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US5245113A Expired / Lapsed US ⏱️ 0.0 years remaining

Decontamination of PCB contaminated solids

Assignee: Dynecology Inc
•
Filing: 1991-05-23
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Granted: 1993-09-14
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Expires: 2011-05-23
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Abstract

Abstract A method and apparatus for removal of PCBs or similar refractory organic substances from solid surfaces, such as soil or hardware, e.g., capacitors and transformers containing a charge or residue of PCB or similar fluids. Such toxic substances are volatilized from substrates contaminated therewith by contacting them with carrier gas, such as a mixture of hydrogen, carbon monoxide and steam. The carrier gas and volatilized components are introduced into a partial oxidation zone of a gas generator where PCBs are completely destroyed at a temperature range of 2800° F. to 3500° F.

Inventors

  • 👤 Helmut W. Schulz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 16:07
CPC Classifications
A; A62; A62D; A62D3/00; A62D3/30; A62D3/38; B; B09; B09C; B09C1/00; B09C1/06; F; F23; F23G; F23G5/00; F23G5/02; F23G5/027; F23G7/00; F23G7/14; A62D2101/00; A62D2101/20; A62D2101/22; F23G2201/00; F23G2201/50; F23G2206/00; F23G2206/20; F23G2206/201; F23G2900/00; F23G2900/54001; F23G2900/70; F23G2900/7011; Y; Y02; Y02E; Y02E20/00; Y02E20/30

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 175 words
A process for decontamination of sealed electrical hardware capacitors and transformers containing absorbed or absorbed polychlorinated biphenyls which comprises: a) opening said polychlorinated biphenyl-contaminated hardware to the atmosphere; b) loading said polychlorinated biphenyl-contaminated hardware into a furnace; c) contacting said contaminated hardware in said furnace with a stream of carrier reducing gas comprising hydrogen and carbon monoxide at a temperature in the range of 750° to 950° F. effecting vaporization of absorbed and adsorbed polychlorinated biphenyls therefrom; d) passing said reducing gas stream containing vaporized polychlorinated biphenyls into a partial oxidation reaction zone maintained at a temperature in the range of 2500° to 3500° F. at the point of entry of said stream; e) simultaneously destroying said polychlorinated biphenyls and generating a reducing gas comprising hydrogen and carbon monoxide in said reaction zone by partial oxidation of a carbonaceous fuel with oxygen and steam at an autogenous temperature in the range of 2500° to 3500° F.; and f) supplying reducing gas from said reaction zone to said furnace as a source of said carrier gas.
Claim 2
Dependent Claim 175 words
A process for decontamination of sealed electrical hardware capacitors and transformers containing absorbed or absorbed polychlorinated biphenyls which comprises: a) opening said polychlorinated biphenyl-contaminated hardware to the atmosphere; b) loading said polychlorinated biphenyl-contaminated hardware into a furnace; c) contacting said contaminated hardware in said furnace with a stream of carrier reducing gas comprising hydrogen and carbon monoxide at a temperature in the range of 750° to 950° F. effecting vaporization of absorbed and adsorbed polychlorinated biphenyls therefrom; d) passing said reducing gas stream containing vaporized polychlorinated biphenyls into a partial oxidation reaction zone maintained at a temperature in the range of 2500° to 3500° F. at the point of entry of said stream; e) simultaneously destroying said polychlorinated biphenyls and generating a reducing gas comprising hydrogen and carbon monoxide in said reaction zone by partial oxidation of a carbonaceous fuel with oxygen and steam at an autogenous temperature in the range of 2500° to 3500° F.; and f) supplying reducing gas from said reaction zone to said furnace as a source of said carrier gas.
Claim 3
Dependent Claim 27 words
A process according to claim 1 wherein the reaction zone is in the hearth zone of a solid fuel gasifier wherein solid fuel is reacted with oxygen.
Claim 4
Dependent Claim 27 words
A process according to claim 1 wherein the reaction zone is an unpacked reactor wherein carbonaceous fuel is converted to reducing gas by partial oxidation with oxygen.

References Cited (Backward Citations)

US3627289A Cited
US4778606A Cited
US4699667A Cited
US4794871A Cited
WO1988000610A1 Cited
EP0284156A1 Cited
US4982039A Cited
US4977839A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-09-13 1997-03-15 1997-09-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-09-13 2001-03-15 2001-09-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-09-13 2005-03-15 2005-09-14 $7700.00 Window Closed / Lapsed

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