Enhanced photo-activated luminescence for screening polychlorobiphenyls (PCBs) and other related chlorinated compounds

Claim 3

An apparatus according to claim 1, wherein the first and second means comprise a UV light source having an output irradiation beam, and first and second optical filters positionable selectively in an optical path of the irradiation beam.

Claim 4

An apparatus according to claim 2, wherein the first optical filter transmits the first wavelength of UV light at <254 nm and the second optical filter transmits the second wavelength of UV light at <360 nm and >254 nm.

Claim 5

An apparatus according to claim 3, wherein the detecting means includes a photo-detector and a third optical filter disposed between the sample and the photo-detector, the third optical filter transmitting a third wavelength of light to the photo-detector, the third wavelength corresponding to a peak wavelength of a luminescence spectrum detected by the photo-detector.

Claim 6

An apparatus according to claim 1, wherein the first and second means comprises first and second light sources.

Claim 7

An apparatus according to claim 1, further comprising a substrate for holding the sample in an optical path between the detecting means and the second means, said substrate being treated with a surfactant.

Claim 8

An apparatus according to claim 1, wherein the photo-activator is selected from the group consisting of indole, diphenylamine, pyrrole, and imidazole.

Claim 9

An apparatus according to claim 6, wherein the photo-activator is carried by the substrate.

Claim 10

An apparatus according to claim 6, wherein the surfactant is selected from the group consisting of sodium lauryl sulfate, CTAB, ethylene oxide, propylene oxide, cyclodextrin, and micellar.

Claim 11

An apparatus according to claim 1, further comprising a substrate for holding the sample in an optical path between the detecting means and the second means, said substrate being treated with a semiconductor particles.

Claim 12

An apparatus according to claim 9, wherein the semiconductor particles are TiO 2 .

Claim 13

A portable field instrument for screening a sample for PCBs and related organic chlorinated compounds, comprising: a photo-activator to be mixed with the sample prior to screening; a housing; a power source disposed within the housing; a UV light source disposed within the housing and being powered by the power source; a substrate positioned in an optical path of an irradiating output beam of the UV light source, and having the sample mountable thereon; first and second optical filters selectively positionable in the optical path of the UV light source, each transmitting UV light at a different wavelength, the first filter transmitting UV light sufficient to photo-activate and form a photo-product complex of the photo-activator and chlorinated compounds, and the second optical filter transmitting UV light sufficient to cause the complex to luminesce; and detecting means, disposed within the housing, for detecting the luminescence of the complex, the detected luminescence having a characteristic indicative of the presence or absence of chlorinated compounds.

Claim 14

A portable field instrument for screening a sample for PCBs and related organic chlorinated compounds, comprising: a photo-activator to be mixed with the sample prior to screening; a housing; a power source disposed within the housing; a UV light source disposed within the housing and being powered by the power source; a substrate positioned in an optical path of an irradiating output beam of the UV light source, and having the sample mountable thereon; first and second optical filters selectively positionable in the optical path of the UV light source, each transmitting UV light at a different wavelength, the first filter transmitting UV light sufficient to photo-activate and form a photo-product complex of the photo-activator and chlorinated compounds, and the second optical filter transmitting UV light sufficient to cause the complex to luminesce; and detecting means, disposed within the housing, for detecting the luminescence of the complex, the detected luminescence having a characteristic indicative of the presence or absence of chlorinated compounds.

Claim 15

An apparatus according to claim 12, wherein the detecting means includes a photo-detector and a third optical filter, both located inside the housing, and the third optical filter being disposed between the sample and the photo-detector, the third optical filter transmitting a third wavelength of the light to the photo-detector, the third wavelength corresponding to a peak wavelength of a luminescence spectrum detected by the photo-detector.

Claim 16

An apparatus according to claim 12, wherein the substrate is located within the housing.

Claim 17

An apparatus according to claim 12, wherein the substrate is located outside of the housing, and the apparatus further comprises a fiber optic probe having a first fiber optic for communicating UV light from the first and second optical filters to the sample, and a second fiber optic for communicating UV luminescent light from the sample to the detecting means.