US5227145A
Expired / Lapsed
US
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Process for removing nitrogen oxides from exhaust gases
Assignee: Cosmo Oil Co Ltd
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Filing: 1991-12-31
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Granted: 1993-07-13
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Expires: 2011-12-31
Abstract
Abstract A process for removing nitrogen oxides from an exhaust gas by bringing the exhaust gas containing nitrogen oxides into contact with at least one catalyst selected from a polyvalent metal phosphate, a polyvalent metal sulfate or an aluminate of a transition metal of the 4th period of the Periodic Table in an oxidizing atmosphere containing excess oxygen and in the presence of a hydrocarbon or an oxygen containing organic compound. There is also disclosed a process for removing nitrogen oxides from an exhaust gas which comprises bringing the exhaust gas into contact with the above catalyst and then with an oxidation catalyst.
Inventors
- 👤 Yoshiaki Kintaichi
- 👤 Hideaki Hamada
- 👤 Takehiko Ito
- 👤 Motoi Sasaki
- 👤 Fujio Suganuma
- 👤 Mitsunori Tabata
- 👤 Akihiro Kitazume
- 👤 Kazushi Usui
- 👤 Tadao Nakatsuji
- 👤 Hiromitsu Shimizu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 00:27
CPC Classifications
B; B01; B01J; B01J27/00; B01J27/14; B01J27/16; B01J27/18; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9404; B01D53/9409; B01D53/9413; B01D53/9418; B01J27/02; B01J27/053; B01D2251/00; B01D2251/20; B01D2251/208; B01D2255/00; B01D2255/10; B01D2255/102; B01D2255/1023; B01D2255/20; B01D2255/204; B01D2255/2047; B01D2255/206; B01D2255/2063; B01D2255/207; B01D2258/00; B01D2258/01; B01D2258/012; F; F02; F02B; F02B2275/00; F02B2275/14
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
118 words
A process for removing nitrogen oxides from an exhaust gas which comprises bringing the exhaust gas containing nitrogen oxides into contact with at least one catalyst selected from the group consisting of a polyvalent metal phosphate, a polyvalent metal sulfate and an aluminate of a transition metal of the 4th period of the Periodic Table in an oxidizing atmosphere containing excess oxygen and in the presence of a hydrocarbon or an oxygen-containing organic compound, wherein said nitrogen oxides are removed from said exhaust gas by contacting a gaseous mixture consisting essentially of said oxidizing atmosphere containing excess oxygen, said hydrocarbon or said oxygen-containing organic compound and said exhaust gas containing nitrogen oxides with said at least one catalyst.
Claim 2
Dependent Claim
118 words
A process for removing nitrogen oxides from an exhaust gas which comprises bringing the exhaust gas containing nitrogen oxides into contact with at least one catalyst selected from the group consisting of a polyvalent metal phosphate, a polyvalent metal sulfate and an aluminate of a transition metal of the 4th period of the Periodic Table in an oxidizing atmosphere containing excess oxygen and in the presence of a hydrocarbon or an oxygen-containing organic compound, wherein said nitrogen oxides are removed from said exhaust gas by contacting a gaseous mixture consisting essentially of said oxidizing atmosphere containing excess oxygen, said hydrocarbon or said oxygen-containing organic compound and said exhaust gas containing nitrogen oxides with said at least one catalyst.
Claim 3
Dependent Claim
23 words
The process as claimed in claim 1, wherein said exhaust gas containing nitrogen oxides is further brought into contact with an oxidation catalyst.
Claim 4
Dependent Claim
91 words
A process for removing nitrogen oxides from an exhaust gas which comprises bringing the exhaust gas containing nitrogen oxides into contact with a polyvalent metal phosphate catalyst in an oxidizing atmosphere containing excess oxygen and in the presence of a hydrocarbon or an oxygen containing organic compound, wherein said nitrogen oxides are removed from said exhaust gas by contacting a gaseous mixture consisting essentially of said oxidizing atmosphere containing excess oxygen, said hydrocarbon or said oxygen-containing organic compound and said exhaust gas containing nitrogen oxides with said polyvalent metal phosphate catalyst.
Claim 5
Dependent Claim
91 words
A process for removing nitrogen oxides from an exhaust gas which comprises bringing the exhaust gas containing nitrogen oxides into contact with a polyvalent metal phosphate catalyst in an oxidizing atmosphere containing excess oxygen and in the presence of a hydrocarbon or an oxygen containing organic compound, wherein said nitrogen oxides are removed from said exhaust gas by contacting a gaseous mixture consisting essentially of said oxidizing atmosphere containing excess oxygen, said hydrocarbon or said oxygen-containing organic compound and said exhaust gas containing nitrogen oxides with said polyvalent metal phosphate catalyst.
Claim 6
Dependent Claim
91 words
A process for removing nitrogen oxides from an exhaust gas which comprises bringing the exhaust gas containing nitrogen oxides into contact with a polyvalent metal sulphate catalyst in an oxidizing atmosphere containing excess oxygen and in the presence of a hydrocarbon or an oxygen containing organic compound, wherein said nitrogen oxides are removed from said exhaust gas by contacting a gaseous mixture consisting essentially of said oxidizing atmosphere containing excess oxygen, said hydrocarbon or said oxygen-containing organic compound and said exhaust gas containing nitrogen oxides with said polyvalent metal sulphate catalyst.
