US5247050A
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Fluorinated quinoline polymers and the corresponding fluorinated monomers
Assignee: Resonac Corp
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Filing: 1991-08-13
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Granted: 1993-09-21
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Expires: 2011-08-13
Abstract
Abstract A new class of polymers is provided as well as the monomers used for their preparation. The polymers provided in accordance with practice of the present invention include repeating units comprising one or more quinoline groups, wherein at least a portion of the repeating units includes a hexafluoroisopropylidene (6F) group or a 1-aryl-2,2,2-trifluoroethylidene (3F) group, or both. The hexafluoroisopropylidene group is referred to herein as a "6F" group and has the following structure: ##STR1## The "6F" group includes a tetravalent carbon atom bound to two trifluoromethyl moieties with its other two bonds forming linkages in the polymer chain. the 1-aryl-2,2,2-trifluoroethylidene group is referred to herein as "3F" group and has the following structure: ##STR2## wherein Ar' is an aryl group. The "3F" group comprises a tetravalent carbon atom bound to one trifluoromethyl moiety and one aryl group with its other two bonds forming linkages in the polymer chain.
Inventors
- 👤 Neil H. Hendricks
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 06:14
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/0683; C08G73/0688; C07; C07C; C07C45/00; C07C45/004; C07C45/61; C07C45/67; C07C45/68; C07C45/70; C07C45/71; C07C49/00; C07C49/76; C07C49/80; C07C49/813; C07C49/84; C08G61/00; C08G61/12
Claims Analysis
Total Claims: 31
Claim 1
Independent Claim
32 words
A polymer comprising repeating units Which comprise one or more quinoline groups wherein at least a portion of the repeating units include a group selected from hexafluoroisopropylidene (6F) and 1-aryl-2,2,2-trifluoroethyllidene (3F) groups.
Claim 2
Dependent Claim
32 words
A polymer comprising repeating units Which comprise one or more quinoline groups wherein at least a portion of the repeating units include a group selected from hexafluoroisopropylidene (6F) and 1-aryl-2,2,2-trifluoroethyllidene (3F) groups.
Claim 3
Dependent Claim
31 words
A polymer as is claimed in claim 1 wherein the quinoline groups comprise at least 10% by weight of the and fluorine comprises at least 1% by weight of the polymer.
Claim 4
Dependent Claim
108 words
A polymer having repeating units of the general formula: ##STR35## wherein R and R' are independently selected from the group consisting of hydrogen and phenyl, and wherein each of the R and R' groups can be the same or different, where Y is --G-- and X is --G-- or --Ar--G--Ar--, wherein X and Y can be the same or different, wherein --G-- is a divalent radical selected from the group consisting of nil, --O--, --N(H), --S--, carbonyl, sulfone, hexafluoroisopropylidene (6F), hexafluoroisopropylidene diphenoxy, 1-aryl-2,2,2-trifluoroethylene (3F), and phenylene, and wherein Ar is a divalent aromatic group, where either X or Y or both include a 3F or a 6F group.
Claim 5
Dependent Claim
108 words
A polymer having repeating units of the general formula: ##STR35## wherein R and R' are independently selected from the group consisting of hydrogen and phenyl, and wherein each of the R and R' groups can be the same or different, where Y is --G-- and X is --G-- or --Ar--G--Ar--, wherein X and Y can be the same or different, wherein --G-- is a divalent radical selected from the group consisting of nil, --O--, --N(H), --S--, carbonyl, sulfone, hexafluoroisopropylidene (6F), hexafluoroisopropylidene diphenoxy, 1-aryl-2,2,2-trifluoroethylene (3F), and phenylene, and wherein Ar is a divalent aromatic group, where either X or Y or both include a 3F or a 6F group.
Claim 6
Dependent Claim
109 words
A polymer having repeating units of the general formula: ##STR36## wherein R and R' are independently selected from the group consisting of hydrogen and phenyl, and wherein each of the R and R' groups can be the same or different, where Y is --G-- and X is --G-- or --Ar--G--Ar--, wherein Y and X can be the same or different, where in --G-- is a divalent radical selected from the group consisting of nil, --O--, --N(H), --S--, carbonyl, sulfone, hexafluoroisopropylidene (6F), hexafluoroisopropylidene diphenoxy, 1-aryl-2,2,2-trifluoroethylidene (3F), and phenylene, and wherein Ar is a divalent aromatic group, where either X or Y or both include a 3F or a 6F group.
