US5219913A
Expired / Lapsed
US
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Polypropylene-based resin composition
Assignee: Prime Polymer Co Ltd
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Filing: 1991-09-03
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Granted: 1993-06-15
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Expires: 2011-09-03
Abstract
Abstract The polypropylene-based resin composition of the invention consists basically of (a) a polypropylene resin or a block copolymer of propylene and ethylene of specified ethylene content specified in terms of the melt index and the isotacticity relative to the isotactic pentad of the propylene moiety and (b) a talc powder specified in terms of the average particle diameter and the average aspect ratio of particles. The resin composition has good blow-moldability and is capable of giving molded articles having excellent mechanical strengths and dimensional accuracy to be useful, for example, as a material of automobile bumper beams. The performance of the resin composition can be further improved when the composition is a ternary composition by partially replacing the component (a) with (a') a high-density polyethylene specified in terms of the melt index and a special parameter derived from the viscosity measurement or when the composition is a quaternary composition consisting of the components (a), (a') and (b) and an additional component (c) which is a rubbery elastomer, e.g., EPR, specified in terms of the complex viscosity.
Inventors
- 👤 Ryuzo Tomomatsu
- 👤 Takumasa Fukuda
- 👤 Minoru Sugawara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 17:30
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/10; C08L23/12; C08K; C08K3/00; C08K3/34; C08K7/00; C08L23/16; C08K2201/00; C08K2201/016
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
220 words
A polypropylene-based resin composition consisting essentially of as a blend; (a,a') from 70 to 99 parts by weight of a combination of (a) a homopolymeric polypropylene or a copolymer of from 85% to 98.5% by weight of propylene and from 15% to 1.5% by weight of ethylene, of which the melt index does not exceed 1.0 g/10 minutes and the fraction of the isotactic pentad in the homopolymeric sequences of the propylene moiety is at least 93% and (a') a high-density polyethylene having a melt index not exceeding 0.1 g/10 minutes, of which the parameter A defined by the equation A=Z.sub.50 /Z.sub.10, in which Z 10 and Z 50 are the constant strain rate elongation viscosity at a rate of strain of 0.05 second -1 at the moments of 10 seconds and 50 seconds, respectively, at 150° C. has a value in the range from 2 to 20; and (b) from 30 to 1 part by weight of a powder of talc of which the average diameter of the particles does not exceed 5 μm and the average aspect ratio of the particles is in the range from 3 to 20, the total amount of the components (a), (a') and (b) being 100 parts by weight and the amount of the component (a') being 30 parts by weight or smaller.
Claim 2
Dependent Claim
220 words
A polypropylene-based resin composition consisting essentially of as a blend; (a,a') from 70 to 99 parts by weight of a combination of (a) a homopolymeric polypropylene or a copolymer of from 85% to 98.5% by weight of propylene and from 15% to 1.5% by weight of ethylene, of which the melt index does not exceed 1.0 g/10 minutes and the fraction of the isotactic pentad in the homopolymeric sequences of the propylene moiety is at least 93% and (a') a high-density polyethylene having a melt index not exceeding 0.1 g/10 minutes, of which the parameter A defined by the equation A=Z.sub.50 /Z.sub.10, in which Z 10 and Z 50 are the constant strain rate elongation viscosity at a rate of strain of 0.05 second -1 at the moments of 10 seconds and 50 seconds, respectively, at 150° C. has a value in the range from 2 to 20; and (b) from 30 to 1 part by weight of a powder of talc of which the average diameter of the particles does not exceed 5 μm and the average aspect ratio of the particles is in the range from 3 to 20, the total amount of the components (a), (a') and (b) being 100 parts by weight and the amount of the component (a') being 30 parts by weight or smaller.
Claim 3
Dependent Claim
256 words
A polypropylene-based resin composition consisting essentially of as a blend: (a,a') from 55 to 93 parts by weight of a combination of (a) a homopolymeric polypropylene or a copolymer of from 85% to 98.5% by weight of propylene and from 15% to 1.5% by weight of ethylene, of which the melt index does not exceed 1.0 g/10 minutes and the fraction of the isotactic pentad ;n the homopolymeric sequences of the propylene moiety is at least 93% and (a') a high density polyethylene having a melt index not exceeding 0.1 g/10 minutes, of which the parameter A defined by the equation A=Z.sub.50 /Z.sub.10, in which Z 10 and Z 50 are the constant strain rate elongation viscosity at a rate of strain of 0.05 second -1 at the moments of 10 seconds and 50 seconds, respectively, at 150° C. has a value in the range from 2 to 20; b) from 5 to 30 parts by weight of a powder of talc of which the average diameter of the particles does not exceed 5 μm and the average aspect ratio of the particles is in the range from 3 to 20; and (c) from 2 to 15 parts by weight of a rubbery elastomer of which the complex viscosity is in the range from 3×10 4 to 1×10 6 poise at a frequency of 0.01 Rad/second, the total amount of the components (a), (a'), (b) and (c) being 100 parts by weight and the amount of the component (a') being 30 parts by weight or smaller.
Claim 4
Dependent Claim
256 words
A polypropylene-based resin composition consisting essentially of as a blend: (a,a') from 55 to 93 parts by weight of a combination of (a) a homopolymeric polypropylene or a copolymer of from 85% to 98.5% by weight of propylene and from 15% to 1.5% by weight of ethylene, of which the melt index does not exceed 1.0 g/10 minutes and the fraction of the isotactic pentad ;n the homopolymeric sequences of the propylene moiety is at least 93% and (a') a high density polyethylene having a melt index not exceeding 0.1 g/10 minutes, of which the parameter A defined by the equation A=Z.sub.50 /Z.sub.10, in which Z 10 and Z 50 are the constant strain rate elongation viscosity at a rate of strain of 0.05 second -1 at the moments of 10 seconds and 50 seconds, respectively, at 150° C. has a value in the range from 2 to 20; b) from 5 to 30 parts by weight of a powder of talc of which the average diameter of the particles does not exceed 5 μm and the average aspect ratio of the particles is in the range from 3 to 20; and (c) from 2 to 15 parts by weight of a rubbery elastomer of which the complex viscosity is in the range from 3×10 4 to 1×10 6 poise at a frequency of 0.01 Rad/second, the total amount of the components (a), (a'), (b) and (c) being 100 parts by weight and the amount of the component (a') being 30 parts by weight or smaller.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-06-14 | 1996-12-14 | 1997-06-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-06-14 | 2000-12-14 | 2001-06-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-06-14 | 2004-12-14 | 2005-06-15 | $7700.00 | Window Closed / Lapsed |