Glass coating with improved adhesion and weather resistance

Claim 2

A compound of formula I [HO[Si(L).sub.2 -O-]n-Si(OE).sub.2 -R-X-].sub.k T (I) wherein n is 1 to 100, and L is methyl, isopropyl, --CH 2 CH 2 CF 3 , tert-butyl, cyclohexyl or phenyl, k is 2 to 4, E is methyl or ethyl, R is ethylene or trimethylene, X is --NHCONH--, --NHCOO--, --S--, --NHCO-- or a direct bond, where the --NH-- groups is attached to R, and T is, when k is 2 and X is a direct bond, --NHCONH--, or T is, when X is --NHCONH--, the residue of a diisocyanate or a triisocyanate after removal of 2 or 3 NCO groups, or T is, when X is --NHCOO--, the residue of a diol, triol or tetraol or of a poly(dimethylsiloxane)alkanepolyol after removal of 2, 3 or 4 OH groups or T is, when X is --S--, alkylene of 1 to 12 carbon atoms, alkanetriyl of 3 to 8 carbon atoms or alkanetetrayl of 4 to 10 carbon atoms, or T is, when X is --NHCO--, alkylene of 2 to 10 carbon atoms or arylene of 6 to 10 carbon atoms.

Claim 3

A compound according to claim 1 wherein n is 1, L is phenyl, k is 2 or 3, E is ethyl, R is trimethylene, X is --NHCONH--, --NHCOO--, --S-- or --NHCO--, when X is --NHCONH-- T is a residue of a diisocyanate, when X is --NHCOO--, T is a residue of a diol, when X is --S--, T is alkylene of 1 to 8 carbon atoms, and when X is --NHCO--, T is alkylene of 2 to 8 carbon atoms.

Claim 4

A compound according to claim 2 wherein X is --NHCONH--.

Claim 5

A compound according to claim 2 wherein, when X is --S--, T is alkylene of 2 to 4 carbon atoms.

Claim 6

A compound according to claim 2 wherein, when X is --NHCO--, T is alkylene of 4 to 6 carbon atoms.

Claim 7

A compound according to claim 1 wherein T is the radical derived from a diisocyanate, triisocyanate or mixture thereof selected from the group consisting of ethylene diisocyanate, 1,2-diisocyanato-propane, 1,3-diisocyanatopropane, 1,6-diisocyanatohexane, 1,2-diisocyanato-cyclohexane, 1,3-diisocyanatocyclohexane, 1,4-diisocyanatobenzene; bis (4-isocyanatocyclohexyl)methane, bis-(4-isocyanatocyclohexenyl) methane, bis(4-isocyanatophenyl)-methane, 1,2- and 1,4-toluene diisocyanate; 3,3'-dichloro-4,4'-diisocyanatobiphenyl; tris(4-isocyanatophenyl)methane, 1,5-diisocyanato-naphthalene, hydrogenated toluene diisocyanate; 1-isocyanatomethyl-5-isocyanato-1,3-3-trimethylcyclohexane (=isophorone diisocyanate); 1,3,5-tris(6-isocyanatohexyl) biuret, 1,6-diisocyanato-2,2-4-(2,4,4)-trimethyl-hexane, 2,2'-diisocyanatodiethyl fumarate; 1,5-diisocyanato-1-carboxypentane; 1,2-, 1,3-, 1,6-, 1,7-, 1,8-, 2,7- and 2,3-diisocyanatonaphthalene; 2,4- and 2,7-diisocyanato-1-methylnaphthalene; 1,4-diisocyanatomethylcyclo-hexane; 1,3-diisocyanato-6(7)-methyl-naphthalene; 4,4'-diisocyanatobiphenyl; 4,4'-diisocyanato-3,3'-dimethoxy-bisphenyl; 3,3'- and 4,4'-diisocyanato-2,2'-dimethyl biphenyl; bis-(4-isocyanatophenyl) ethane; and bis(4-isocyanatophenyl ether.

Claim 8

A compound according to claim 6 wherein T is the radical derived from a dicyclohexylmethane-4,4'-diisocyanate.

Claim 9

A compound of formula I according to claim 1 wherein n is 1, L is phenyl, k is 2 or 3, E is ethyl, R is trimethylene, X is --NHCONH-- and T is a residue of a diisocyanate or a triisocyanate.

Claim 10

A compound according to claim 1 wherein T is the residue of a diol, triol or tetraol or of a poly(dimethylsiloxane) alkanepolyol selected from the group consisting of ##STR29## wherein R is --CH 2 CH 2 CH 2 OH, --CH 2 CH 2 CH(OH)CH 3 , --(CH 2 ) 3 )--O--CH 2 CH(OH)CH 2 OH, --(CH 2 ) 3 N(CH 2 CH 2 OH) 2 ), or --(CH 2 ) 4 --CH(OH)CH 2 OH, and n 1 and n 2 are integer from 2 to 50, with the proviso that n 1 and n 2 is not greater than 60%, or of

Claim 11

2 Butanediol, 1,3-butanediol, 1,4 butanediol, 1,2-cyclohexane diol, 1,2-cyclooctanediol, 1,3-cyclopentanediol, 1,2-decanediol, 1,10-decanediol, dicyclohexyl-4,4'-diol, 2,2-diethyl-1,3-propane diol, 2,5-dimethyl-2,5-hexanediol, 2,4-dimethyl-2,4-pentane diol, ethylene glycol, 1,7-heptanediol, 1,2-hexanediol, 1,5-hexanediol, 1,6-hexanediol, 2-methyl-2,4-pentanediol, 1,8-octanediol, pentaerythritol, 1,5-pentanediol, 1,14-tetradecanediol, polyethylene glycol, polypropylene glycol, polybutylene glycol, neopentyl glycol, trimethyololpropane.

Claim 12

2 Butanediol, 1,3-butanediol, 1,4 butanediol, 1,2-cyclohexane diol, 1,2-cyclooctanediol, 1,3-cyclopentanediol, 1,2-decanediol, 1,10-decanediol, dicyclohexyl-4,4'-diol, 2,2-diethyl-1,3-propane diol, 2,5-dimethyl-2,5-hexanediol, 2,4-dimethyl-2,4-pentane diol, ethylene glycol, 1,7-heptanediol, 1,2-hexanediol, 1,5-hexanediol, 1,6-hexanediol, 2-methyl-2,4-pentanediol, 1,8-octanediol, pentaerythritol, 1,5-pentanediol, 1,14-tetradecanediol, polyethylene glycol, polypropylene glycol, polybutylene glycol, neopentyl glycol, trimethyololpropane.

Claim 13

The compound of formula I according to claim 1 which is ##STR30##