US5234757A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Expandable films and molded products therefrom
Assignee: Henkel Loctite Corp
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Filing: 1991-04-30
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Granted: 1993-08-10
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Expires: 2011-04-30
Abstract
Abstract A thin, tacky, non-pourable film of incompatible in situ-expandable thermoplastic particles and thermosettable matrix resin that contains an essentially uniform density and thickness across the breadth of the film. The in situ-expandable mass is not pourable yet can be easily dispensed in a uniform manner within a mold and thereafter expanded to the dimensions of the mold. Composites and reinforced compositions, as well as methods of molding, are disclosed.
Inventors
- 👤 Raymond S. Wong
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 01:53
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0085; B; B29; B29B; B29B15/00; B29B15/08; B29B15/10; B29B15/12; B29B15/122; B29C; B29C43/00; B29C43/22; B29C43/24; B29C43/28; B29C44/00; B29C44/34; B29C44/36; B29C44/38; B29C70/00; B29C70/02; B29C70/021; B29C70/025; B29C70/04; B29C70/28; B29C70/40; B29C70/50; B29C70/504; B29C70/58; B29C70/62; B29C70/66; C08J9/32; B29K; B29K2101/00; B29K2101/12; B29K2105/00; B29K2105/04; B29K2105/06; B29K2105/12; B29K2105/16; B29K2105/165; C08J2363/00; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1355; Y10T428/1359; Y10T428/1362; Y10T428/1366; Y10T428/1369; Y10T428/1372; Y10T428/1376; Y10T428/1386; Y10T428/139; Y10T428/1393; Y10T428/249921; Y10T428/249953; Y10T428/249954; Y10T428/249962; Y10T428/249971; Y10T428/249972; Y10T428/249981; Y10T428/249986; Y10T428/249987; Y10T428/249991; Y10T442/00; Y10T442/10; Y10T442/102; Y10T442/164; Y10T442/172; Y10T442/174; Y10T442/184; Y10T442/195; Y10T442/198; Y10T442/60; Y10T442/699
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
98 words
A thin and drapable, non-pourable, in situ-expandible film having a uniform thickness of ±10% variation, of up to about 3.5 millimeters, that contains (i) a non-pourable thermosetting matrix resin system and (ii) particles of a microcellular in situ-expandable thermoplastic polymer containing an expansion agent therein in which both (i) and (ii) are uniformly distributed throughout the film, so that upon expansion of the thermoplastic polymer into microcells in the non-pourable film, the resulting film is a molded thermoset thin film syntactic foam the thickness of which is about 1.01 to about 4 times greater than the non-expanded film.
Claim 2
Dependent Claim
98 words
A thin and drapable, non-pourable, in situ-expandible film having a uniform thickness of ±10% variation, of up to about 3.5 millimeters, that contains (i) a non-pourable thermosetting matrix resin system and (ii) particles of a microcellular in situ-expandable thermoplastic polymer containing an expansion agent therein in which both (i) and (ii) are uniformly distributed throughout the film, so that upon expansion of the thermoplastic polymer into microcells in the non-pourable film, the resulting film is a molded thermoset thin film syntactic foam the thickness of which is about 1.01 to about 4 times greater than the non-expanded film.
Claim 3
Dependent Claim
19 words
The thin and drapable, non-pourable, in situ-expandible film of claim 1 wherein the film is adhered to another material.
Claim 4
Dependent Claim
44 words
The thin and drapable, non-pourable, in situ-expandible film of claim 2 wherein the other material is one or more of thin metal films or foils, fabrics, prepregs, composites derived from the molding of prepregs, other fiber reinforced composites, and syntactic foams of another composition.
Claim 5
Dependent Claim
27 words
The thin and drapable, non-pourable, in situ-expandible film of claim 1 wherein the film has a uniform thickness of between about 1.5 millimeters and about 3 millimeters.
Claim 6
Dependent Claim
68 words
The thin and drapable, non-pourable, in situ-expandible film of claim 4 wherein the film comprises a mass of one or more of staple performance and engineering thermoplastic fibers, the fibers and the non-pourable, in situ-expandable thermoplastic non-fibrous particles are uniformly distributed in the non-pourable matrix resin and the matrix resin contains a thermosetting resin that is incompatible with the thermoplastic polymer of the fibers and the expandable particles.
Claim 7
Dependent Claim
33 words
The thin and drapable, non-pourable, in situ-expandible film of claim 5 wherein the thermoplastic fibers have a T m or T g that is greater than the cure temperature of the matrix resin.
Claim 8
Dependent Claim
33 words
The thin and drapable, non-pourable, in situ-expandible film of claim 5 wherein the thermoplastic fibers have a T m or T g that is greater than the cure temperature of the matrix resin.
Claim 9
Dependent Claim
30 words
The thin and drapable, non-pourable, in situ-expandible film of claim 5 wherein the fiber reinforced film contains the fibers oriented in a direction primarily essentially parallel to the film's surface.
