/22; C01P2006/80; C01P2006/90

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 197 words
A compound, comprising a polymeric backbone, having a pigment-interactive substituent and a stabilizing substituent; wherein the pigment-interactive substituent has at least one functionality selected from the group consisting of ##STR14## wherein A 1 , A 2 , A 3 , and A 4 are each independently hydroxy, alkyl of one to ten carbon atoms, alkoxy of one to ten carbon atoms, alkoxyalkoxy of two to ten carbon atoms, alkanoyloxy of two to ten carbon atoms, or halogen, with the proviso that A 1 , A 2 , and A 3 may not all be alkyl; and wherein the stabilizing substituent comprises the structure ##STR15## wherein D 1 and D 2 are divalent radicals, each independently --O--or --NA 5 --, wherein A 5 is hydrogen or alkyl of one to twelve carbon atoms; R 1 is a divalent radical selected from straight or branched alkylenes of three to thirty carbon atoms; R 2 is hydrogen or a mixture of hydrogen and alkyl of one to eight carbon atoms; R 3 is an alkyl of one to thirty carbon atoms; m is an integer from zero to one thousand, and n is an integer from one to one thousand.
Claim 2
Dependent Claim 197 words
A compound, comprising a polymeric backbone, having a pigment-interactive substituent and a stabilizing substituent; wherein the pigment-interactive substituent has at least one functionality selected from the group consisting of ##STR14## wherein A 1 , A 2 , A 3 , and A 4 are each independently hydroxy, alkyl of one to ten carbon atoms, alkoxy of one to ten carbon atoms, alkoxyalkoxy of two to ten carbon atoms, alkanoyloxy of two to ten carbon atoms, or halogen, with the proviso that A 1 , A 2 , and A 3 may not all be alkyl; and wherein the stabilizing substituent comprises the structure ##STR15## wherein D 1 and D 2 are divalent radicals, each independently --O--or --NA 5 --, wherein A 5 is hydrogen or alkyl of one to twelve carbon atoms; R 1 is a divalent radical selected from straight or branched alkylenes of three to thirty carbon atoms; R 2 is hydrogen or a mixture of hydrogen and alkyl of one to eight carbon atoms; R 3 is an alkyl of one to thirty carbon atoms; m is an integer from zero to one thousand, and n is an integer from one to one thousand.
Claim 3
Dependent Claim 181 words
A compound as described in claim 1, of the formula: ##STR16## wherein D 1 , D 2 , R 1 , R 2 , R 3 , m, and n are as defined in claim 1; and wherein X is either ##STR17## wherein A 1 , A 2 , A 3 , and A 4 are as defined in claim 1; R 4 is a divalent radical selected from straight or branched alkylenes of one to twelve carbon atoms; D 3 is either a divalent radical selected from the group consisting of --O--, --NA 6 --, and --S--, or a trivalent radical of the formula ##STR18## wherein A 6 , A 7 , A 8 and A 9 are each independently hydrogen or alkyl of one to twelve carbon atoms; R 5 is hydrogen or a covalent bond with D 3 , with the proviso that R 5 is only a covalent bond with D 3 when D 3 is a trivalent radical; R 6 is the polymeric backbone; and j and k are integers, each independently being one to fifty.
Claim 4
Dependent Claim 14 words
A coating composition, comprising a compound according to claim 1 and an inorganic pigment.
Claim 5
Dependent Claim 11 words
A coating composition as described in claim 3, further comprising water.
Claim 6
Dependent Claim 14 words
A coating composition, comprising a compound according to claim 2 and an inorganic pigment.
Claim 7
Dependent Claim 11 words
A coating composition as described in claim 5, further comprising water.
Claim 8
Dependent Claim 28 words
A coating composition as described in claim 5, wherein the D 1 and the D 2 are each --O--, and wherein the D 3 is either --O--or --NH--.
Claim 9
Dependent Claim 16 words
A coating composition according to claim 5, wherein the R 6 is an acrylic polymeric backbone.
Claim 10
Dependent Claim 22 words
A coating composition as described in claim 8, wherein the molecular weight of the acrylic polymeric backbone is from 2000 to 50,000.
Claim 11
Dependent Claim 24 words
A coating composition as described in claim 5, wherein the m is from 0 to 20 and the n is from 40 to 70.
Claim 12
Dependent Claim 20 words
A coating composition as described in claim 5, wherein the R 2 is hydrogen and the R 3 is methyl.
Claim 13
Dependent Claim 20 words
A coating composition as described in claim 5, wherein the j and k are each independently from 1 to 10.
Claim 14
Dependent Claim 13 words
A coating composition as described in claim 5, wherein the m is 0.
Claim 15
Dependent Claim 11 words
A coating composition according to claim 5 wherein X is ##STR19##
Claim 16
Dependent Claim 14 words
A coating composition as described in claim 14, wherein the A 4 is hydroxy.
Claim 17
Dependent Claim 23 words
A compound as described in claim 1, wherein the pigment-interactive substituent is incorporated into the compound by copolymerization of an ethylenically unsaturated group.
Claim 18
Dependent Claim 23 words
A compound as described in claim 1, wherein the stabilizing substituent is incorporated into the compound by copolymerization of an ethylenically unsaturated group.
Claim 19
Dependent Claim 23 words
A coating composition, comprising a compound according to claim 1 and a metallic particle, with the proviso that m is at least one.
Claim 20
Dependent Claim 17 words
A coating composition as described in claim 18, wherein the metallic particle is a metallic flake pigment.
Claim 21
Dependent Claim 14 words
A coated article, comprising a substrate having thereon the coating composition according claim 3.
Claim 22
Dependent Claim 14 words
A coated article, comprising a substrate having thereon the coating composition according claim 19.

References Cited (Backward Citations)

US4213886A Cited
US4350535A Cited
US4565716A Cited
US4675358A Cited
US4750940A Cited
US5057156A Cited
US5039343A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-06-13 1997-12-13 1998-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-06-13 2001-12-13 2002-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-06-13 2005-12-13 2006-06-14 $7700.00 Window Closed / Lapsed

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