Claim 7
Dependent Claim
109 words
A polymer having repeating units of the general formula: ##STR36## wherein R and R' are independently selected from the group consisting of hydrogen and phenyl, and wherein each of the R and R' groups can be the same or different, where Y is --G-- and X is --G-- or --Ar--G--Ar--, wherein Y and X can be the same or different, where in --G-- is a divalent radical selected from the group consisting of nil, --O--, --N(H), --S--, carbonyl, sulfone, hexafluoroisopropylidene (6F), hexafluoroisopropylidene diphenoxy, 1-aryl-2,2,2-trifluoroethylidene (3F), and phenylene, and wherein Ar is a divalent aromatic group, where either X or Y or both include a 3F or a 6F group.
Claim 8
Dependent Claim
108 words
A polymer having repeating units of the general formula: ##STR37## wherein R and R' are independently selected from the group consisting of hydrogen and phenyl, and wherein each of the R and R' groups can be the same or different, where Y is --G-- and X is --G-- or --Ar--G--Ar--, wherein Y and X can be the same or different, wherein --G-- is a divalent radical selected from the group consisting of nil, --O--, --N(H), --S--, carbonyl, sulfone, hexafluoroisopropylidene (6F), hexafluoroisopropylidene diphenoxy, 1-aryl-2,2,2-trifluoroethylidene (3F), and phenylene, and wherein Ar is a divalent aromatic group, where either X or Y or both include a 3F or a 6F group.
Claim 9
Dependent Claim
108 words
A polymer having repeating units of the general formula: ##STR37## wherein R and R' are independently selected from the group consisting of hydrogen and phenyl, and wherein each of the R and R' groups can be the same or different, where Y is --G-- and X is --G-- or --Ar--G--Ar--, wherein Y and X can be the same or different, wherein --G-- is a divalent radical selected from the group consisting of nil, --O--, --N(H), --S--, carbonyl, sulfone, hexafluoroisopropylidene (6F), hexafluoroisopropylidene diphenoxy, 1-aryl-2,2,2-trifluoroethylidene (3F), and phenylene, and wherein Ar is a divalent aromatic group, where either X or Y or both include a 3F or a 6F group.
Claim 10
Dependent Claim
108 words
A polymer having repeating units of the general formula: ##STR38## wherein R and R' are independently selected from the group consisting of hydrogen and phenyl, and wherein each of the R and R' groups can be the same or different, where Y is --G-- and X is --G-- or --Ar--G--Ar--, wherein Y and X can be the same or different, wherein --G-- is a divalent radical selected from the group consisting of nil, --O--, --N(H), --S--, carbonyl, sulfone, hexafluoroisopropylidene (6F), hexafluoroisopropylidene diphenoxy, 1-aryl-2,2,2-trifluoroethylidene (3F), and phenylene, and wherein Ar is a divalent aromatic group, where either X or Y or both include a 3F or a 6F group.
Claim 11
Dependent Claim
108 words
A polymer having repeating units of the general formula: ##STR38## wherein R and R' are independently selected from the group consisting of hydrogen and phenyl, and wherein each of the R and R' groups can be the same or different, where Y is --G-- and X is --G-- or --Ar--G--Ar--, wherein Y and X can be the same or different, wherein --G-- is a divalent radical selected from the group consisting of nil, --O--, --N(H), --S--, carbonyl, sulfone, hexafluoroisopropylidene (6F), hexafluoroisopropylidene diphenoxy, 1-aryl-2,2,2-trifluoroethylidene (3F), and phenylene, and wherein Ar is a divalent aromatic group, where either X or Y or both include a 3F or a 6F group.
