US5230893A
Expired / Lapsed
US
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Stable agrochemical compositions including alpha-unsaturated amine derivative and acid incorporated into a carrier
Assignee: Takeda Pharmaceutical Co Ltd
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Filing: 1991-12-23
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Granted: 1993-07-27
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Expires: 2011-12-23
Abstract
Abstract Stable agrochemical compositions are provided by incorporating at least one of the alpha -unsaturated amine derivatives having the following formula: <CHEM> wherein one of X<1> and X<2> is an electron attracting group and the other is hydrogen or an electron attracting group; R<1> is a group attached through a nitrogen atom; R<2> is hydrogen or a group attached through a carbon, nitrogen, or oxygen atom; n is an integer of 0, 1, or 2; and A is a substituted or unsubstituted heterocyclic group or a substituted or unsubstituted cyclic hydrocarbon group; and salts thereof, into an agrochemically acceptable solid carrier (clay minerals capable of adsorption (including fuller's earth, terra alba, bentonite, and activated fuller's earth), zeolite, activated charcoal, and beta -cyclodextrin, etc.) under a pH 5.5 or less condition. The agrochemical (pesticidal) compositions exert potent shelf life and light-resistance.
Inventors
- 👤 Yukio Gotou
- 👤 Masatoshi Sawamura
- 👤 Tetsuo Okauchi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 08:43
CPC Classifications
A; A01; A01N; A01N33/00; A01N33/02; A01N35/00; A01N35/08; A01N43/00; A01N43/34; A01N43/40; A01N43/72; A01N43/74; A01N43/78
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
126 words
An agrochemical composition which comprises: (i) at least one α-unsaturated amine derivative having the following formula: ##STR25## wherein B a is a substituted or unsubstituted pyridyl or thiazolyl group, and R 8a , R 9a and R 10a are each independently hydrogen; an alkyl, alkenyl, alkynyl, cycloalkyl, acyl, or alkoxycarbonyl group, or an agrochemically acceptable salt thereof; (ii) an acid whose dissociation constant is at least about 1×10 -3 ; and (iii) an agrochemically acceptable solid carrier which is capable of adsorbing at least 5.0×10 -2 mmol/g of the α-unsaturated amine derivative or salt thereof from a solution or suspension adjusted to a pH less than or equal to 5, both the α-unsaturated amine derivative and the acid each being incorporated into the agrochemically acceptable carrier.
Claim 2
Dependent Claim
126 words
An agrochemical composition which comprises: (i) at least one α-unsaturated amine derivative having the following formula: ##STR25## wherein B a is a substituted or unsubstituted pyridyl or thiazolyl group, and R 8a , R 9a and R 10a are each independently hydrogen; an alkyl, alkenyl, alkynyl, cycloalkyl, acyl, or alkoxycarbonyl group, or an agrochemically acceptable salt thereof; (ii) an acid whose dissociation constant is at least about 1×10 -3 ; and (iii) an agrochemically acceptable solid carrier which is capable of adsorbing at least 5.0×10 -2 mmol/g of the α-unsaturated amine derivative or salt thereof from a solution or suspension adjusted to a pH less than or equal to 5, both the α-unsaturated amine derivative and the acid each being incorporated into the agrochemically acceptable carrier.
Claim 3
Dependent Claim
22 words
The agrochemical composition according to claim 1, in which B a is a group having the formula: ##STR26## wherein Hal is halogen.
Claim 4
Dependent Claim
68 words
The agrochemical composition according to claim 1, comprising a compound of the formula: ##STR27## wherein R 8 b, R 9 b, and R 10 b are each independently hydrogen or an alkyl group, and Hal is halogen, or ##STR28## wherein R 8 c, R 9 c, and R 10 c are each independently hydrogen or an alkyl group, and Hal is halogen, or an agrochemically acceptable salt thereof.
Claim 5
Dependent Claim
21 words
The agrochemical composition according to claim 1, in which the α-unsaturated amine derivative is 1-[N-(6-chloro-3-pyridylmethyl)-N-ethyl]amino-1-methylamino-2-nitroethylene or an agrochemically acceptable salt thereof.
Claim 6
Dependent Claim
52 words
The agrochemical composition according to claim 1, in which the acid is selected from the group consisting of perchloric acid, hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, aspartic acid, citric acid, glutamic acid, oxalic acid, dichloroacetic acid, trichloroacetic acid, fumaric acid, maleic acid, malonic acid, benzenesulfonic acid, and isopropyl acid phosphate.
Claim 7
Dependent Claim
31 words
The agrochemical composition according to claim 1, in which the agrochemically acceptable solid carrier is selected from the group consisting of clay minerals capable of adsorption, zeolite, activated charcoal, and β-cyclodextrin.
Claim 8
Dependent Claim
35 words
The agrochemical composition according to claim 1, in which the solid carrier is selected from the group consisting of montmorillonite-saponite groups having 2:1 crystal structure type form and sepiolite having double-chain crystal structure type form.
Claim 9
Dependent Claim
36 words
The agrochemical composition according to claim 1, in which the agrochemically acceptable solid carrier is selected from the group consisting of montmorillonite, beidellite, nontronite, saponite, hectorite, sauconite, fuller's earth, terra alba, bentonite, and activated fuller's earth.
Claim 10
Dependent Claim
17 words
The agrochemical composition according to claim 1, in which the agrochemically acceptable solid carrier is fuller's earth.
Claim 11
Dependent Claim
29 words
The agrochemical composition according to claim 1, in which contains one or more species of agrochemically active substances in addition to at least one of the α-unsaturated amine derivatives.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1996-07-26 | 1997-01-25 | 1997-07-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-07-26 | 2001-01-25 | 2001-07-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-07-26 | 2005-01-25 | 2005-07-27 | $7700.00 | Window Closed / Lapsed |