US5256706A
Expired / Lapsed
US
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Cross-linkage surface-modifed micaceous particulates and coating compositions containing the same
Assignee: BASF Corp
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Filing: 1991-02-11
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Granted: 1993-10-26
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Expires: 2011-02-11
Abstract
Abstract Compounds useful for improving the intra-film binding of micaceous particulates in films formed from coating compositions which contain such micaceous particulates comprise urethanes or ureas which are the reaction products of silylalkyl- or silylaryl isocyanates with blocked or unblocked alcohols, aminoalcohols, or polydiol alcohols. The compounds may also be the reaction products of silylalkyl- or silylarylamines with half-blocked diisocyanates which are themselves the reaction products of a diisocyanate with a blocked or unblocked alcohol, aminoalcohol, or polydiol alcohol. Micaceous particulates which have been surface modified by reaction with these compounds, as well as coating compositions comprising such surface-modified micaceous particulates, and coated substrates are also disclosed.
Inventors
- 👤 Clint W. Carpenter
- 👤 Thomas G. Savino
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 18:16
CPC Classifications
C; C09; C09D; C09D7/00; C09D7/40; C09D7/60; C09D7/61; C09D7/62; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C09C; C09C1/00; C09C1/40; C09C1/405; C09C3/00; C09C3/12; C01; C01P; C01P2004/00; C01P2004/20; C01P2004/60; C01P2004/61; C01P2004/62; C01P2004/80; C01P2004/82; C01P2004/84; C01P2006/00; C01P2006/60; C08; C08K; C08K3/00; C08K3/34; C08K9/00; C08K9/08
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
239 words
A compound for use in the surface-modification of micaceous particulates in coating compositions comprising a compound having the formula ##STR23## wherein R 1 , R 2 , and R 3 may be the same or different and are selected from alkyl of from one to ten carbon atoms, alkoxyl of from one to ten carbon atoms, alkoxylalkoxyl of from two to ten carbon atoms, alkanoyloxy of from two to ten carbon atoms, or halogen, with the proviso that R 1 , R 2 , and R 3 may not all be alkyl; A is a divalent radical selected from straight or branched alkylene of from one to twelve carbon atoms, phenylene, or phenylene substituted with halogen, alkyl of from one to four carbon atoms, or alkoxyl of from one to four carbon atoms; X is a divalent radical selected from --O-- or --NH--; B is a direct valence bond or is a divalent group having the formula ##STR24## wherein D is a residue derived from the hypothetical removal of the two isocyanate groups from a diisocyanate molecule, and X is a divalent group selected from --O-- and --NH--; ##STR25## wherein n is an integer of from zero to one thousand, R 6 is hydrogen, alkyl of from one to eight carbon atoms, or ##STR26## R 5 is selected from polyols having at least one hydroxyl group, and blocked polyols wherein said hydroxy groups are blocked by hydroxy protecting groups.
Claim 2
Dependent Claim
239 words
A compound for use in the surface-modification of micaceous particulates in coating compositions comprising a compound having the formula ##STR23## wherein R 1 , R 2 , and R 3 may be the same or different and are selected from alkyl of from one to ten carbon atoms, alkoxyl of from one to ten carbon atoms, alkoxylalkoxyl of from two to ten carbon atoms, alkanoyloxy of from two to ten carbon atoms, or halogen, with the proviso that R 1 , R 2 , and R 3 may not all be alkyl; A is a divalent radical selected from straight or branched alkylene of from one to twelve carbon atoms, phenylene, or phenylene substituted with halogen, alkyl of from one to four carbon atoms, or alkoxyl of from one to four carbon atoms; X is a divalent radical selected from --O-- or --NH--; B is a direct valence bond or is a divalent group having the formula ##STR24## wherein D is a residue derived from the hypothetical removal of the two isocyanate groups from a diisocyanate molecule, and X is a divalent group selected from --O-- and --NH--; ##STR25## wherein n is an integer of from zero to one thousand, R 6 is hydrogen, alkyl of from one to eight carbon atoms, or ##STR26## R 5 is selected from polyols having at least one hydroxyl group, and blocked polyols wherein said hydroxy groups are blocked by hydroxy protecting groups.
