US5311352A
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Increasing the birefringence of KTP and its isomorphs for type II phase matching
Assignee: EIDP Inc
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Filing: 1992-12-23
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Granted: 1994-05-10
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Expires: 2012-12-23
Abstract
Abstract Method and device for wavelength conversion using type II phase matching are characterized by employing a crystal consisting essentially of doped MTiOXO 4 (wherein M is K, Rb and/or Tl and X is P and/or As) containing Fe, Nb and/or Ta dopant in an amount, totalling at least about 100 ppm, effective to increase the n z -n x optical birefringence of the doped crystal at least about 0.001 compared to a crystal without the dopant. Generation of output waves of an optical birefringence higher than the highest corresponding optical birefringence of a crystal without the dopant is disclosed. Among the useful crystals are crystals consisting essentially of doped MTiOXO 4 containing at least about 100 ppm Ta.
Inventors
- 👤 John D. Bierlein
- 👤 Lap K. Cheng
- 👤 Lap-Tak A. Cheng
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 18:44
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/35; G02F1/355; G02F1/3551; G02F1/3553
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
162 words
A method for phase matching including the steps of directing electromagnetic radiation into a crystal having nonlinear optical properties, and generating output waves from said crystal having a selected wavelength different from the wavelength of input waves to said crystal using type II phase matching, characterized by: said crystal consisting essentially of doped MTiOXO 4 wherein M is selected from the group consisting of K, Rb and Tl and mixtures thereof and X is selected from P, As, and mixtures thereof, said crystal containing at least one dopant selected from the group consisting of Fe, Nb, and Ta in an amount, totalling at least about 100 ppm, effective to increase the n z -n x optical birefringence of the doped crystal at least about 0.001 compared to a crystal without said dopant; and said output waves being generated in said crystal from said input waves at an optical birefringence higher than the highest corresponding optical birefringence of a crystal without said dopant.
Claim 2
Independent Claim
162 words
A method for phase matching including the steps of directing electromagnetic radiation into a crystal having nonlinear optical properties, and generating output waves from said crystal having a selected wavelength different from the wavelength of input waves to said crystal using type II phase matching, characterized by: said crystal consisting essentially of doped MTiOXO 4 wherein M is selected from the group consisting of K, Rb and Tl and mixtures thereof and X is selected from P, As, and mixtures thereof, said crystal containing at least one dopant selected from the group consisting of Fe, Nb, and Ta in an amount, totalling at least about 100 ppm, effective to increase the n z -n x optical birefringence of the doped crystal at least about 0.001 compared to a crystal without said dopant; and said output waves being generated in said crystal from said input waves at an optical birefringence higher than the highest corresponding optical birefringence of a crystal without said dopant.
Claim 3
Dependent Claim
9 words
The method of claim 1 wherein X is P.
Claim 4
Dependent Claim
15 words
The method of claim 1 wherein the crystal consists essentially of doped KTiOPO 4 .
Claim 5
Dependent Claim
23 words
The method of claim 2 or claim 3 wherein second harmonic generation is achieved at an input wavelength of less than 0.994 microns.
Claim 6
Dependent Claim
9 words
The method of claim 1 wherein X is As.
Claim 7
Dependent Claim
15 words
The method of claim 1 wherein the crystal consists essentially of doped KTiOAsO 4 .
Claim 8
Dependent Claim
22 words
The method of claim 5 or 6 wherein second harmonic generation is achieved at an input wavelength of less than 1.074 microns.
Claim 9
Dependent Claim
168 words
A nonlinear optical device comprising a nonlinear optical crystal and input means for directing electromagnetic radiation into said crystal to generate output waves from said crystal having a selected wavelength different from the wavelength of input waves to said crystal using type II phase matching, characterized by: said crystal consisting essentially of doped MTiOXO 4 wherein M is selected from the group consisting of K, Rb, Tl and mixtures thereof and X is selected from the group consisting of P, As and mixtures thereof, said crystal containing at least one dopant selected from the group consisting of Fe, Nb, and Ta in an amount, totalling at least about 100 ppm, effective to increase the n z -n x optical birefringence of the doped crystal at least about 0.001 compared to a crystal without said dopant; and said input means being adapted to provide input waves suitable for generating said output waves at an optical birefringence higher than the highest corresponding optical birefringence of a crystal without said dopant.
Claim 10
Dependent Claim
168 words
A nonlinear optical device comprising a nonlinear optical crystal and input means for directing electromagnetic radiation into said crystal to generate output waves from said crystal having a selected wavelength different from the wavelength of input waves to said crystal using type II phase matching, characterized by: said crystal consisting essentially of doped MTiOXO 4 wherein M is selected from the group consisting of K, Rb, Tl and mixtures thereof and X is selected from the group consisting of P, As and mixtures thereof, said crystal containing at least one dopant selected from the group consisting of Fe, Nb, and Ta in an amount, totalling at least about 100 ppm, effective to increase the n z -n x optical birefringence of the doped crystal at least about 0.001 compared to a crystal without said dopant; and said input means being adapted to provide input waves suitable for generating said output waves at an optical birefringence higher than the highest corresponding optical birefringence of a crystal without said dopant.
Claim 11
Dependent Claim
15 words
The device of claim 8 wherein said crystal consists essentially of doped KTiOPO 4 .
Claim 12
Dependent Claim
15 words
The device of claim 8 wherein said crystal consists essentially of doped KTiOAsO 4 .
Claim 13
Dependent Claim
44 words
A crystal consisting essentially of doped MTiOXO 4 containing at least about 100 ppm Ta, wherein M is selected from the group consisting of K, Rb, Tl and mixtures thereof and X is selected from the group consisting of P, As and mixtures thereof.
Claim 14
Dependent Claim
44 words
A crystal consisting essentially of doped MTiOXO 4 containing at least about 100 ppm Ta, wherein M is selected from the group consisting of K, Rb, Tl and mixtures thereof and X is selected from the group consisting of P, As and mixtures thereof.
Claim 15
Dependent Claim
13 words
The crystal of claim 11 wherein M is K and X is P.
References Cited (Backward Citations)
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