Negative photosensitive composition and method for forming a resist pattern by means thereof

Claim 2

A negative photosensitive composition, comprising: (a-1) an aromatic compound having at least two organic groups of formula (I): --OCH.sub.2 OR.sup.1 (I) wherein R 1 is an alkyl group, in its molecule and an alkali-soluble resin having phenolic groups, or (a-2) an alkali-soluble resin having at least two organic groups of the above formula (I) in its molecule; and (b) a photo-acid-generating material, said aromatic compound (a-1), upon acid decomposition of the --OCH 2 OR 1 groups, acting as a cross-linking agent for the alkali-soluble resin.

Claim 3

The negative photosensitive composition according to claim 1, wherein the compound having at least two organic groups of the formula (I) in its molecule, is a compound having the organic groups of the formula (I) substituted for at least two hydroxyl groups of at least one phenol selected from the group consisting of (1) phenols having a structure in which a plurality of structures each having one hydroxyl group bonded to one aromatic ring, are connected directly or via an at least bivalent organic group, (2) polyhydric phenols having a structure in which at least two hydroxyl groups are bonded to one aromatic ring, and (3) polyhydric phenols having a structure in which a plurality of structures each having at least two hydroxyl groups bonded to one aromatic ring, or a plurality of structures including a structure having at least two hydroxyl groups bonded to one aromatic ring and a structure having one hydroxyl group bonded to one aromatic ring, are connected directly or via an at least bivalent organic group.

Claim 4

The negative photosensitive composition according to claim 1, wherein the compound having at least two organic groups of the formula (I) in its molecule, is a compound having the organic groups of the formula (I) substituted for at least two hydroxyl groups of at least one phenol selected from the group consisting of compounds of the following formulas (i) to (iv): ##STR10## wherein each of A 1 and A 6 is a lower alkylene, phenylene or lower alkylenephenylene group which may have a substituent, or a direct bond, R 2 is a hydrogen atom or a lower alkyl or phenyl group which may have a substituent, each of n and m is an integer, provided that either one of n and m is an integer of at least 2, or a compound having the organic groups of formula (I) substituted for at least two hydroxyl groups of a polyhydric phenol having a structure wherein at least two hydroxyl groups are bonded to one aromatic ring.

Claim 5

The negative photosensitive composition according to claim 3, wherein the compound having at least two organic groups of the formula (I) in its molecule, is a compound having the organic groups of the formula (I) substituted for at least two hydroxyl groups of a phenol of the formula (ii).

Claim 6

The negative photosensitive composition according to claim 1, wherein the alkali-soluble resin having at least two organic groups of the formula (I) in its molecule, is a compound having the organic groups of the formula (I) substituted for at least two hydroxyl groups of a polymer having repeating units of the following formula (v) or (vi): ##STR11## wherein each of R 3 or R 7 is a hydrogen atom or a lower alkyl group.

Claim 7

The negative photosensitive composition according to claim 5, wherein the alkali-soluble resin having at least two organic groups of the formula (I) in its molecule, is a compound having the organic groups of the formula (I) substituted for at least two hydroxyl groups of a polymer having repeating units of the formula (vi).

Claim 8

The negative photosensitive composition according to claim 1, wherein the compound having at least two organic groups of the formula (I) in its molecule, is a compound selected from the group consisting of compounds of the following formulas (vii) to (xii): ##STR12##

Claim 9

The negative photosensitive composition according to claim 1, wherein the alkali-soluble resin having at least two organic groups of the formula (I) in its molecule, is a polymer having repeating units of the following formula (xiii) or (xiv): ##STR13##

Claim 10

The negative photosensitive composition according to claim 1, wherein the alkali-soluble resin is a polyvinylphenol.

Claim 11

The negative photosensitive composition according to claim 1, wherein the alkali-soluble resin is a novolak resin.

Claim 12

The negative photosensitive composition according to claim 1, wherein the alkali-soluble resin is a polycondensation product of cresol with formaldhyde.

Claim 13

The negative photosensitive composition according to claim 1, wherein the photo-acid-generating material is at least one member selected from the group consisting of organic halogen compounds, onium salts and sulfonic acid esters.

Claim 14

The negative photosensitive composition according to claim 1, wherein the photo-acid-generating material is an organic halogen compound.

Claim 15

The negative photosensitive composition according to claim 1, which comprises: (a-1) an aromatic compound having at least two organic groups of formula (I): --OCH.sub.2 OR.sup.1 (I) wherein R 1 is an alkyl group, in its molecule and an alkali-soluble resin having phenolic groups, and (b) a photo-acid-generating material, said aromatic compound (a-1), upon acid decomposition of the --OCH 2 OR 1 groups, acting as a cross-linking agent for the alkali-soluble resin, wherein the compound (a-1) having at least two organic groups of formula (I) in its molecule, is present in an amount ranging from 1-50 parts by weight, and the photo-acid-generating material is present in an amount ranging from 0.05 to 20 parts by weight, per 100 parts by weight of the alkali-soluble resin.

Claim 16

The negative photosensitive composition according to claim 14, wherein the compound having at least two organic groups of the formula (I) in its molecule, is from 5 to 30 parts by weight, and the photo-acid-generating material is from 0.1 to 10 parts by weight, per 100 parts by weight of the alkali-soluble resin.

Claim 17

The negative photosensitive composition according to claim 1, which comprises (a-2) an alkali-soluble resin having two organic groups of the formula (I) in its molecule, and (b) a photo-acid-generating material, wherein the photo-acid-generating material is from 1 to 100 parts by weight, per 100 parts by weight of the alkali-soluble resin having at least two organic groups of the formula (I) in its molecule.

Claim 18

The negative photosensitive composition according to claim 16, wherein the photo-acid-generating material is from 5 to 50 parts by weight, per 100 parts by weight of the alkali-soluble resin having at least two organic group of the formula (I) in its molecule.

Claim 19

The negative photosensitive composition according to claim 1, which contains a phenothiazine as a sensitizer.