US5302197A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Ink jet inks
Assignee: EIDP Inc
•
Filing: 1992-12-30
•
Granted: 1994-04-12
•
Expires: 2012-12-30
Abstract
Abstract An aqueous ink jet composition comprising a pigment dispersion, an aqueous carrier medium, and a cosolvent mixture comprising a polyol/alkylene oxide condensate and a cyclic amide derivative have excellent print quality due to high optical density and minimum feathering over a wide range of commercial papers having different properties, dry rapidly by media penetration without excessive loss of image definition, and become 100% waterfast as soon as the inks are dry to the touch.
Inventors
- 👤 Palitha Wickramanayke
- 👤 Sheau-Hwa Ma
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 00:11
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/32; C09D11/322
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
213 words
An aqueous ink jet ink composition comprising: (a) a pigment dispersion; (b) an aqueous carrier medium; and (c) a cosolvent combination comprising: (i) at least 4.5% by weight based on the total weight of the ink composition of a polyol/alkylene oxide condensate having a solubility in water of at least 4.6% at 25° C. and represented by the formula: ##STR5## wherein X is independently --H or --CH 3 ; R=--H, --CH 3 , --C 2 H 5 , --C 3 H 9 , --C 4 H 9 , or --CH 2 O(CH 2 CH 2 O) e H; b=0 or 1; a+d+f(c+e)=2-100; f=1-6; and (ii) at least 2% by weight based on the total weight of the ink composition of a cyclic amide derivative having a solubility in water of at least 4.5% at 25° C. and represented by the formula: ##STR6## wherein n=3-7, R=H, or alkyl group having 1 to 4 carbon atoms, and optionally containing one or more hydroxy or ether groups, m=0-3, X=alkyl group having 1 to 4 carbon atoms, and optionally containing one or more hydroxy or ether groups, and wherein X replaces a H on the ring when m=1-3; wherein the ratio of cosolvent (i) to cosolvent (ii) is in the range from 10:1 to 1:10 by weight.
Claim 2
Dependent Claim
213 words
An aqueous ink jet ink composition comprising: (a) a pigment dispersion; (b) an aqueous carrier medium; and (c) a cosolvent combination comprising: (i) at least 4.5% by weight based on the total weight of the ink composition of a polyol/alkylene oxide condensate having a solubility in water of at least 4.6% at 25° C. and represented by the formula: ##STR5## wherein X is independently --H or --CH 3 ; R=--H, --CH 3 , --C 2 H 5 , --C 3 H 9 , --C 4 H 9 , or --CH 2 O(CH 2 CH 2 O) e H; b=0 or 1; a+d+f(c+e)=2-100; f=1-6; and (ii) at least 2% by weight based on the total weight of the ink composition of a cyclic amide derivative having a solubility in water of at least 4.5% at 25° C. and represented by the formula: ##STR6## wherein n=3-7, R=H, or alkyl group having 1 to 4 carbon atoms, and optionally containing one or more hydroxy or ether groups, m=0-3, X=alkyl group having 1 to 4 carbon atoms, and optionally containing one or more hydroxy or ether groups, and wherein X replaces a H on the ring when m=1-3; wherein the ratio of cosolvent (i) to cosolvent (ii) is in the range from 10:1 to 1:10 by weight.
Claim 3
Dependent Claim
17 words
The ink composition of claim 1 wherein the pigment dispersion comprises a pigment and a polymeric dispersant.
Claim 4
Dependent Claim
31 words
The ink composition of claim 2 wherein the pigment is an organic pigment present in the amount of up to about 30% based on the total weight of the ink composition.
Claim 5
Dependent Claim
26 words
The ink composition of claim 2 wherein the dispersant is present in the amount of about 0.1-25% based on the total weight of the ink composition.
Claim 6
Dependent Claim
22 words
The ink composition of claim 3 wherein the polymeric dispersant is selected from the group consisting of random, block and branched polymers.
Claim 7
Dependent Claim
26 words
The ink composition of claim 1 wherein the the ratio of cosolvent (i) to cosolvent (ii) is in the range from 4:1 to 1:4 by weight.
Claim 8
Dependent Claim
30 words
The ink composition of claim 1 or 6 wherein the cyclic amide derivative is present in the amount of about 2-25% based on the total weight of the ink composition.
Claim 9
Dependent Claim
30 words
The ink composition of claim 1 or 6 wherein the polyol/alkylene oxide condensate is present in the amount of about 4.5-25% based on the total weight of the ink composition.
Claim 10
Dependent Claim
8 words
The ink composition of claim 1 wherein a+d+f(c+e)=10-40.
Claim 11
Dependent Claim
15 words
The ink composition of claim 1 wherein, in cosolvent (i), X=--H, R=--H, f=1 and b=0.
Claim 12
Dependent Claim
23 words
The ink composition of claim 1 wherein, in cosolvent (i) , X=--H, R=--CH 3 or --C 2 H 5 , f=1 and b=1.
Claim 13
Dependent Claim
15 words
The ink composition of claim I wherein, in cosolvent (i), X=--H, R=--H, f=4 and b=0.
Claim 14
Dependent Claim
21 words
The ink composition of claim 1 wherein cosolvent (i) is the reaction product of glycerol with 26 moles of ethylene oxide.
Claim 15
Dependent Claim
21 words
The ink composition of claim 1 wherein cosolvent (i) is the reaction product of sorbitol with 20 moles of ethylene oxide.
Claim 16
Dependent Claim
9 words
The ink composition of claim 1 wherein n 3-5.
Claim 17
Dependent Claim
31 words
The ink composition of claim 1 wherein cosolvent (ii) is selected from the group of 2-pyrrolidone, 1-methyl-2-pyrrolidone, 1,5-dimethyl-2-pyrrolidone, 1-ethyl-2-pyrrolidone, 1-propyl-2-pyrrolidone, 1-isopropyl-2-pyrrolidone, 1-butyl-2-pyrrolidone, 1-(2-hydroxyethyl)-2-pyrrolidone, 1-methyl-2-piperidone, valerolactam, 1-ethyl valerolactam, caprolactam, 1-methylcaprolactam and oenantholactam.
Claim 18
Dependent Claim
31 words
The ink composition of claim 1 wherein the aqueous carrier medium comprises water or a mixture of at least one water soluble organic solvent other than cosolvent (i) or cosolvent (ii).
Claim 19
Dependent Claim
28 words
The ink composition of claim 1 wherein the aqueous carrier medium is present in the amount of about 65-93.5% based on the total weight of the ink composition.
References Cited (Backward Citations)
US4627875A
Cited
JPS6210547A
Cited
US4986850A
Cited
US5108503A
Cited
US5205861A
Cited
US5180425A
Cited
US5173112A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-04-11 | 1997-10-11 | 1998-04-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-04-11 | 2001-10-11 | 2002-04-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-04-11 | 2005-10-11 | 2006-04-12 | $7700.00 | Window Closed / Lapsed |