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US5280000A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst for olefin polymerization and process for producing olefin polymer using the catalyst

Assignee: Sumitomo Chemical Co Ltd
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Filing: 1986-10-09
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Granted: 1994-01-18
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Expires: 2006-10-09
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Abstract

Abstract The present invention relates to a novel catalyst used for homopolymerization of an olefin of 2 or more carbon atoms or for copolymerization of two or more olefins of 2 or more carbon atoms, as well as to a process for producing an olefin polymer using said catalyst. High molecular olefin polymers can be produced at a high yield, by homopolymerizing an olefin or copolymerizing olefins using a catalyst system consisting of a transition metal compound of the general formula M(R) l (OR') m X n- (l+m) and an aluminoxane or a catalyst system comprising a transition metal compound of the general formula M(R) l (OR') m X n- (l+m), an aluminoxane and an organic compound having at least 2 hydroxyl groups.

Inventors

  • 👤 Masahiro Kakugo
  • 👤 Tatsuya Miyatake
  • 👤 Yoshio Kawai
  • 👤 Akinobu Shiga
  • 👤 Kooji Mizunuma

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 07:37
CPC Classifications
C; C08; C08F; C08F10/00; Y; Y10; Y10S; Y10S526/00; Y10S526/943

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 298 words
A catalyst for olefin polymerization consisting of: a catalyst compound (A) which is a transition metal compound represented by the general formula M(R) l (OR') m X n- (l+m) (wherein M represents a transition metal atom selected from the group consisting of Ti, Zr, Hf and V; R and R' each represents a hydrocarbon group of 1 to 20 carbon atoms; X represents a halogen atom; l, m and n represent numbers satisfying l≧0, m≧0 and n-(l-m)≧0; and n corresponds to the valency of the transition metal), a catalyst component (B) which is an aluminoxane obtained by the reaction of a trialkylaluminum and water, and a catalyst compound (C) which is an organic compound having at least 2 hydroxyl groups, represents by the general formula (V) and (VI) ##STR5## (wherein R 5 represents hydrogen or a hydrocarbon group of 1 to 6 carbon atoms); R 1 , R 2 , R 3 and R 4 each represents a hydrocarbon group of 1 to 20 carbon atoms, a hydroxyl group, a nitro group, a nitrile group, a hydrocarbyloxy group or a halogen atom, and R 1 , R 2 , R 3 and R 4 may be the same or different; n' is 0 or an integer of 1 or larger and represents the times of repetition of the unit Y; y, y' and y", z, z' and z" each represents the number of a substituent bonding to an aromatic ring, y, y', z and z' each represents 0 or an integer of 1 to 4, y" and z" each represents 0 or an integer of 1 to 2 wherein component (C) is prereacted with component (A), the ratio of component (A) to component (C) being 1:1, and the ratio of Al to the transition metal (M) being 10-10,000.
Claim 2
Dependent Claim 298 words
A catalyst for olefin polymerization consisting of: a catalyst compound (A) which is a transition metal compound represented by the general formula M(R) l (OR') m X n- (l+m) (wherein M represents a transition metal atom selected from the group consisting of Ti, Zr, Hf and V; R and R' each represents a hydrocarbon group of 1 to 20 carbon atoms; X represents a halogen atom; l, m and n represent numbers satisfying l≧0, m≧0 and n-(l-m)≧0; and n corresponds to the valency of the transition metal), a catalyst component (B) which is an aluminoxane obtained by the reaction of a trialkylaluminum and water, and a catalyst compound (C) which is an organic compound having at least 2 hydroxyl groups, represents by the general formula (V) and (VI) ##STR5## (wherein R 5 represents hydrogen or a hydrocarbon group of 1 to 6 carbon atoms); R 1 , R 2 , R 3 and R 4 each represents a hydrocarbon group of 1 to 20 carbon atoms, a hydroxyl group, a nitro group, a nitrile group, a hydrocarbyloxy group or a halogen atom, and R 1 , R 2 , R 3 and R 4 may be the same or different; n' is 0 or an integer of 1 or larger and represents the times of repetition of the unit Y; y, y' and y", z, z' and z" each represents the number of a substituent bonding to an aromatic ring, y, y', z and z' each represents 0 or an integer of 1 to 4, y" and z" each represents 0 or an integer of 1 to 2 wherein component (C) is prereacted with component (A), the ratio of component (A) to component (C) being 1:1, and the ratio of Al to the transition metal (M) being 10-10,000.
