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US5292561A Expired / Lapsed US ⏱️ 0.0 years remaining

Transparent shrink film made from biaxially oriented polypropylene

Assignee: Hoechst AG
•
Filing: 1991-09-19
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Granted: 1994-03-08
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Expires: 2011-09-19
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Abstract

Abstract A transparent shrink film made from propylene useful for all-round labeling of essentially cylindrical containers, such as bottles, comprises a propylene polymer and has, at 100° C., a shrinkage in the longitudinal direction of at least 10% and a shrinkage in the transverse direction of less than 2%. A process for producing the film is also provided.

Inventors

  • 👤 Herbert Peiffer
  • 👤 Ursula Murschall
  • 👤 Gunter Schloegl

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:04
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/10; B; B29; B29C; B29C61/00; B29C61/003; B29C61/06; B29K; B29K2023/00; B29K2023/10; B29K2023/12; B29K2995/00; B29K2995/0018; B29K2995/0026; B29L; B29L2031/00; B29L2031/744; C08L2203/00; C08L2203/10; C08L23/14; C08L23/142; C08L57/00; C08L57/02; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/13; Y10T428/1328; Y10T428/1331; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24967; Y10T428/28; Y10T428/2813; Y10T428/2817; Y10T428/2826; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 36 words
A film comprising a propylene polymer, wherein said film has at 100° C. a shrinkage in the longitudinal direction of at least about 10% and a shrinkage in the transverse direction of less than about 2%.
Claim 2
Dependent Claim 36 words
A film comprising a propylene polymer, wherein said film has at 100° C. a shrinkage in the longitudinal direction of at least about 10% and a shrinkage in the transverse direction of less than about 2%.
Claim 3
Dependent Claim 26 words
A film as claimed in claim 1, wherein said propylene polymer is an isotactic polypropylene having an n-heptane-soluble content of about 15% by weight or less.
Claim 4
Dependent Claim 23 words
A film as claimed in claim 2, wherein said isotactic polypropylene has an n-heptane-soluble content of about 2 to about 6% by weight.
Claim 5
Dependent Claim 24 words
A film as claimed in claim which contains the propylene polymer in an amount of from 60 to 95% by weight of the film.
Claim 6
Dependent Claim 49 words
A film as claimed in claim 4, which additionally comprises about 5 to about 40% by weight of a hydrogenated hydrocarbon resin having a softening point in the range from about 130° to about 180° C., the percentages being based on the total weight of the polypropylene/hydrocarbon resin mixture.
Claim 7
Dependent Claim 38 words
A film as claimed in claim 5, wherein said hydrogenated hydrocarbon resin is a low-molecular-weight synthetic resin which has a softening point in the range of about 130° to about 160° C., determined in accordance with ASTM E28.
Claim 8
Dependent Claim 47 words
A film as claimed in claim additionally comprising outer layers on both sides of said film, independently comprised of a propylene homopolymer or ethylene-propylene copolymer, the outer layers may contain up to 40 % by weight of the individual outer layer of a low molecular weight resin.
Claim 9
Dependent Claim 20 words
A film as claimed in claim 7, wherein one or both of the outer layers additionally comprises an antiblocking agent.
Claim 10
Dependent Claim 48 words
A film as claimed in claim 8, wherein said antiblocking agent comprises silicon dioxide or calcium carbonate, each having a mean particle size of between about 1.5 and about 3 μm and present in an amount of about 0.1 to about 0.5% by weight of the outer layer.
Claim 11
Dependent Claim 21 words
A film as claimed in claim 1, having an overall thickness in the range of about 10 to about 50 μm.
Claim 12
Dependent Claim 72 words
A film as claimed in claim 1, which has a shrink capacity of greater than about 10% at 100° C. and greater than about 25% at 120° C. in the longitudinal direction and a shrink capacity of less than about 2% at 100° C. and less than about 10% at 120° C. in the transverse direction, the percentages being based on the respective length extension of the film before the shrinking process.
Claim 13
Dependent Claim 42 words
A film as claimed in claim 1, which has a modulus of elasticity in the longitudinal direction of greater than about 2800 N/mm 2 , and a modulus of elasticity in the transverse direction of greater than about 2500 N/mm 2 .
Claim 14
Dependent Claim 44 words
A film as claimed in claim 12, wherein said modulus of elasticity in the longitudinal direction is about 3000 to about 3300 N/mm 2 , and wherein said modulus of elasticity in the transverse direction is about 2800 to about 3300 N/mm 2 .
Claim 15
Dependent Claim 37 words
A film as claimed in claim 1, which has a tear strength in the longitudinal direction of greater than about 170 N/mm 2 , and in the transverse direction of greater than about 150 N/mm 2 .
Claim 16
Dependent Claim 41 words
A film as claimed in claim 14, wherein said tear strength in the longitudinal direction is about 180 to about 200 N/mm 2 and wherein said tear strength in the transverse direction is about 160 to about 180 N/mm 2 .
Claim 17
Dependent Claim 22 words
A film as claimed in claim 1, wherein said film is a transparent shrink film for shrink-wrap labeling of substantially cyclindrical containers.
Claim 18
Dependent Claim 36 words
A film as claimed in claim 7, having an overall thickness in the range of about 10 to about 50 μm, wherein the outer layers each have a thickness of about 0.2 to about 0.7 μm.
Claim 19
Dependent Claim 14 words
A film as claimed in claim 1, wherein the film consists essentially of polypropylene.
Claim 20
Dependent Claim 27 words
A film as claimed in claim 7, wherein the outer layers comprise a polypropylene having a higher melt flow index than the polypropylene of the base layer.
Claim 21
Dependent Claim 28 words
A film as claimed in claim 7, wherein the outer layers are heat-sealable and comprise an ethylenepropylene copolymer containing about 2 to about 10% by weight of ethylene.
Claim 22
Dependent Claim 55 words
A film as claimed in claim 1, which has a shrink capacity of about 14 to about 18 at 100° C. and about 25 to 30% at 120° C. in the longitudinal direction and about 0 to about 2% at 100° C. and about 3 to about 7 at 120° C. in the transverse direction.
Claim 23
Dependent Claim 17 words
A film as claimed in claim 5, which consists essentially of polypropylene and said hydrogenated hydrocarbon resin.

References Cited (Backward Citations)

GB1069450A Cited
EP0348749A2 Cited
US5091237A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-03-07 1997-09-06 1998-03-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-03-07 2001-09-06 2002-03-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-03-07 2005-09-06 2006-03-08 $7700.00 Window Closed / Lapsed

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