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US5246469A Expired / Lapsed US ⏱️ 0.0 years remaining

Fuel stabilization

Assignee: Department of Defence
•
Filing: 1987-07-24
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Granted: 1993-09-21
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Expires: 2007-07-24
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Abstract

Abstract PCT No. PCT/AU87/00235 Sec. 371 Date Feb. 29, 1988 Sec. 102(e) Date Feb. 29, 1988 PCT Filed Jul. 24, 1987 PCT Pub. No. WO88/00914 PCT Pub. Date Feb. 11, 1988.Distillate fuel is stabilized against degradation during storage by inserting into storage tanks solid materials containing polar sites to enable polar condensation of the fuel constituents active in degradation. Polyether or polyester polyurethane open cell foams are the prime solid stabilizers proposed.

Inventors

  • 👤 William Arfelli
  • 👤 Alan Power
  • 👤 Richard Solly

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 23:31
CPC Classifications
C; C10; C10L; C10L1/00

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 126 words
A method for minimizing the chemical degradation of a liquid hydrocarbon distillate fuel during storage for an extended period of time, said liquid hydrocarbon distillate fuel containing cracked products derived from a heavy crude or distillation fraction, said cracked products including chemically unstable species that promote fuel degradation upon storage for an extended period of time leading to a build-up of insoluble particulate material, comprising the step of storing said hydrocarbon fuel in contact with a polymeric solid which is capable of removing or counteracting fuel components catalyzing or participating in degradation reactions and which is selected from the group consisting of polyurethane foam, polyolefin fiber, polyacrylonitrile, cotton, wool, and polyacetate, whereby the amount of said chemically unstable species in said liquid hydrocarbon fuel is reduced.
Claim 2
Independent Claim 126 words
A method for minimizing the chemical degradation of a liquid hydrocarbon distillate fuel during storage for an extended period of time, said liquid hydrocarbon distillate fuel containing cracked products derived from a heavy crude or distillation fraction, said cracked products including chemically unstable species that promote fuel degradation upon storage for an extended period of time leading to a build-up of insoluble particulate material, comprising the step of storing said hydrocarbon fuel in contact with a polymeric solid which is capable of removing or counteracting fuel components catalyzing or participating in degradation reactions and which is selected from the group consisting of polyurethane foam, polyolefin fiber, polyacrylonitrile, cotton, wool, and polyacetate, whereby the amount of said chemically unstable species in said liquid hydrocarbon fuel is reduced.
Claim 3
Dependent Claim 38 words
The method according to claim 1, wherein the polymeric solid is in the form of cellular foam, sponge, mesh, woven fabric, naturally entwined or bound fiber bundles, surface coatings, strips, films, or solids encapsulated in a fuel-permeable container.
Claim 4
Dependent Claim 15 words
The method according to claim 1, wherein the polymeric solid is an open-cell polyurethane foam.
Claim 5
Dependent Claim 15 words
The method according to claim 1, wherein the polymeric solid is a polyether-based polyurethane foam.
Claim 6
Dependent Claim 23 words
The method according to claim 1, wherein the polymeric solid is a polyester-based polyurethane foam and the liquid hydrocarbon fuel contains aromatic hydrocarbons.
Claim 7
Dependent Claim 31 words
The method according to claim 1, wherein the polymeric solid is a polyurethane foam based on poly(diethylene glycol) adipate or poly(oxypropyl) poly(oxyethyl) glycerol or on an acrylonitrile-styrene modified polyoxyalkylene polyether resin.
Claim 8
Dependent Claim 21 words
The method according to claim 1, wherein the polymeric solid is a polyethylene cloth containing heteroatom functional groups or polar additives.
Claim 9
Dependent Claim 14 words
The method according to claim 1, wherein the polymeric solid is poly(1,4-phenylene terephthalamide) cloth.
Claim 10
Dependent Claim 56 words
The method according to claim 1, wherein the polymeric solid is a polyurethane foam and the method of storing the hydrocarbon fuel in contact with the polymeric solid is by adding the polymeric solid to a storage tank containing the fuel in an amount of 1 to 5 grams of polyurethane foam per liter of fuel.
Claim 11
Independent Claim 132 words
A method for minimizing the chemical degradation of a liquid hydrocarbon distillate fuel during storage for an extended period of time, said liquid hydrocarbon distillate fuel containing cracked products derived from a heavy crude or distillation fraction, said cracked products including chemically unstable species that promote fuel degradation upon storage for an extended period of time leading to a build-up of insoluble particulate material, comprising the step of contacting said hydrocarbon fuel with a polymeric solid which is capable of removing or counteracting fuel components catalyzing or participating in degradation reactions and which is selected from the group consisting of polyurethane foam, polyolefin incorporating a polar copolymer, polyamide, Nylon 6--6, polyester fiber, polyacrylonitrile, cotton, wool, and polyacetate, whereby the amount of said chemically unstable species in said liquid hydrocarbon fuel is reduced.
Claim 12
Independent Claim 132 words
A method for minimizing the chemical degradation of a liquid hydrocarbon distillate fuel during storage for an extended period of time, said liquid hydrocarbon distillate fuel containing cracked products derived from a heavy crude or distillation fraction, said cracked products including chemically unstable species that promote fuel degradation upon storage for an extended period of time leading to a build-up of insoluble particulate material, comprising the step of contacting said hydrocarbon fuel with a polymeric solid which is capable of removing or counteracting fuel components catalyzing or participating in degradation reactions and which is selected from the group consisting of polyurethane foam, polyolefin incorporating a polar copolymer, polyamide, Nylon 6--6, polyester fiber, polyacrylonitrile, cotton, wool, and polyacetate, whereby the amount of said chemically unstable species in said liquid hydrocarbon fuel is reduced.

References Cited (Backward Citations)

US2306870A Cited
GB1341693A Cited
US4032510A Cited
US4339246A Cited
US4659334A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-09-20 1997-03-22 1997-09-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-09-20 2001-03-22 2001-09-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-09-20 2005-03-22 2005-09-21 $7700.00 Window Closed / Lapsed

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