Fabrication process for microminiature electron emitting device

Claim 2

A process for fabricating a microminiature electron emitting vacuum device having a tipped electron emitter supported on a substrate and disposed in a vacuum for emitting electrons from the tip, the process comprising the steps of: forming on a first planar surface of the substrate a metallic layer of electron emitter material, the layer being formed in such a way that the material covers the surface of tipped apertures formed in the substrate, grinding a second planar surface of the substrate, opposite the first planar surface, to remove sufficient substrate material, but leaving the metallic tips covered by a thickness of substrate no greater than about 10 microns, finishing the second surface of the substrate utilizing a wet etching solution to remove additional substrate material to expose the metallic tips, and wherein the step of forming comprises etching the tipped apertures in the first surface of the substrate and plating the metallic later on the etched first surface and in the apertures prior to the step of grinding.

Claim 3

The process as set forth in claim 1 wherein the step of finishing is accomplished by the etching solution without the use of abrasive grinding particles in such a way that any surface scratches resulting from the grinding step are polished and the metallic tips freed of the substrate material without substantial damage to the tips.

Claim 4

The process as set forth in claim 1 wherein the step of finishing comprises a first mechanochemical etching phase followed by a second chemical etching phase.

Claim 5

The process as set forth in claim 3 wherein the mechanochemical etching phase removes additional substrate material without exposing the tips, and the tips are exposed during the chemical etching phase.

Claim 6

A process for fabricating a microminiature electron emitting vacuum device having tipped electron emitter means supported on a substrate and disposed in a vacuum for emitting electrons from the tip means, the process comprising the steps of: providing a substrate having opposed substantially planar front and rear surfaces, forming a comparatively thick metallic layer of electron emitter material in tipped recess means formed on the front surface of the substrate in such a way that the metallic layer lines the walls of the recess means to form a metallic structure having tip means within the substrate, the metallic layer being of sufficient thickness to render the tip means of the metallic structure self-supporting when freed of the surrounding substrate material. grinding the rear planar surface of the substrate to remove at least half of the substrate material and to create an as-ground position of the rear surface of the substrate which is displaced from the front surface by a distance adequate to maintain the tip means of the metallic structure within the substrate and protected from the grinding step, finishing the rear surface of the substrate to create an as-finished position for the plane of the rear surface which is displaced from the front surface by a distance adequate to free the tip means of the metallic structure, thereby reliably exposing the tip means for emission of electrons, the tip means comprises an array of individual tips for respective emitters connected by a metallic structure which plates the tipped recess means and covers the front surface of the substrate, and the tip means comprises a first metallic layer having a low work function of 10.0 eV or less, and a second conductive metallic layer electroplated on the front surface of the electrode and in ohmnic contact with the low work function metal.

Claim 7

A process for fabricating a microminiature electron emitting vacuum device having tipped electron emitter means supported on a substrate and disposed in a vacuum for emitting electrons from the tip means, the process comprising the steps of: providing a substrate having opposed substantially planar front and rear surfaces, forming a comparatively thick metallic layer of electron emitter material in tipped recess means formed on the front surface of the substrate in such a way that the metallic layer lines the walls of the recess means to form a metallic structure having tip means within the substrate, the metallic layer being of sufficient thickness to render the tip means of the metallic structure self-supporting when freed of the surrounding substrate material. grinding the rear planar surface of the substrate to remove at least half of the substrate material and to create an as-ground position of the rear surface of the substrate which is displaced from the front surface by a distance adequate to maintain the tip means of the metallic structure within the substrate and protected from the grinding step, finishing the rear surface of the substrate to create an as-finished position for the plane of the rear surface which is displaced from the front surface by a distance adequate to free the tip means of the metallic structure, thereby reliably exposing the tip means for emission of electrons, the tip means comprises an array of individual tips for respective emitters connected by a metallic structure which plates the tipped recess means and covers the front surface of the substrate, and the tip means comprises a first metallic layer having a low work function of 10.0 eV or less, and a second conductive metallic layer electroplated on the front surface of the electrode and in ohmnic contact with the low work function metal.

Claim 8

A process for fabricating a microminiature electron emitting vacuum device having a tipped electron emitter supported on a substrate and disposed in a vacuum for emitting electrons from the tip, the process comprising the steps of: forming on a first planar surface of the substrate a metallic layer of electron emitter material, the layer being formed in such a way that the material covers the surface of tipped apertures formed in the substrate, grinding a second planar surface of the substrate, opposite the first planar surface, to remove sufficient substrate material, but leaving the metallic tips covered by a thickness of substrate no greater than about 50 microns, finishing the second surface of the substrate utilizing a wet etching solution to remove additional substrate material to expose the metallic tips, wherein the step of forming comprises etching the tipped apertures in the first surface of the substrate and plating the metallic layer on the etched first surface and in the apertures, and, wherein the step of plating comprises plating a first material in the tips of the apertures to form the metallic tips, and electroplating a second conductive metal in contact with the tip structure.