Claim 3
Dependent Claim
14 words
A compound in accordance with claim 1 wherein B is a direct valence bond.
Claim 4
Dependent Claim
44 words
A compound as defined by claim 1 wherein B is a divalent group having the formula ##STR27## where D is a diisocyanate moiety derived from the hypothetical removal of the two isocyanate functional groups from a diisocyanate molecule, and X is --O-- or --NH--.
Claim 5
Dependent Claim
29 words
A compound as defined by claim 2 having the formula ##STR28## wherein A, R 1 , R 2 , R 3 , and R 5 are as defined therein.
Claim 6
Dependent Claim
29 words
A compound as defined by claim 2 having the formula ##STR29## wherein A, R 1 , R 2 , R 3 , and R 5 are as defined therein.
Claim 7
Dependent Claim
34 words
A compound as defined by claim 2 having the formula ##STR30## wherein A, R 1 , R 2 , R 3 , R 5 , R 6 , and n are as defined therein.
Claim 8
Dependent Claim
34 words
A compound as defined by claim 2 having the formula ##STR31## wherein A, R 1 , R 2 , R 3 , R 5 , R 6 , and n are as defined therein.
Claim 9
Dependent Claim
31 words
A compound as defined by claim 3 having the formula ##STR32## wherein A, D, R 1 , R 2 , R 3 , and R 5 , are as defined therein.
Claim 10
Dependent Claim
31 words
A compound as defined by claim 3 having the formula ##STR33## wherein A, D, R 1 , R 2 , R 3 , and R 5 , are as defined therein.
Claim 11
Dependent Claim
34 words
A compound as defined by claim 3 having the formula ##STR34## wherein A, D, R 1 , R 2 , R 3 , R 5 , R 6 and n are as defined therein.
Claim 12
Dependent Claim
35 words
A compound as defined by claim 3 having the formula ##STR35## wherein A, D, R 1 , R 2 , R 3 , R 5 , R 6 , and n are as defined therein.
Claim 13
Dependent Claim
28 words
A compound as defined in claim 1 wherein R 1 , R 2 , and R 3 are selected from alkoxyl of from one to ten carbon atoms.
Claim 14
Dependent Claim
33 words
A compound as defined by claim 3 wherein the group D is a divalent group selected from methylene, ethylene, or straight chain or branched chain alkylene of from three to six carbon atoms.
Claim 15
Dependent Claim
28 words
A compound as defined by claim 3 wherein the group D is a divalent group selected from cycloalkylene and substituted cycloalkylene of from five to twelve carbon atoms.
Claim 16
Dependent Claim
28 words
A compound as defined by claim 3 wherein the group D is a divalent group selected from phenylene, substituted phenylene, biphenylene, substituted biphenylene, diarylalkylene, naphthylenyl, and substituted naphthalenyl.
Claim 17
Dependent Claim
11 words
A compound as defined by claim 1 wherein n is 0.
Claim 18
Dependent Claim
17 words
A compound as defined by claim 1 wherein n is an integer of from 1 to 1000.
Claim 19
Dependent Claim
17 words
A compound as defined by claim 6 wherein n is an integer of from 1 to 1000.
Claim 20
Dependent Claim
17 words
A compound as defined by claim 7 wherein n is an integer of from 1 to 1000.
Claim 21
Dependent Claim
17 words
A compound as defined by claim 10 wherein n is an integer of from 1 to 1000.
Claim 22
Dependent Claim
17 words
A compound as defined by claim 11 wherein n is an integer of from 1 to 1000.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-10-25 | 1997-04-26 | 1997-10-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-10-25 | 2001-04-26 | 2001-10-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-10-25 | 2005-04-26 | 2005-10-26 | $7700.00 | Window Closed / Lapsed |