Claim 12
Dependent Claim
28 words
A polymer having repeating units of the general formula: ##STR39## wherein R, R' and Y are independently hydrogen or phenyl, and Y is selected from the group: ##STR40##
Claim 13
Dependent Claim
28 words
A polymer having repeating units of the general formula: ##STR39## wherein R, R' and Y are independently hydrogen or phenyl, and Y is selected from the group: ##STR40##
Claim 14
Dependent Claim
9 words
A polymer having repeating units of the formula: ##STR41##
Claim 15
Dependent Claim
9 words
A polymer having repeating units of the formula: ##STR41##
Claim 16
Dependent Claim
9 words
A polymer having repeating units of the formula: ##STR42##
Claim 17
Dependent Claim
9 words
A polymer having repeating units of the formula: ##STR42##
Claim 18
Dependent Claim
9 words
A polymer having repeating units of the formula: ##STR43##
Claim 19
Dependent Claim
9 words
A polymer having repeating units of the formula: ##STR43##
Claim 20
Dependent Claim
9 words
A polymer having repeating units of the formula: ##STR44##
Claim 21
Dependent Claim
9 words
A polymer having repeating units of the formula: ##STR44##
Claim 22
Dependent Claim
15 words
A polymer having repeating units of the formula: ##STR45## wherein Ar is an aryl group.
Claim 23
Dependent Claim
15 words
A polymer having repeating units of the formula: ##STR45## wherein Ar is an aryl group.
Claim 24
Dependent Claim
9 words
A polymer having repeating units of the formula: ##STR46##
Claim 25
Dependent Claim
9 words
A polymer having repeating units of the formula: ##STR46##
Claim 26
Dependent Claim
110 words
A copolymer wherein the repeating units comprise one or more quinoline groups, the copolymer formed by polymerizing a combination of monomers selected from the group consisting of: (a) One or more type AA monomers, one or more type BB monomers and one or more type AB monomers; (b) One or more type AA monomers and one or more type BB monomers, wherein the total number of different type AA and BB monomers is three or greater; and (c) Two or more type AB monomers; Wherein at least one of the monomers in each of the combinations (a), (b) and (c) incorporates a 3F group or a 6F group or both.
Claim 27
Dependent Claim
110 words
A copolymer wherein the repeating units comprise one or more quinoline groups, the copolymer formed by polymerizing a combination of monomers selected from the group consisting of: (a) One or more type AA monomers, one or more type BB monomers and one or more type AB monomers; (b) One or more type AA monomers and one or more type BB monomers, wherein the total number of different type AA and BB monomers is three or greater; and (c) Two or more type AB monomers; Wherein at least one of the monomers in each of the combinations (a), (b) and (c) incorporates a 3F group or a 6F group or both.
Claim 28
Dependent Claim
19 words
A copolymer as is claimed in claim 14 wherein fluorine comprises at least 1% by weight of the copolymer.
Claim 29
Dependent Claim
22 words
A copolymer as is claimed in claim 14, wherein fluorine comprises between about 1% and about 10% by weight of the copolymer.
Claim 30
Dependent Claim
116 words
A copolymer having repeating units of the general formula: ##STR47## wherein R and R' are independently selected from the group consisting of hydrogen and phenyl, and wherein each of the R and R' groups can be the same or different, where Y is --G-- and X is --G-- or --Ar--G--Ar--, wherein X and Y can be the same or different, wherein --G-- is a divalent radical selected from the group consisting of nil, --O--, --N(H), --S--, carbonyl, sulfone, hexafluoroisopropylidene, hexafluoroisopropylidene diphenoxy, 1-aryl-2,2,2-trifluoroethylidene, and phenylene, and wherein Ar is a divalent aromatic group, where Y includes a 3F or a 6F group and wherein W is a divalent radical selected from nil, --O--,--N(H),--S--, carbonyl, sulfone and phenylene.
Claim 31
Dependent Claim
116 words
A copolymer having repeating units of the general formula: ##STR47## wherein R and R' are independently selected from the group consisting of hydrogen and phenyl, and wherein each of the R and R' groups can be the same or different, where Y is --G-- and X is --G-- or --Ar--G--Ar--, wherein X and Y can be the same or different, wherein --G-- is a divalent radical selected from the group consisting of nil, --O--, --N(H), --S--, carbonyl, sulfone, hexafluoroisopropylidene, hexafluoroisopropylidene diphenoxy, 1-aryl-2,2,2-trifluoroethylidene, and phenylene, and wherein Ar is a divalent aromatic group, where Y includes a 3F or a 6F group and wherein W is a divalent radical selected from nil, --O--,--N(H),--S--, carbonyl, sulfone and phenylene.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-09-20 | 1997-03-22 | 1997-09-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-09-20 | 2001-03-22 | 2001-09-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-09-20 | 2005-03-22 | 2005-09-21 | $7700.00 | Window Closed / Lapsed |