US5237006A
Expired / Lapsed
US
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Thermoplastic resin compositions containing polyphenylene ethers and polyesters
Assignee: General Electric Co
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Filing: 1990-09-28
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Granted: 1993-08-17
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Expires: 2010-09-28
Abstract
Abstract Improved thermoplastic compositions are disclosed, comprising a polyethylene ether resin capped with an epoxytriazine compound; a thermoplastic polyester; and a radial block copolymer which itself comprises at least about 60% by weight of a polymerized vinyl aromatic material, and about 5%-40% of a polymerized conjugated diene monomer.
Inventors
- 👤 John B. Yates, III
- 👤 Alexandros Hasson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 17:30
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08L67/03; C08G; C08G65/00; C08G65/34; C08G65/48; C08G65/485; C08L67/025; C08L69/00; C08L69/005; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/126; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
59 words
A thermoplastic composition comprising: a) polyphenylene ether capped with an epoxytriazine compound; b) thermoplastic polyester; and c) a radial block copolymer which comprises about 60% to about 95% by weight polymerized vinyl aromatic material, and about 40% to about 5% by weight polymerized conjugated diene monomer, said copolymer having at least three polymer chains which form the radial configuration.
Claim 2
Dependent Claim
59 words
A thermoplastic composition comprising: a) polyphenylene ether capped with an epoxytriazine compound; b) thermoplastic polyester; and c) a radial block copolymer which comprises about 60% to about 95% by weight polymerized vinyl aromatic material, and about 40% to about 5% by weight polymerized conjugated diene monomer, said copolymer having at least three polymer chains which form the radial configuration.
Claim 3
Dependent Claim
73 words
The composition of claim 1 wherein the polyphenylene ether comprises a plurality of structural units of the formula: ##STR8## wherein each Q 1 is independently halogen, primary or secondary lower alkyl, phenyl, haloalkyl, aminoalkyl, hydrocarbonoxy, or halohydro-carbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms; and each Q 2 is independently hydrogen, halogen, primary or secondary lower alkyl, phenyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy as defined for Q 1 .
Claim 4
Dependent Claim
12 words
The composition of claim 2 wherein the polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene ether).
Claim 5
Dependent Claim
27 words
The composition of claim 2 wherein the polyphenylene ether is derived from a monomer selected from the group consisting of 2,6-dimethyl phenol; 2,3,6-trimethyl phenol, and mixtures thereof.
Claim 6
Dependent Claim
40 words
The composition of claim 2 wherein the polyester comprises structural units of the formula ##STR9## where each R 4 is independently a divalent aliphatic, alicyclic, or aromatic hydrocarbon group or polyoxyalkylene group, and A 1 is a divalent aromatic group.
Claim 7
Dependent Claim
20 words
The composition of claim 5 wherein the polyester is a poly(alkylene dicarboxylate), or mixtures of at least two poly(alkylene dicarboxylates).
Claim 8
Dependent Claim
18 words
The composition of claim 6 wherein the poly(alkylene dicarboxylate) is either poly(ethylene terephthalate), poly(butylene terephthalate), or mixtures thereof.
Claim 9
Dependent Claim
30 words
The composition of claim 5 wherein the polyester further comprises units of the formula ##STR10## wherein R 5 is a polyoxyalkylene group, and A 2 is a trivalent aromatic group.
Claim 10
Dependent Claim
54 words
The composition of claim 1 wherein the capped polyphenylene ether is prepared by reacting at least one polyphenylene either polymer with an epoxytriazine compound of the formula ##STR11## wherein R 1 is a divalent aliphatic, alicyclic, heterocyclic, or substituted or unsubstituted aromatic hydrocarbon group, and X is an alkyl, cycloalkyl, aromatic group, or ##STR12##
Claim 11
Dependent Claim
25 words
The composition of claim 9 wherein the epoxytriazine compound is selected from the group consisting of diglycidyl chlorocyanurate, n-butyl glycidyl chlorocyanurate, and mesityl glycidyl chlorocyanurate.
Claim 12
Dependent Claim
20 words
The composition of claim 1 wherein each polymer chain of the radial block copolymer terminates with a substantially non-elastomeric segment.
Claim 13
Dependent Claim
37 words
The composition of claim 1 wherein the radial block copolymer of compound (c) comprises about 70% to about 95% by weight polymerized vinyl aromatic material, and about 30% to about 5% by weight polymerized conjugated diene monomer.
