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US5250626A Expired / Lapsed US ⏱️ 0.0 years remaining

Miscible blends of polyphosphazenes and acidic functional polymers

Assignee: Eastman Kodak Co
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Filing: 1990-11-08
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Granted: 1993-10-05
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Expires: 2010-11-08
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Abstract

Abstract There are disclosed miscible blends of etheric polyphosphazenes and polymers bearing acidic functional groups such as poly(vinylphenol) or polymers containing acrylic acid.

Inventors

  • 👤 Christine J. T. Landry
  • 👤 Wayne T. Ferrar
  • 👤 David M. Teegarden

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 01:00
CPC Classifications
C; C08; C08L; C08L85/00; C08L85/02

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 183 words
A miscible blend comprising a) an etheric polyphosphazene comprising recurring units represented by the structural formula: ##STR5## wherein R 1 and R 2 each independently represents the formula --(R 3 --O) n --R 4 where n is 0 to 50 and n is 1 or more in at least half of the total substituents, R 3 is randomly alkyl having from 2 to 4 carbon atoms between oxygen atoms, R 4 is alkyl, alkylaryl, alkenyl, haloalkyl, aryl, substituted aromatic, aminoalkyl or thioalkyl, W and X each independently represents ##STR6## R 6 , R 7 and R 8 each independently represents H, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, phenyl, substituted aromatic, aminoalkyl or thioalkyl, and (b) a polymer made from a monomer or combination of monomers selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, citriconic acid, 1-propene-1,2,3-tricarboxylic acid, a-chloroacrylic acid, fumaric acid, chlorofumaric acid, itaconic acid, vinylbenzoic acid, phenolic polymers (e.g., phenol formaldehyde resins), vinylphenol, N-(hydroxyphenyl)acrylamide, N-(hydroxyphenyl)methacryla-mide, hydroxyphenyl acrylate, hydroxyphenyl methacrylate, 3-sulfopropylmethacrylate, 2-acrylamido-2-methylpropane sulfonic acid, vinyl alcohol, vinyl chloride, 2-ethenylbenzenesulfonic acid, 4-ethenylbenzenesulfonic acid, 2-isopropenylbenzenesulfonic acid, 4-isopropenylbenzenesulfonic acid, α,α-bis(trifluoromethyl)-4-ethenylbenzenemethanol, and α,α-bis(trifluoromethyl)-4-isopropenylbenzenemethanol.
Claim 2
Dependent Claim 183 words
A miscible blend comprising a) an etheric polyphosphazene comprising recurring units represented by the structural formula: ##STR5## wherein R 1 and R 2 each independently represents the formula --(R 3 --O) n --R 4 where n is 0 to 50 and n is 1 or more in at least half of the total substituents, R 3 is randomly alkyl having from 2 to 4 carbon atoms between oxygen atoms, R 4 is alkyl, alkylaryl, alkenyl, haloalkyl, aryl, substituted aromatic, aminoalkyl or thioalkyl, W and X each independently represents ##STR6## R 6 , R 7 and R 8 each independently represents H, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, phenyl, substituted aromatic, aminoalkyl or thioalkyl, and (b) a polymer made from a monomer or combination of monomers selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, citriconic acid, 1-propene-1,2,3-tricarboxylic acid, a-chloroacrylic acid, fumaric acid, chlorofumaric acid, itaconic acid, vinylbenzoic acid, phenolic polymers (e.g., phenol formaldehyde resins), vinylphenol, N-(hydroxyphenyl)acrylamide, N-(hydroxyphenyl)methacryla-mide, hydroxyphenyl acrylate, hydroxyphenyl methacrylate, 3-sulfopropylmethacrylate, 2-acrylamido-2-methylpropane sulfonic acid, vinyl alcohol, vinyl chloride, 2-ethenylbenzenesulfonic acid, 4-ethenylbenzenesulfonic acid, 2-isopropenylbenzenesulfonic acid, 4-isopropenylbenzenesulfonic acid, α,α-bis(trifluoromethyl)-4-ethenylbenzenemethanol, and α,α-bis(trifluoromethyl)-4-isopropenylbenzenemethanol.
Claim 3
Dependent Claim 70 words
A miscible blend as in claim 1 wherein the polymer (b) comprises recurring units at least 5% of which are represented by the structural formula: ##STR7## wherein R 9 represents H or CH 3 and R 10 represents CO 2 H, C 6 H 4 CO 2 H, C 6 H 4 OH, C 6 H 4 SO 3 H, or C 6 H 4 C(CF 3 ) 2 OH.
Claim 4
Dependent Claim 7 words
A miscible blend comprising poly(vinylphenol) and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene].
Claim 5
Dependent Claim 7 words
A miscible blend comprising poly(vinylphenol) and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene].
Claim 6
Dependent Claim 7 words
A miscible blend comprising poly(vinylphenol) and poly[bis(methoxyethoxyethoxyethoxy)phosphazene].
Claim 7
Dependent Claim 7 words
A miscible blend comprising poly(vinylphenol) and poly[bis(methoxyethoxyethoxyethoxy)phosphazene].
Claim 8
Dependent Claim 7 words
A miscible blend comprising poly(styrene-co-vinylphenol) and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene].
Claim 9
Dependent Claim 7 words
A miscible blend comprising poly(styrene-co-vinylphenol) and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene].
Claim 10
Dependent Claim 8 words
A miscible blend comprising poly(styrene-co-styrene-4-sulfonic acid) and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene].
Claim 11
Dependent Claim 8 words
A miscible blend comprising poly(styrene-co-styrene-4-sulfonic acid) and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene].
Claim 12
Dependent Claim 8 words
A miscible blend comprising poly(styrene-4-carboxylic acid) and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene].
Claim 13
Dependent Claim 8 words
A miscible blend comprising poly(styrene-4-carboxylic acid) and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene].
Claim 14
Dependent Claim 9 words
A miscible blend comprising poly(butyl acrylate-co-acrylic acid) and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene].
Claim 15
Dependent Claim 9 words
A miscible blend comprising poly(butyl acrylate-co-acrylic acid) and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene].

References Cited (Backward Citations)

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US4055520A Cited
US4073824A Cited
US4061606A Cited
US4559117A Cited
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USPTO Annuity & Maintenance Windows

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