US5288688A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Thermal recording material
Assignee: Fujifilm Holdings Corp
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Filing: 1993-03-24
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Granted: 1994-02-22
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Expires: 2013-03-24
Abstract
Abstract Disclosed is a thermal recording material having, on a support, a heat-sensitive coloring layer containing an electron-donating colorless dye, an isocyanate compound and an amino compound. The storage stability of the raw stock material as well as the color image stability of the material are excellent.
Inventors
- 👤 Hiroshi Kawakami
- 👤 Chiyoshi Nozaki
- 👤 Ken Iwakura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 05:01
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M5/333; B41M5/3333
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
291 words
A thermal recording material comprising, on a support, a heat-sensitive coloring layer containing an electron-donating colorless dye, an isocyanate compound and an amino compound, wherein the amino compound is one represented by formula (I): ##STR5## wherein X represents a direct bond, --CO--, --SO 2 --, --CONH-- or --SO 2 NH--; R 1 , R 2 , and R 3 each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a sulfonyloxy group, an oxycarbonyl group, a carbamoyl group, a sulfamoyl group, an oxysulfonyl group, an acyl group, a sulfonyl group, a halogen atom, a nitro group, a cyano group, a hydroxyl group, --CONH 2 , --SO 2 NH 2 , --CONHNH 2 , --SO 2 NHNH 2 or a group represented by formula (II): ##STR6## wherein y represents a divalent group; R 4 and R 5 each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an acyl group, a sulfonyl group, a halogen atom, a nitro group or a cyano group; X 2 represents a direct bond, --CO--, --SO 2 --, --CONH-- or --SO 2 NH--; and the R 1 , R 2 , R 3 , R 4 and R 5 substituents may optionally be substituted, and R 1 and R 2 , and R 4 and R 5 each may be bonded to each other to form a ring; wherein the electron-donating colorless dye is a black-coloring fluoran compound substituted by an arylamino group at the 2-position, a hydrogen atom, a halogen atom or an alkyl group at the 3-position and an amino group at the 6-position, said amino group being further substituted by an alkyl group, a cycloalkyl group, an alkoxyalkyl group or a tetrahydrofurfuryl group.
Claim 2
Dependent Claim
291 words
A thermal recording material comprising, on a support, a heat-sensitive coloring layer containing an electron-donating colorless dye, an isocyanate compound and an amino compound, wherein the amino compound is one represented by formula (I): ##STR5## wherein X represents a direct bond, --CO--, --SO 2 --, --CONH-- or --SO 2 NH--; R 1 , R 2 , and R 3 each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a sulfonyloxy group, an oxycarbonyl group, a carbamoyl group, a sulfamoyl group, an oxysulfonyl group, an acyl group, a sulfonyl group, a halogen atom, a nitro group, a cyano group, a hydroxyl group, --CONH 2 , --SO 2 NH 2 , --CONHNH 2 , --SO 2 NHNH 2 or a group represented by formula (II): ##STR6## wherein y represents a divalent group; R 4 and R 5 each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an acyl group, a sulfonyl group, a halogen atom, a nitro group or a cyano group; X 2 represents a direct bond, --CO--, --SO 2 --, --CONH-- or --SO 2 NH--; and the R 1 , R 2 , R 3 , R 4 and R 5 substituents may optionally be substituted, and R 1 and R 2 , and R 4 and R 5 each may be bonded to each other to form a ring; wherein the electron-donating colorless dye is a black-coloring fluoran compound substituted by an arylamino group at the 2-position, a hydrogen atom, a halogen atom or an alkyl group at the 3-position and an amino group at the 6-position, said amino group being further substituted by an alkyl group, a cycloalkyl group, an alkoxyalkyl group or a tetrahydrofurfuryl group.
Claim 3
Dependent Claim
25 words
The thermal recording material as claimed in claim 1, in which the isocyanate compound is an aromatic isocyanate compound having 2 or more --NCO groups.
Claim 4
Dependent Claim
20 words
The thermal recording material as claimed in claim 1, in which the amino compound has 2 or more amino groups.
Claim 5
Dependent Claim
69 words
The thermal recording material as claimed in claim 3, in which the amino compound is one represented by formula (III): ##STR7## wherein Z represents a divalent group; and R 6 , R 7 , R 8 and R 9 each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an acyl group, a sulfonyl group, a halogen atom, a nitro group or a cyano group.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-02-21 | 1997-08-23 | 1998-02-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-02-21 | 2001-08-23 | 2002-02-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-02-21 | 2005-08-23 | 2006-02-22 | $7700.00 | Window Closed / Lapsed |