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US5284732A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic material

Assignee: Fujifilm Holdings Corp
•
Filing: 1993-06-09
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Granted: 1994-02-08
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Expires: 2013-06-09
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Abstract

Abstract A silver halide light-sensitive material containing a hydrazine compound represented by formula (I): ##STR1## wherein L 1 represents a single bond, --O--, --S--, --NR 6 --, --CO--, SO 2 --, --P(O) (G 2 R 6 )-- or a combination thereof; L 2 represents --SO 2 NR 6 --, --NR 6 SO 2 NR 6 --, --CONR 6 --, --NR 6 CONR 6 -- or --G 2 P(O) (G 2 R 6 )NR 6 --; G 1 represents --CO--, --SO 2 --, --SO--, --COCO--, a thiocarbonyl group, an iminomethylene group or --P(O) (G 2 R 6 )--; G 2 represents a single bond, --O-- or --NR 6 --; R 1 represents an aliphatic group or an aromatic group; R 2 , R 3 , and R 4 each represent a divalent aliphatic group or a divalent aromatic group; R 5 represents a hydrogen atom, an aliphatic group, an aromatic group, an alkoxy group, an aryloxy group or an amino group; R 6 represents a hydrogen atom, an aliphatic group or an aromatic group; m represents 0 or 1; and X - represents a counter anion or a counter anion moiety of an intramolecular salt, as a nucleating agent. The light-sensitive material exhibits high processing stability even in rapid processing to provide a ultrahigh contrast negative image for photomechanical processing.

Inventors

  • 👤 Kazumi Nii
  • 👤 Toshihide Ezoe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 19:43
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/061

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 199 words
A silver halide light-sensitive material comprising a support and a silver halide emulsion layer and containing a compound represented by formula (I): ##STR12## wherein L 1 represents a single bond, --O--, --S--, --NR 6 --, --CO--, SO 2 --, --P(O) (G 2 R 6 )-- or a combination thereof; L 2 represents --SO 2 NR 6 --, --NR 6 SO 2 NR 6 --, --CONR 6 --, --NR 6 CONR 6 -- or --G 2 R 6 )NR 6 --; G 1 represents --CO--, --SO 2 --, --SO--, --COCO--, a thiocarbonyl group, an iminomethylene group or --P(O) (G 2 R 6 )--; G 2 represents a single bond, --O-- or --NR 6 --; R 1 represents an aliphatic group or an aromatic group; R 2 , R 3 , and R 4 each represent a divalent aliphatic group or a divalent aromatic group; R 5 represents a hydrogen atom, an aliphatic group, an aromatic group, an alkoxy group, an aryloxy group or an amino group; R 6 represents a hydrogen atom, an aliphatic group or an aromatic group; m represents 0 or 1; and X - represents a counter anion or a counter anion moiety of an intramolecular salt.
Claim 2
Dependent Claim 199 words
A silver halide light-sensitive material comprising a support and a silver halide emulsion layer and containing a compound represented by formula (I): ##STR12## wherein L 1 represents a single bond, --O--, --S--, --NR 6 --, --CO--, SO 2 --, --P(O) (G 2 R 6 )-- or a combination thereof; L 2 represents --SO 2 NR 6 --, --NR 6 SO 2 NR 6 --, --CONR 6 --, --NR 6 CONR 6 -- or --G 2 R 6 )NR 6 --; G 1 represents --CO--, --SO 2 --, --SO--, --COCO--, a thiocarbonyl group, an iminomethylene group or --P(O) (G 2 R 6 )--; G 2 represents a single bond, --O-- or --NR 6 --; R 1 represents an aliphatic group or an aromatic group; R 2 , R 3 , and R 4 each represent a divalent aliphatic group or a divalent aromatic group; R 5 represents a hydrogen atom, an aliphatic group, an aromatic group, an alkoxy group, an aryloxy group or an amino group; R 6 represents a hydrogen atom, an aliphatic group or an aromatic group; m represents 0 or 1; and X - represents a counter anion or a counter anion moiety of an intramolecular salt.
Claim 3
Dependent Claim 46 words
The silver halide light-sensitive material as in claim 1, wherein said aliphatic group for R 1 is an alkyl group having from 1 to 20 carbon atoms, and said aromatic group for R 1 is a monocyclic or bicyclic aryl group, or an unsaturated heterocyclic group.
Claim 4
Dependent Claim 61 words
The silver halide light-sensitive material as in claim 1, wherein said divalent aliphatic group for R 2 , R 3 or R 4 is an alkylene group having from 1 to 20 carbon atoms, and said divalent aromatic group for R 2 , R 3 or R 4 is a monocyclic or bicyclic arylene group, or an unsaturated divalent heterocyclic group.
Claim 5
Dependent Claim 44 words
The silver halide light-sensitive material as in claim 1, wherein said L 1 represents --SO 2 NR 6 --, --NR 6 SO 2 NR 6 --, --CONR 6 --, --NR 6 CONR 6 --, or --G 2 (P)O(G 2 R 6 )NR 6 --.
Claim 6
Dependent Claim 41 words
The silver halide light-sensitive material as in claim 1, wherein said aliphatic group for R 5 is an alkyl group having from 1 to 4 carbon atoms, and said aromatic group for R 5 is a monocyclic or bicyclic aryl group.
Claim 7
Dependent Claim 15 words
The silver halide light-sensitive material as in claim 1, wherein said G 1 represents --CO--.
Claim 8
Dependent Claim 33 words
The silver halide light-sensitive material as in claim 1, wherein said compound of formula (I) is contained in an amount of from 1.0×10 -6 to 5×10 -2 mole per mole of silver halide.
Claim 9
Dependent Claim 33 words
The silver halide light-sensitive material as in claim 7, wherein said compound of formula (I) is contained in an amount of from 1.0×10 -5 to 2×10 -2 mole per mole of silver halide.
Claim 10
Dependent Claim 23 words
The silver halide light-sensitive material as in claim 1, wherein said compound of formula (I) is incorporated into the silver halide emulsion layer.
Claim 11
Dependent Claim 29 words
The silver halide light-sensitive material as in claim 1, wherein silver halide grains of the silver halide emulsion layer are silver chloride, silver chlorobromide, silver iodobromide or silver iodochlorobromide.
Claim 12
Dependent Claim 22 words
The silver halide light-sensitive material as in claim 10, wherein said silver halide grains comprise at least 60 mol% of silver chloride.
Claim 13
Dependent Claim 33 words
The silver halide light-sensitive material as in claim 10, wherein said silver halide grains comprise at least 70 mol% of silver bromide with a silver iodide content being not more than 10 mol%.
Claim 14
Dependent Claim 24 words
The silver halide light-sensitive material as in claim 10, wherein said silver halide grins have a mean grain size of 0.7 μm or less.

References Cited (Backward Citations)

US4383948A Cited
US4824774A Cited
US4988604A Cited
US4994365A Cited
US5229248A Cited
US5126227A Cited
US5213944A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-02-07 1997-08-09 1998-02-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-02-07 2001-08-09 2002-02-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-02-07 2005-08-09 2006-02-08 $7700.00 Window Closed / Lapsed

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