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US5223560A Expired / Lapsed US ⏱️ 0.0 years remaining

Self-extinguishing polymeric compositions

Assignee: Ministry of Education, Universities and Research
•
Filing: 1992-07-21
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Granted: 1993-06-29
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Expires: 2012-07-21
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Abstract

Abstract Polymeric compositions endowed with high self-extinguishing characteristics when exposed to a flame, based on thermoplastic polymers or polymers endowed with elastomeric properties, in particular olefinic polymers or copolymers comprising: (a) from 89 to 45 parts by weight of a thermoplastic polymer, or of a polymer, or of a polymer endowed with elastomeric properties; (b) from 8 to 30 parts by weight of one or more ammonium or amine phosphate(s) and/or phosphonate(s); (c) from 3 to 25 parts by weight of one or more compound(s) derivatives of 2,4,6-triamino-1,3,5-triazine, having the general formula (I): <IMAGE> (I)

Inventors

  • 👤 Roberto Cipolli
  • 👤 Enrico Masarati
  • 👤 Gilberto Nucida
  • 👤 Mario Pirozzi
  • 👤 Roberto Oriani

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 15:07
CPC Classifications
C; C07; C07D; C07D251/00; C07D251/02; C07D251/12; C07D251/26; C07D251/40; C07D251/54; C07D251/70; C08; C08K; C08K3/00; C08K3/32; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/35; C08K5/357