Claim 7
Dependent Claim
91 words
A process for removing nitrogen oxides from an exhaust gas which comprises bringing the exhaust gas containing nitrogen oxides into contact with a polyvalent metal sulphate catalyst in an oxidizing atmosphere containing excess oxygen and in the presence of a hydrocarbon or an oxygen containing organic compound, wherein said nitrogen oxides are removed from said exhaust gas by contacting a gaseous mixture consisting essentially of said oxidizing atmosphere containing excess oxygen, said hydrocarbon or said oxygen-containing organic compound and said exhaust gas containing nitrogen oxides with said polyvalent metal sulphate catalyst.
Claim 8
Dependent Claim
117 words
A process for removing nitrogen oxides from an exhaust gas which comprises bringing the exhaust gas containing nitrogen oxides into contact with a catalyst composed of an aluminate of a transition metal of the 4th period of the Periodic Table in an oxidizing atmosphere containing excess oxygen and in the presence of a hydrocarbon or an oxygen containing organic compound, wherein said nitrogen oxides are removed from said exhaust gas by contacting a gaseous mixture consisting essentially of said oxidizing atmosphere containing excess oxygen, said hydrocarbon or said oxygen-containing organic compound and said exhaust gas containing nitrogen oxides with said catalyst composed of an aluminate of a transition metal of the 4th period of the Periodic Table.
Claim 9
Dependent Claim
117 words
A process for removing nitrogen oxides from an exhaust gas which comprises bringing the exhaust gas containing nitrogen oxides into contact with a catalyst composed of an aluminate of a transition metal of the 4th period of the Periodic Table in an oxidizing atmosphere containing excess oxygen and in the presence of a hydrocarbon or an oxygen containing organic compound, wherein said nitrogen oxides are removed from said exhaust gas by contacting a gaseous mixture consisting essentially of said oxidizing atmosphere containing excess oxygen, said hydrocarbon or said oxygen-containing organic compound and said exhaust gas containing nitrogen oxides with said catalyst composed of an aluminate of a transition metal of the 4th period of the Periodic Table.
Claim 10
Dependent Claim
29 words
The process as claimed in claim 1, 2, or 3, wherein said polyvalent metal phosphate is tin phosphate, zirconium phosphate, titanium phosphate, vanadium phosphate, niobium phosphate or cerium phosphate.
Claim 11
Dependent Claim
43 words
The process as claimed in claim 1, 2 or 4, wherein said polyvalent metal sulfate is copper sulfate, magnesium sulfate, zinc sulfate, cadmium sulfate, barium sulfate, aluminum sulfate, zirconium sulfate, vanadium sulfate, chromium sulfate, manganese sulfate, iron sulfate, cobalt sulfate or nickel sulfate.
Claim 12
Dependent Claim
42 words
The process as claimed in claim 1, 2 or 5, wherein said catalyst composed of a transition metal of the 4th period of the Periodic Table is chromium aluminate, manganese aluminate, iron aluminate, cobalt aluminate, nickel aluminate, copper aluminate or zinc aluminate.
Claim 13
Dependent Claim
33 words
The process as claimed in claim 2, wherein said oxidation catalyst is composed of a noble metal, a base metal or a material having a perovskite crystal structure supported on a porous carrier.
Claim 14
Dependent Claim
47 words
The process as claimed in claim 9, wherein said noble metal is platinum, palladium, rhodium, ruthenium or iridium; said base metal is lanthanum, cerium, copper, iron or molybdenum; and said material having a perovskite crystal structure is cobalt lanthanum trioxide, iron lanthanum trioxide or cobalt strontium trioxide.
Claim 15
Dependent Claim
44 words
The process as claimed in claim 1, 2, 3, 4 or 5, wherein said hydrocarbon or said oxygen containing organic compound is used in an amount of 20 to 2000% in excess of the theoretical amount required for the reduction of NO x .
Claim 16
Dependent Claim
16 words
The process as claimed in claim 11, wherein said hydrocarbon is a gaseous or liquid hydrocarbon.
Claim 17
Dependent Claim
20 words
The process as claimed in claim 12, wherein said gaseous hydrocarbon is methane, ethane, propane, butane, ethylene, propylene or butylene.
Claim 18
Dependent Claim
19 words
The process as claimed in claim 12, wherein said liquid hydrocarbon is gasoline, kerosene, gas oil or heavy oil.
Claim 19
Dependent Claim
23 words
The process as claimed in claim 11, wherein said oxygen containing organic compound is an alcohol, an ether, an ester or a ketone.
Claim 20
Dependent Claim
34 words
The process as claimed in claim 1, 2, 3, 4 or 5, wherein said nitrogen oxides are removed from the exhaust gas at a temperature in the range of from 100° to 800° C.
Claim 21
Dependent Claim
48 words
The process as claimed in claim 1, 2, 3, 4 or 5, wherein said at least one catalyst is in the form of a catalyst bed and the exhaust gas is introduced into the catalyst bed at a space velocity of from 500 to 100,000 hr -1 .
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-07-12 | 1997-01-11 | 1997-07-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-07-12 | 2001-01-11 | 2001-07-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-07-12 | 2005-01-11 | 2005-07-13 | $7700.00 | Window Closed / Lapsed |