US5287421A
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All-optical modulation in crystalline organic semiconductor waveguides
Assignee: University of Southern California
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Filing: 1993-01-11
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Granted: 1994-02-15
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Expires: 2013-01-11
Abstract
Abstract All-optical modulation occurs in crystalline organic semiconductor waveguides (10a) grown by the ultrahigh vacuum process of organic molecular-beam deposition onto substrates (10b). Two light beams with wavelengths of 1.06 and 0.514 (my)m from a first source (12) and a second source (34), respectively, may be used as the guided and the pump light sources, respectively. A resonant non-linear coefficient at room temperature of 5.4*10-5 cm2/W at 1.06 (my)occurs at a pump intensity of 1.0 W/cm2. This large non-linear effect is attributed to free electron-hole pairs produced by the dissociation of excitons generated by the short wavelength beam. A carrier lifetime of (17+-1) us, which determines the modulator switching time, is in good agreement with theoretical predictions. This appears to be the first observation of free-carrier-induced index modulation in crystalline organic waveguides.
Inventors
- 👤 Stephen R. Forrest
- 👤 De Yu Zang
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 19:09
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/35; G02F1/355; G02F1/361; G02F1/365; G02F1/01; G02F1/061; G02F1/065; G02F1/3515
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
88 words
An improved method of modulating light in at least one waveguide, comprising: (a) providing said at least one waveguide; (b) introducing light from a first source into said waveguide; (c) introducing light from a second source at an angle to said waveguide to cause modulation of said light from said first source, wherein the improvement comprises fabricating said waveguide from a crystalline organic aromatic semiconductor compound having a resonant non-linear coefficient of at least 10 -6 cm -2 /W at room temperature and grown in a quasi-epitaxial structure.
Claim 2
Dependent Claim
88 words
An improved method of modulating light in at least one waveguide, comprising: (a) providing said at least one waveguide; (b) introducing light from a first source into said waveguide; (c) introducing light from a second source at an angle to said waveguide to cause modulation of said light from said first source, wherein the improvement comprises fabricating said waveguide from a crystalline organic aromatic semiconductor compound having a resonant non-linear coefficient of at least 10 -6 cm -2 /W at room temperature and grown in a quasi-epitaxial structure.
Claim 3
Dependent Claim
23 words
The method of claim 1 wherein said crystalline organic aromatic semiconductor compound comprises a polyacene compound having at least two fused benzene rings.
Claim 4
Dependent Claim
14 words
The method of claim 2 wherein said crystalline organic aromatic semiconductor compound is planar.
Claim 5
Dependent Claim
15 words
The method of claim 3 wherein said crystalline organic aromatic semiconductor compound comprises 3,4,9,10-perylenetetracarboxylic dianhydride.
Claim 6
Dependent Claim
19 words
The method of claim 1 wherein said light from said first source has a wavelength of about 1.06 μm.
Claim 7
Dependent Claim
18 words
The method of claim 1 wherein said light from said source has a wavelength of about 0.514 μm.
Claim 8
Dependent Claim
52 words
The method of claim 1 wherein said waveguide is formed in the shape of a strip having a substantially rectangular cross-section and having faceted ends suitable for waveguiding light, with light from said first source introduced into one of said faceted ends and with light from said second source introduced orthogonal thereto.
Claim 9
Dependent Claim
19 words
The method of claim 7 wherein light from said second source is introduced onto the top of said waveguide.
Claim 10
Dependent Claim
88 words
The method of claim 1 wherein light is modulated in a directional coupler switch comprising two waveguides supported on a substrate, said directional coupler comprising (a) a coupled region in which said two waveguides are separated by a first distance and (b) two guiding regions on either side of said coupled region in which said two waveguides are separated by a second distance, said second distance greater than said first distance, said first distance having a value to permit switching of light from one waveguide to the other.
Claim 11
Dependent Claim
54 words
The method of claim 9 wherein light from said first source is introduced into a first of said waveguides and light from said second source is introduced onto the top of at least said first waveguide, with light from said second source causing light in said first waveguide to switch into the other waveguide.
Claim 12
Dependent Claim
25 words
The method of claim 1 wherein said organic semiconductor compound has a carrier lifetime that is reduced by forming said compound in a multiple-quantum-well structure.
Claim 13
Dependent Claim
35 words
The method of claim 1 wherein said organic semiconductor compound has a carrier lifetime that is reduced by electrically injecting holes therein from a contact, and then sweeping them out using an applied electric field.
Claim 14
Dependent Claim
90 words
An improved method of modulating light in at least one waveguide, comprising: (a) providing said at least one waveguide; (b) introducing light from a first source into said waveguide; (c) introducing light from a second source at an angle to said waveguide to cause modulation of said light from said first source, wherein the improvement comprises fabricating said waveguide from a planar stacking crystalline organic aromatic semiconductor compound having a resonant non-linear coefficient of at least 10 -5 cm 2 /W at room temperature and grown in a quasi-epitaxial structure.
Claim 15
Dependent Claim
90 words
An improved method of modulating light in at least one waveguide, comprising: (a) providing said at least one waveguide; (b) introducing light from a first source into said waveguide; (c) introducing light from a second source at an angle to said waveguide to cause modulation of said light from said first source, wherein the improvement comprises fabricating said waveguide from a planar stacking crystalline organic aromatic semiconductor compound having a resonant non-linear coefficient of at least 10 -5 cm 2 /W at room temperature and grown in a quasi-epitaxial structure.
Claim 16
Dependent Claim
21 words
The method of claim 13 wherein said crystalline organic aromatic semiconductor compound comprises a polyacene compound having four fused benzene rings.
Claim 17
Dependent Claim
15 words
The method of claim 14 wherein said crystalline organic aromatic semiconductor compound comprises 3,4,9,10-perylenetetracarboxylic dianhydride.
Claim 18
Dependent Claim
19 words
The method of claim 13 wherein said light from said first source has a wavelength of about 1.06 μm.
Claim 19
Dependent Claim
19 words
The method of claim 13 wherein said light from said second source has a wavelength of about 0.514 μm.
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