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 585 words
Polymeric self-extinguishing compositions comprising: (a) from 89 to 45 parts by weight of a thermoplastic polymer, or of a polymer endowed with elastomeric properties; (b) from 8 to 30 parts by weight of one or more ammonium or amine phosphate(s) and/or phosphonate(s); (c) from 3 to 25 parts by weight of one or more compound(s) derivatives of 2,4,6-triamino-1,3,5-triazine, having the formula (I): ##STR109## wherein the radicals from R to R 3 , which can be either equal to or different from one another, and can have different meanings in each triazinic ring are: H; (C 1 -C 18 )-alkyl; (C 2 -C 8 )-alkenyl; (C 6 -C 16 )-cycloalkyl or -alkylcycloalkyl, optionally substituted with a hydroxy or (C 1 -C 4 )-hydroxyalkyl function; ##STR110## wherein: n=an integer within the range of from 2 to 8; m=an integer within the range of from 2 to 6; R 5 =H; (C 1 -C 8 )-alkyl; (C 2 -C 6 )-alkenyl; --C p H 2p --O--R 7 ; wherein p is an integer within the range of from 1 to 4 and R 7 is either H or a (C 1 -C 4 )-alkyl; (C 6 -C 12 )-cycloalkyl or -alkylcycloalkyl; the radicals R 6 , which can be either equal to, or different from, one another, are: H; (C 1 -C 8 )-alkyl; (C 2 -C 6 )-alkenyl; (C 6 -C 12 )-cycloalkyl or -alkylcycloalkyl; (C 1 -C 4 )-hydroxyalkyl; or the moiety: ##STR111## is replaced by a heterocyclic radical linked to the alkyl chain through the nitrogen atom and possibly containing another heteroatom; or in formula (I) at least one of the moieties ##STR112## is replaced by a heterocyclic radical linked to the triazinic ring through the nitrogen atom and optionally containing another heteroatom; a is either 0 or 1; b is 0 or an integer within the range of from 1 to 5; R 4 is hydrogen or: R 4 is hydrogen or: ##STR113## and its meaning can vary inside each repeating unit; when b is zero, Z is a divalent radical comprised in one of the following formulas: ##STR114## where radicals R 8 , like or different from one another, are hydrogen or (C 1 -C 4 )-alkyl; ##STR115## where r is an integer comprised within the range of from 2 to 14; R 9 is hydrogen; (C 1 -C 4 )-alkyl; (C 2 -C 6 )-alkenyl; (C 1 -C 4 )-hydroxyalkyl; ##STR116## where s is an integer within the range of from 2 to 5 and t is an integer within the range of from 1 to 3; ##STR117## where: X is a direct bond C--C; O; S; S--S; SO; SO 2 ; NH; NHSO 2 ; NHCO; N═N; CH 2 ; R 10 is hydrogen; hydroxyl; (C 1 -C 4 )-alkyl; (C 1 -C 4 )-alkoxyl; ##STR118## where A can be a saturated or unsaturated cycle; ##STR119## where s has the hereinabove defined meaning; when b is an integer within the range of from 1 to 5, the group: ##STR120## is a polyvalent radical comprised in one of the following formulas: ##STR121## where: R 11 is either hydrogen or (C 1 -C 4 )-alkyl; c is an integer within the range of from 1 to 5; the indexes s, which can be either equal to or different from each other, have the hereinabove defined meaning; ##STR122## where: R 11 has the hereinabove defined meaning; w is an integer within the range of from 2 to 4; d is either 1 or 2.
Claim 2
Dependent Claim 585 words
Polymeric self-extinguishing compositions comprising: (a) from 89 to 45 parts by weight of a thermoplastic polymer, or of a polymer endowed with elastomeric properties; (b) from 8 to 30 parts by weight of one or more ammonium or amine phosphate(s) and/or phosphonate(s); (c) from 3 to 25 parts by weight of one or more compound(s) derivatives of 2,4,6-triamino-1,3,5-triazine, having the formula (I): ##STR109## wherein the radicals from R to R 3 , which can be either equal to or different from one another, and can have different meanings in each triazinic ring are: H; (C 1 -C 18 )-alkyl; (C 2 -C 8 )-alkenyl; (C 6 -C 16 )-cycloalkyl or -alkylcycloalkyl, optionally substituted with a hydroxy or (C 1 -C 4 )-hydroxyalkyl function; ##STR110## wherein: n=an integer within the range of from 2 to 8; m=an integer within the range of from 2 to 6; R 5 =H; (C 1 -C 8 )-alkyl; (C 2 -C 6 )-alkenyl; --C p H 2p --O--R 7 ; wherein p is an integer within the range of from 1 to 4 and R 7 is either H or a (C 1 -C 4 )-alkyl; (C 6 -C 12 )-cycloalkyl or -alkylcycloalkyl; the radicals R 6 , which can be either equal to, or different from, one another, are: H; (C 1 -C 8 )-alkyl; (C 2 -C 6 )-alkenyl; (C 6 -C 12 )-cycloalkyl or -alkylcycloalkyl; (C 1 -C 4 )-hydroxyalkyl; or the moiety: ##STR111## is replaced by a heterocyclic radical linked to the alkyl chain through the nitrogen atom and possibly containing another heteroatom; or in formula (I) at least one of the moieties ##STR112## is replaced by a heterocyclic radical linked to the triazinic ring through the nitrogen atom and optionally containing another heteroatom; a is either 0 or 1; b is 0 or an integer within the range of from 1 to 5; R 4 is hydrogen or: R 4 is hydrogen or: ##STR113## and its meaning can vary inside each repeating unit; when b is zero, Z is a divalent radical comprised in one of the following formulas: ##STR114## where radicals R 8 , like or different from one another, are hydrogen or (C 1 -C 4 )-alkyl; ##STR115## where r is an integer comprised within the range of from 2 to 14; R 9 is hydrogen; (C 