Claim 9

A process for fabricating a microminiature electron emitting vacuum device having a tipped electron emitter supported on a substrate and disposed in a vacuum for emitting electrons from the tip, the process comprising the steps of: forming on a first planar surface of the substrate a metallic layer of electron emitter material, the layer being formed in such a way that the material covers the surface of tipped apertures formed in the substrate, grinding a second planar surface of the substrate, opposite the first planar surface, to remove sufficient substrate material, but leaving the metallic tips covered by a thickness of substrate no greater than about 50 microns, finishing the second surface of the substrate utilizing a wet etching solution to remove additional substrate material to expose the metallic tips, wherein the step of forming comprises etching the tipped apertures in the first surface of the substrate and plating the metallic layer on the etched first surface and in the apertures, and, wherein the step of plating comprises plating a first material in the tips of the apertures to form the metallic tips, and electroplating a second conductive metal in contact with the tip structure.

Claim 10

The process as set forth in claim 1 in which the substrate is silicon and the etching step comprises utilizing a fluorine-based etching solution or a KOH series etching solution.

Claim 11

The process as set forth in claim 1 wherein the substrate is GaAs, and the etching step comprises utilizing a fluorine-based etching solution, a sulphuric etching solution, a tartaric acid etching solution, or a bromine series etching solution.

Claim 12

The process as set forth in claim 1 in which the metallic layer forming the metallic tip has a work function of 10.0 eV or less.

Claim 13

The process as set forth in claim 9 in which the metal layer is tungsten.

Claim 14

A process for fabricating a microminiature electron emitting vacuum device having tipped electron emitter means supported on a substrate and disposed in a vacuum for emitting electrons from the tip means, the process comprising the steps of: providing a substrate having opposed substantially planar front and rear surfaces, forming a comparatively thick metallic layer of electron emitter material in tipped recess means formed on the front surface of the substrate in such a way that the metallic layer lines the walls of the recess means to form a metallic structure having tip means within the substrate, the metallic layer being of sufficient thickness to render the tip means of the metallic structure self-supporting when freed of the surrounding substrate material, subsequent to the forming step grinding the rear planar surface of the substrate to remove at least half of the substrate material and to create an as-ground position of the rear surface of the substrate which is displaced from the front surface by a distance adequate to maintain the tip means of the metallic structure within the substrate and protected from the grinding step, and finishing the rear surface of the substrate to create an as-finished position for the plane of the rear surface which is displaced from the front surface by a distance adequate to free the tip means of the metallic structure, thereby reliably exposing the tip means for emission of electrons, and wherein the step of finishing comprises wet etching using an etching solution adapted to remove additional substrate material to free the metallic tips, the step of grinding being performed to remove sufficient material so that the wet etching does not substantially disturb the planarity of the as-finished rear surface.

Claim 15

A process for fabricating a microminiature electron emitting vacuum device having tipped electron emitter means supported on a substrate and disposed in a vacuum for emitting electrons from the tip means, the process comprising the steps of: providing a substrate having opposed substantially planar front and rear surfaces, forming a comparatively thick metallic layer of electron emitter material in tipped recess means formed on the front surface of the substrate in such a way that the metallic layer lines the walls of the recess means to form a metallic structure having tip means within the substrate, the metallic layer being of sufficient thickness to render the tip means of the metallic structure self-supporting when freed of the surrounding substrate material, subsequent to the forming step grinding the rear planar surface of the substrate to remove at least half of the substrate material and to create an as-ground position of the rear surface of the substrate which is displaced from the front surface by a distance adequate to maintain the tip means of the metallic structure within the substrate and protected from the grinding step, and finishing the rear surface of the substrate to create an as-finished position for the plane of the rear surface which is displaced from the front surface by a distance adequate to free the tip means of the metallic structure, thereby reliably exposing the tip means for emission of electrons, and wherein the step of finishing comprises wet etching using an etching solution adapted to remove additional substrate material to free the metallic tips, the step of grinding being performed to remove sufficient material so that the wet etching does not substantially disturb the planarity of the as-finished rear surface.

Claim 16

The process as set forth in claim 11 in which the tip means comprises an array of individual tips for respective emitters connected by a metallic structure which plates the tipped recess means and covers the front surface of the substrate.

Claim 17

The process as set forth in claim 11 in which the tip means comprises a single conical tip.

Claim 18

The process as set forth in claim 11 in which the tipped recess means in an elongate V-shaped recess forming a tip means in the shape of an elongate tip at the apex of the V.

Claim 19

The process as set forth in claim 11 wherein the step of forming comprises etching a plurality of conical apertures in the front surface of the substrate, and plating the metallic layer over the front surface and on the walls of the conical apertures to form an array of conical metallic structures having tips buried in the substrate at substantially the same level, the step of grinding serving to produce an as-ground position for the plane of the rear surface which protects all of the tips, and the step of finishing serving to produce an as-finished position for the plane of the rear surface which exposes all of the tips.

Claim 20

The process as set forth in claim 15 wherein the step of finishing comprises a first phase of mechanochemical etching in which the wet etching solution removes substrate material while the rear surface is being subjected to a mechanical rubbing action, and a second phase of wet etching without mechanical rubbing.

Claim 21

The process as set forth in claim 16 in which the step of mechanochemical etching removes substrate material without exposing the tips of the conical metallic structures, and the step of wet etching advances the plane of the rear surface to the as-finished position to expose the metallic tips.

Claim 22

The process as set forth in claim 15 in which the step of finishing comprises mechanochemical etching utilizing a wet etching solution and a grit-free polishing means, the wet etching solution being applied to rear surface in conjunction with mechanical rubbing of the polishing means to enhance the etching action and smooth the as-finished surface, the polishing means being operated in such a way as to minimize damage to the metallic tips during finishing.