US5290857A
Expired / Lapsed
US
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Epoxy resin adhesive composition
Assignee: Zeon Corp
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Filing: 1992-09-03
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Granted: 1994-03-01
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Expires: 2012-09-03
Abstract
Abstract An epoxy resin adhesive composition has excellent adhesive properties such as impact resistance, tensile shear strength and T-peel strength as well as excellent semi-gelling property. An epoxy resin adhesive composition comprising ionic crosslinking in a polymer utilized as the impact resistance modifier has not only excellent semi-gelling property and mechanical properties of cured products but also excellent storage stability for a long time and it is advantageously utilized when the application occasionally requires storage or standing of the material for one month to one year at the room temperature. The epoxy resin adhesive composition comprises an epoxy resin, a powder core/shell polymer and a heat activation type hardener for epoxy resins. The powder core/shell polymer is composed of a core comprising an acrylate polymer or a methacrylate polymer having a glass transition temperature of -30° C. or lower and a shell comprising an acrylate polymer or a methacrylate polymer comprising crosslinking monomer units having a glass transition temperature of 70° C. or higher and weight ratio of the core to the shell is in the range from 10/1 to 1/4.
Inventors
- 👤 Tadashi Ashida
- 👤 Masahiko Ohnishi
- 👤 Toshio Nagase
- 👤 Akira Nakayama
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 10:46
CPC Classifications
C; C09; C09J; C09J163/00; C09J151/00; C09J151/003; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/04; C08L2666/08; C08L2666/14; Y; Y10; Y10S; Y10S525/00; Y10S525/902
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
286 words
An epoxy resin adhesive composition comprising: (A) an epoxy resin, (B) 10 to 100 weight parts based on 100 weight parts of (A) of a powder core/shell polymer comprising particles having, a core comprising an acrylate polymer or a methacrylate polymer having a glass transition temperature of -30° C. or lower and 0.01 to 5 weight %, based on the total amount of the monomers, of a crosslinking monomer having two or more double bonds of substantially the same reactivity in the molecule and a shell comprising a copolymer having a glass transition temperature of 70° C. or higher which is made from (a) an acrylate monomer or a methacrylate monomer, (b) a radical polymerizable unsaturated carboxylic acid monomer having 3 to 8 carbon atoms and carboxyl groups, the amount of the monomer having carboxyl groups being 0.01 to 20 weight parts based on 100 weight parts of the shell copolymer, and (c) 0.01 to 5 weight %, based on the total weight of monomers in the shell, of a crosslinking monomer having two or more double bonds of substantially the same reactivity in the molecule, wherein the powder core/shell polymer comprises powder polymer particles ion-crosslinked by addition of a monovalent or divalent metal cation in a mole ratio of metal cation to the carboxyl groups in the copolymer of 0.1:1 to 3:1, and wherein the weight ratio of the core to the shell is from 10:1 to 1:4 and the weight average diameter of the core comprising a single particle or an aggregate of the particles is from 0.1 to 3.0 μm; and (C) 3 to 30 weight parts based on 100 weight parts of (A) of a heat activation type hardener for epoxy resins,
Claim 2
Dependent Claim
286 words
An epoxy resin adhesive composition comprising: (A) an epoxy resin, (B) 10 to 100 weight parts based on 100 weight parts of (A) of a powder core/shell polymer comprising particles having, a core comprising an acrylate polymer or a methacrylate polymer having a glass transition temperature of -30° C. or lower and 0.01 to 5 weight %, based on the total amount of the monomers, of a crosslinking monomer having two or more double bonds of substantially the same reactivity in the molecule and a shell comprising a copolymer having a glass transition temperature of 70° C. or higher which is made from (a) an acrylate monomer or a methacrylate monomer, (b) a radical polymerizable unsaturated carboxylic acid monomer having 3 to 8 carbon atoms and carboxyl groups, the amount of the monomer having carboxyl groups being 0.01 to 20 weight parts based on 100 weight parts of the shell copolymer, and (c) 0.01 to 5 weight %, based on the total weight of monomers in the shell, of a crosslinking monomer having two or more double bonds of substantially the same reactivity in the molecule, wherein the powder core/shell polymer comprises powder polymer particles ion-crosslinked by addition of a monovalent or divalent metal cation in a mole ratio of metal cation to the carboxyl groups in the copolymer of 0.1:1 to 3:1, and wherein the weight ratio of the core to the shell is from 10:1 to 1:4 and the weight average diameter of the core comprising a single particle or an aggregate of the particles is from 0.1 to 3.0 μm; and (C) 3 to 30 weight parts based on 100 weight parts of (A) of a heat activation type hardener for epoxy resins,
Claim 3
Dependent Claim
53 words
An epoxy resin adhesive composition as claimed in claim 1 wherein the epoxy resin is an epoxy resin derived by addition of 2 to 20 mols of ethylene oxide to bisphenol A, an epoxy resin derived by addition of 2 to 20 mols of propylene oxide to bisphenol A or a mixture thereof.
Claim 4
Dependent Claim
37 words
An epoxy resin adhesive composition as claimed in claim 1 wherein the weight average diameter of the core comprising a single particle or an aggregate of the particles is in the range from 0.15 to 2.0 μm.
Claim 5
Dependent Claim
62 words
An epoxy resin adhesive composition as claimed in claim 1 wherein the amount of (B) the powder core/shell polymer is in the range from 10 to 50 weight parts and the amount of (C) the heat activation type hardener for epoxy resins is in the range from 5 to 20 weight parts based on 100 weight parts of (A) the epoxy resin.
Claim 6
Dependent Claim
33 words
An epoxy resin adhesive as claimed in claim 1 wherein the core comprises an acrylate polymer or a methacrylate polymer having a glass transition temperature in the range from -40° to -70° C.
Claim 7
Dependent Claim
34 words
An epoxy resin adhesive composition as claimed in claim 1 wherein the shell comprises an acrylate polymer or a methacrylate polymer having a glass transition temperature in the range from 80° to 120° C.
Claim 8
Dependent Claim
46 words
An epoxy resin adhesive composition as claimed in claim 1 wherein the core is made by copolymerization of an acrylate monomer or a methacrylate monomer and 0.1 to 2 weight % of a crosslinking monomer based on the total amount of the monomer constituting the core.
Claim 9
Dependent Claim
21 words
An epoxy resin adhesive composition as claimed in claim 1 wherein the crosslinking monomer (C) for the shell is triallyl trimellitate.
Claim 10
Dependent Claim
29 words
The epoxy resin adhesive composition of claim 1 wherein the core comprises an acrylate polymer or methacrylate polymer having a glass transition temperature of -30° C. to -70° C.
Claim 11
Dependent Claim
27 words
The epoxy resin adhesive composition of claim 1 wherein the copolymer comprised in the shell has a glass transition temperature of 70° C. to 120° C. V
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-02-28 | 1997-08-30 | 1998-03-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-02-28 | 2001-08-30 | 2002-03-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-02-28 | 2005-08-30 | 2006-03-01 | $7700.00 | Window Closed / Lapsed |