1 -C 4 )-alkyl; (C 2 -C 6 )-alkenyl; (C 1 -C 4 )-hydroxyalkyl; ##STR116## where s is an integer within the range of from 2 to 5 and t is an integer within the range of from 1 to 3; ##STR117## where: X is a direct bond C--C; O; S; S--S; SO; SO 2 ; NH; NHSO 2 ; NHCO; N═N; CH 2 ; R 10 is hydrogen; hydroxyl; (C 1 -C 4 )-alkyl; (C 1 -C 4 )-alkoxyl; ##STR118## where A can be a saturated or unsaturated cycle; ##STR119## where s has the hereinabove defined meaning; when b is an integer within the range of from 1 to 5, the group: ##STR120## is a polyvalent radical comprised in one of the following formulas: ##STR121## where: R 11 is either hydrogen or (C 1 -C 4 )-alkyl; c is an integer within the range of from 1 to 5; the indexes s, which can be either equal to or different from each other, have the hereinabove defined meaning; ##STR122## where: R 11 has the hereinabove defined meaning; w is an integer within the range of from 2 to 4; d is either 1 or 2.
Claim 3
Dependent Claim 41 words
Self-extinguishing polymeric compositions according to claim 1, wherein one or both of the following moieties: ##STR123## in formula (I) is (are) replaced by heterocyclic radicals selected from: aziridine; pyrrolidine; piperidine; morpholine; thiomorpholine; piperazine; 4-methylpiperazine; 4-ethylpiperazine; 2-methylpiperazine; 2,5-dimethylpiperazine; 2,3,5,6-tetramethylpiperazine; 2,2,5,5-tetramethylpiperazine; 2-ethylpiperazine; 2,5-diethylpiperazine.
Claim 4
Dependent Claim 52 words
Self-extinguishing polymeric compositions according to claim 1, wherein at least one of the radicals from R to R 3 in formula (I) is replaced by: --C.sub.n H.sub.2n --O--R.sub.5 wherein: n is an integer within the range of from 2 t 4 and R 5 is H or (C 1 -C 4 )-alkyl.
Claim 5
Dependent Claim 26 words
Self-extinguishing polymeric compositions according to claim 1, wherein at least one of the following moieties: ##STR124## in formula (I) is replaced by an --NH 2 radical.
Claim 6
Dependent Claim 32 words
Self-extinguishing polymeric compositions according to claim 1, wherein the moiety: ##STR125## in formula (I) is replaced by a heterocyclic radical selected from among: aziridine; pyrrolidine; piperidine; morpholine; thiomorpholine; piperazine; 4-methylpiperazine; or 4-ethylpiperazine.
Claim 7
Dependent Claim 32 words
Self-extinguishing polymeric compositions according to claim 1, wherein the ammonium phosphate(s) as mentioned under (b) have the formula (NH.sub.4).sub.n+2 P.sub.n O.sub.3n+1 wherein n is an integer equal to, or greater than, 2.
Claim 8
Dependent Claim 33 words
Self-extinguishing polymeric compositions according to claim 1, wherein the ammonium phosphate(s) as mentioned under (b) have the formula (NH.sub.4 PO.sub.3).sub.n wherein n is a numeral within the range of from 50 to 500.
Claim 9
Dependent Claim 29 words
Self-extinguishing polymeric compositions according to claim 1, wherein the amine phosphate(s) as mentioned under (b) are selected from among dimethylammonium or diethylammonium phosphate; ethylenediamine phosphate; melamine ortho- or pyrophosphate.
Claim 10
Dependent Claim 26 words
Self-extinguishing polymeric compositions according to claim 1, wherein the ammonium phosphate(s) as mentioned under (b) are the mono or polyammonium derivatives from mono or polyphosphonic acids.
Claim 11
Dependent Claim 50 words
Self-extinguishing polymeric compositions according to claim 1, wherein the (a) polymer is selected from polymers and copolymers of olefins of formula R--CH═CH.sub.2 wherein R is a hydrogen atom or a (C 1 -C 8 )-alkyl or -aryl radical; acrylonitrile/butadiene/styrene copolymers (ABS); styrene/acrylonitrile copolymers (SAN); polyurethane; poly(ethylene terephthalate); poly(butylene terephthalate); polyamides.
Claim 12
Dependent Claim 115 words
Self-extinguishing polymeric compositions according to claim 10, wherein the olefinic polymers and copolymers are selected from: (1) either isotactic or prevailingly isotactic polypropylene; (2) HDPE, LLDPE, LDPE polyethylene; (3) crystalline copolymers of propylene with minor proportions of ethylene and/or other alpha-olefins, such as 1-butene, 1-hexene, 1-octene, 4-methyl-pentene; (4) heterophasic compositions comprising (A) a fraction constituted by a propylene homopolymer and one of the copolymers as specified under above item (3); and (B) a copolymeric fraction constituted by elastomeric copolymers of ethylene with an alpha-olefin, optionally containing minor proportions of a diene, wherein the alpha-olefin is preferably selected from propylene and 1-butene; (5) elastomeric copolymers of ethylene with alpha-olefins optionally containing minor proportions of a diene.
Claim 13
Dependent Claim 10 words
Molded articles obtained from the compositions according to claim 1.

References Cited (Backward Citations)

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US4812499A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-06-28 1996-12-28 1997-06-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-06-28 2000-12-28 2001-06-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-06-28 2004-12-28 2005-06-29 $7700.00 Window Closed / Lapsed

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