Claim 10
Dependent Claim
35 words
An in situ formed syntactic foam molded article containing staple fibers therein, wherein the fibers are concentrated at the article surfaces obtained by curing the thin and drapable, non-pourable in situ-expandible film of claim 5.
Claim 11
Dependent Claim
16 words
The syntactic foam molded article of claim 9 wherein the fibers are made of polyetheretherketone fibers.
Claim 12
Dependent Claim
16 words
The syntactic foam molded article of claim 9 wherein the fibers are made of polyetherimide fibers.
Claim 13
Dependent Claim
16 words
The syntactic foam molded article of claim 9 wherein the fibers are made of polyethersulfone fibers.
Claim 14
Dependent Claim
18 words
The abrasion resistent syntactic foam molded article of claim 9 wherein the fibers are made of polyaramide fibers.
Claim 15
Dependent Claim
69 words
The thin and drapable, non-pourable, in situ-expandible film of claim 1 wherein the film is reinforced by a mass of one or more staple performance and engineering thermoplastic fibers, the fibers and the non-pourable, in situ-expandable thermoplastic non-fibrous particles are uniformly distributed in the non-pourable matrix resin and the matrix resin contains a thermosetting resin that is incompatible with the thermoplastic polymer of the fibers and the expandable particles.
Claim 16
Dependent Claim
33 words
The thin and drapable, non-pourable, in situ-expandible film of claim 14 wherein the thermoplastic fibers have a T m or T g that is greater than the cure temperature of the matrix resin.
Claim 17
Dependent Claim
34 words
The thin and drapable, non-pourable, in situ-expandible film of claim 15 wherein the thermoplastic polymer of the expandable particles has a T m which is less than the cure temperature of the matrix resin.
Claim 18
Dependent Claim
30 words
The thin and drapable, non-pourable, in situ-expandible film of claim 14 wherein the fiber reinforced film contains the fibers oriented in a direction primarily essentially parallel to the film's surface.
Claim 19
Dependent Claim
35 words
An in situ formed syntactic foam molded article containing staple fibers therein, wherein the fibers are concentrated at the article surfaces obtained by curing the thin and drapable, non-pourable in situ-expandible film of claim 14.
Claim 20
Dependent Claim
20 words
An abrasion resistent syntactic foam article formed by molding the thin and drapable, non-pourable, in situ-expandible film of claim 14.
Claim 21
Dependent Claim
18 words
The abrasion resistent syntactic foam molded article of claim 19 wherein the fibers are made of polyetheretherketone fibers.
Claim 22
Dependent Claim
18 words
The abrasion resistent syntactic foam molded article of claim 19 wherein the fibers are made of polyetherimide fibers.
Claim 23
Dependent Claim
18 words
The abrasion resistent syntactic foam molded article of claim 19 wherein the fibers are made of polyethersulfone fibers.
Claim 24
Dependent Claim
18 words
The abrasion resistent syntactic foam molded article of claim 19 wherein the fibers are made of polyaramide fibers.
Claim 25
Dependent Claim
18 words
The thin and drapable, non-pourable, in situ-expandible film of claim 1 wherein the (ii) particle have different expandabilities.
Claim 26
Dependent Claim
149 words
A thin and drapable, non-pourable film suitable for forming, on molding, a syntactic foam thermoset article, that contains across its breadth (i) an essentially uniform thickness of ±10%, (ii) an essentially uniform density, (iii) a uniform mixture of (1) in situ-expandable thermoplastic particles having a mixed particle size having different expandabilities ranging from about 1 μm to about 1 mm and (2) a thermosettable matrix resin in which (1) and (2) are incompatible throughout the thermal expansion cycle in forming the syntactic foam thermoset article, said film possessing a predetermined shape and thickness of up to 3.5 millimeters, for converting it to the syntactic foam thermoset article in which the film a. expands up to 4 times in thickness to the dimensions of the thermoset article, b. without major redistribution of the mass within the film, c. to form a syntactic foam thermoset article having a predetermined density pattern.
Claim 27
Dependent Claim
149 words
A thin and drapable, non-pourable film suitable for forming, on molding, a syntactic foam thermoset article, that contains across its breadth (i) an essentially uniform thickness of ±10%, (ii) an essentially uniform density, (iii) a uniform mixture of (1) in situ-expandable thermoplastic particles having a mixed particle size having different expandabilities ranging from about 1 μm to about 1 mm and (2) a thermosettable matrix resin in which (1) and (2) are incompatible throughout the thermal expansion cycle in forming the syntactic foam thermoset article, said film possessing a predetermined shape and thickness of up to 3.5 millimeters, for converting it to the syntactic foam thermoset article in which the film a. expands up to 4 times in thickness to the dimensions of the thermoset article, b. without major redistribution of the mass within the film, c. to form a syntactic foam thermoset article having a predetermined density pattern.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-08-09 | 1997-02-08 | 1997-08-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-08-09 | 2001-02-08 | 2001-08-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-08-09 | 2005-02-08 | 2005-08-10 | $7700.00 | Window Closed / Lapsed |