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US5290731A Expired / Lapsed US ⏱️ 0.0 years remaining

Aluminum metallization method

Assignee: Sony Corp
•
Filing: 1992-03-09
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Granted: 1994-03-01
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Expires: 2012-03-09
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Abstract

Abstract A metallization method for improving wettability and reactivity of a titanium (Ti) based barrier metal layer with respect to an aluminum (Al) based material and simultaneously achieving high barrier properties and superior step coverage, is proposed. An operation of increasing the crystal grain size of and planarizing at least a surface region of a barrier metal layer is effected simultaneously at the time of formation of a barrier metal layer. In this manner, Al migration characteristics and reactivity on a barrier metal surface are improved so that voids are not produced when an Al-based material layer is charged into small-sized connecting hole by a process sensitive to surface morphology, such as high temperature bias sputtering. By this technique, wettability of a material layer having distinctly inferior wettability with Al, while being excellent in barrier properties, such as a TiON layer, may be improved. As a smoothing operation, bias sputtering, laser irradiation and lamp annealing are proposed. Satisfactory results have been achieved on applying these to a Ti/TiON/Ti system, a Ti/TiON system or to a Ti/TiON/TiSi 2 system.

Inventors

  • 👤 Yukiyasu Sugano
  • 👤 Shinji Minegishi
  • 👤 Kazuhide Koyama
  • 👤 Hirofumi Sumi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 23:20
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/032; H10W20/052; H10W20/0523; H10W20/033; H10W20/035; H10W20/047; H10W20/056

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 85 words
A metallization method comprising the steps of coating at least the bottom and the sidewall of a connecting hole opened in an insulating film on a substrate with a barrier metal layer system including a Ti-based material layer, and then forming an Al-based material layer for filling at least said connecting hole, the improvement comprising performing an operation of increasing the crystal grain size of a surface layer of said barrier metal layer system during said step of coating with said barrier metal layer system.
Claim 2
Dependent Claim 85 words
A metallization method comprising the steps of coating at least the bottom and the sidewall of a connecting hole opened in an insulating film on a substrate with a barrier metal layer system including a Ti-based material layer, and then forming an Al-based material layer for filling at least said connecting hole, the improvement comprising performing an operation of increasing the crystal grain size of a surface layer of said barrier metal layer system during said step of coating with said barrier metal layer system.
Claim 3
Dependent Claim 48 words
A metallization method as claimed in claim 1 wherein said barrier metal layer system has a three-layered structure comprising a Ti layer; one layer selected from the group consisting of a TiON layer, a TiN layer and a TiW layer; and a Ti layer, stacked in this order.
Claim 4
Dependent Claim 45 words
A metallization method as claimed in claim 1 wherein said barrier metal layer system has a two-layered structure comprising a Ti layer and a layer selected from the group consisting of a TiON layer, a TiN layer and a TiW layer, stacked in this order.
Claim 5
Dependent Claim 49 words
A metallization method as claimed in claim 1 wherein said barrier metal layer system has a three-layered structure comprising a Ti layer; one layer selected from the group consisting of a TiON layer, a TiN layer and a TiW layer; and a TiSi 2 layer, stacked in this order.
Claim 6
Dependent Claim 14 words
A metallization method as claimed in claim 1 wherein said operation is bias sputtering.
Claim 7
Dependent Claim 14 words
A metallization method as claimed in claim 1 wherein said operation is laser irradiation.
Claim 8
Dependent Claim 14 words
A metallization method as claimed in claim 1 wherein said operation is lamp annealing.

References Cited (Backward Citations)

JPS62113421A Cited
US4782380A Cited
US4784973A Cited
US5162262A Cited
JPH02260630A Cited
JPH03185722A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-02-28 1997-08-30 1998-03-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-02-28 2001-08-30 2002-03-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-02-28 2005-08-30 2006-03-01 $7700.00 Window Closed / Lapsed

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