Claim 3
Dependent Claim 38 words
A catalyst for olefin polymerization according to claim 1, wherein in the catalyst component (A), the M of the transition metal compound represented by the general formula M(R) l (OR') m X n- (l+m) is titanium or zirconium.
Claim 4
Dependent Claim 42 words
A catalyst for olefin polymerization according to claim 1, wherein in the catalyst component (A), the M of the transition metal compound represented by the general formula M(R) l (OR') m X n- (l+m) is titanium or zirconium, l=0, m>0 and n-m≧0.
Claim 5
Dependent Claim 31 words
A catalyst for olefin polymerization accoriding to claim 1, wherein in the catalyst component (A), the general formula M(R) l (OR') m X n- (l+m) is titanium tetrachloride or zirconium tetrachloride.
Claim 6
Dependent Claim 39 words
A catalyst for olefin polymerization according to claim 1, wherein in the catalyst component (A), the R and R' of the general formula M(R) l (OR') m X n- (l+m) are each an alkyl group or an aryl group.
Claim 7
Dependent Claim 38 words
A catalyst for olefin polymerization according to claim 1, wherein in the catalyst component (A), the R is a methyl, ethyl, phenyl or benzyl group and the R' is an n-propyl, isopropyl, n-butyl, t-butyl or a phenyl group.
Claim 8
Dependent Claim 37 words
A catalyst for olefin polymerization according to claim 1, wherein in the catalyst component (A), the general formula M(R) l (OR') m X n- (l+m) is tetraisopropoxytitanium, tetra-n-butoxytitanium, tetra-t-butoxytitanium, diphenoxytitanium dichloride, dinaphthoxytitanium dichloride, tetraisopropoxyzirconium, tetra-n-butoxyzirconium or tetra-t-butoxyzirconium.
Claim 9
Dependent Claim 28 words
A catalyst for olefin polymerization according to claims 1, 2, 3, 4, 5, 6 or 7, wherein in the catalyst component (B), the trialkylaluminum is trimethylaluminum or triethylaluminum.
Claim 10
Dependent Claim 43 words
A catalyst for olefin polymerization according to claims 1, 2, 3, 4, 5, 6 or 7, wherein the catalyst component (C) is a compound represented by the general formula ##STR6## wherein y"' and z"' are 0 or an integer from 1 to 3.
Claim 11
Dependent Claim 28 words
A catalyst for olefin polymerization according to claim 9, wherein the catalyst component (C) is a compound in which the y, y"', z and Z"' are 1, respectively.
Claim 12
Dependent Claim 23 words
A catalyst for olefin polymerization according to claim 10, wherein the catalyst component (C) is a compound in which the n' is 1.
Claim 13
Dependent Claim 28 words
A catalyst for olefin polymerization according to claim 11, wherein the catalyst component (C) is a compound in which the n' is 1 and the Y is --S--.
Claim 14
Dependent Claim 49 words
A catalyst for olefin polymerization according to claims 1, 2, 3, 4, 5, 6 or 7, wherein in the catalyst component (C), the R 1 , R 2 , R 3 and R 4 are each an alkyl group of 1 to 10 carbon atoms or an aryl group.
Claim 15
Dependent Claim 39 words
A catalyst for olefin polymerization according to claim 13, wherein in the catalyst component (C), the R 1 , R 2 , R 3 and R 4 are each a methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl or t-butyl group.
Claim 16
Dependent Claim 17 words
A catalyst for olefin polymerization according to claim 12, wherein the catalyst component (C) is 2,2'-dihydroxy-3,3'-di-t-butyl-5,5'-dimethyldiphenyl sulfide.
Claim 17
Dependent Claim 36 words
A catalyst for olefin polymerization according to claim 8, wherein the catalyst component (C) is a compound represented by the general formula ##STR7## wherein y"' and z"' are 0 or an integer from 1 to 3.
Claim 18
Dependent Claim 23 words
A catalyst for olefin polymerization according to claim 9, wherein the catalyst component (C) is a compound in which the n' is 1.
Claim 19
Dependent Claim 23 words
A catalyst for olefin polymerization according to claim 16, wherein the catalyst component (C) is a compound in which the n' is 1.
Claim 20
Dependent Claim 41 words
A catalyst for olefin polymerization according to claim 8, wherein the catalyst component (C), the R 1 , R 2 , R 3 and R 4 are each an alkyl group of 1 to 10 carbon atoms or an aryl group.

References Cited (Backward Citations)

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JPS5819309A Cited
JPS5865708A Cited
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JPS6035005A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-01-17 1997-07-19 1998-01-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-01-17 2001-07-19 2002-01-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-01-17 2005-07-19 2006-01-18 $7700.00 Window Closed / Lapsed

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