Claim 14
Dependent Claim
42 words
The composition of claim 12 wherein the polymerized vinyl aromatic material is derived from a monomer selected from the group consisting of styrene, chlorostyrene, vinyl toluene, 3-methylstyrene, 4-n-propylstyrene, 4-cyclohexylstyrene, 4-dodecylstyrene, 2-ethyl-4-benzylstyrene, 4-p-tolylstyrene, 4-(4-phenyl-n-butyl)styrene, 1-vinylnpahthalene, 2-vinylnaphthalene, and mixtures of any of these monomers.
Claim 15
Dependent Claim
32 words
The composition of claim 12 wherein the polymerized conjugated diene monomer is derived from the group consisting of 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, piperylene, 3-butyl-1,3-octadiene, phenyl-1,3-butadiene, and mixtures of any of the foregoing compounds.
Claim 16
Dependent Claim
22 words
The composition of claim 1, wherein the weight ratio of component (a) to component (b) ranges from about 60:40 to about 20:80.
Claim 17
Dependent Claim
32 words
The composition of claim 15 wherein the amount of radial block copolymer present ranges from about 1% by weight to about 30% by weight, based on the weight of the entire composition.
Claim 18
Dependent Claim
32 words
The composition of claim 16 wherein the amount of radial block copolymer present ranges from about 5% by weight to about 15% by weight, based on the weight of the entire composition.
Claim 19
Dependent Claim
36 words
The composition of claim 1, further comprising effective amounts of at least one additive selected from the group consisting of flame retardants, plasticizers, stabilizers, antistatic agents, fillers, reinforcing agents, lubricants, colorants, dyes, pigments, and drip retardants.
Claim 20
Dependent Claim
37 words
The composition of claim 17, wherein said radial block copolymer comprises from about 70% to about 95% by weight polymerized vinyl aromatic material, and from about 30% to about 5% by weight non-hydrogenated polymerized conjugated diene monomer.
Claim 21
Dependent Claim
21 words
The composition of claim 19, wherein said polymerized vinyl aromatic material comprises polystyrene, and said polymerized conjugated diene monomer comprises polybutadiene.
Claim 22
Dependent Claim
86 words
A thermoplastic composition comprising: I) at least one copolymer of polyphenylene ether and thermoplastic polyester, and II) a radial block copolymer which itself comprises about 60% to about 95% by weight polymerized vinyl aromatic material, and about 40% to about 5% by weight polymerized conjugated diene monomer, said radial block copolymer having at least three polymer chains which form the radial configuration, each chain terminating with a substantially non-elastomeric segment, said polyphenylene either being capped with an epoxytriazine compound prior to reaction with said thermoplastic polyester.
Claim 23
Dependent Claim
86 words
A thermoplastic composition comprising: I) at least one copolymer of polyphenylene ether and thermoplastic polyester, and II) a radial block copolymer which itself comprises about 60% to about 95% by weight polymerized vinyl aromatic material, and about 40% to about 5% by weight polymerized conjugated diene monomer, said radial block copolymer having at least three polymer chains which form the radial configuration, each chain terminating with a substantially non-elastomeric segment, said polyphenylene either being capped with an epoxytriazine compound prior to reaction with said thermoplastic polyester.
Claim 24
Dependent Claim
52 words
The composition of claim 21, wherein the polyphenylene ether is derived from a monomer selected from the group consisting of 2,6-dimethyl phenol; 2,3,6-trimethyl phenol; and mixtures thereof; and wherein the polyester is selected from the group consisting of poly(alkylene dicarboxylates), elastomeric polyesters, polyarylates, polyester copolymers, and mixtures of any of these materials.
Claim 25
Dependent Claim
23 words
The composition of claim 22, wherein the poly(alkylene dicarboxylate) is selected from the group consisting of poly(ethylene terephthalate), poly(butylene terephthalate), and mixtures thereof.
Claim 26
Dependent Claim
25 words
The composition of claim 22, wherein the epoxytriazine compound is selected from the group consisting of diglycidyl chlorocyanurate, n-butyl glycidyl chlorocyanurate and mesityl glycidyl chlorocyanurate.
Claim 27
Dependent Claim
30 words
The composition of claim 22, wherein the polymerized vinyl aromatic material of component (II) is comprised substantially of polystyrene, and the polymerized conjugated diene monomer is comprised substantially of polybutadiene.
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