Liquid-crystalline polyorganosiloxanes containing (meth) acryloxy groups

Claim 2

A process for preparing liquid-crystalline polyorganosiloxanes having more than 20 mol percent of crosslinkable methacryloxy and/or acryloxy groups per molecule which is obtained from the reaction of an organosilicon compound selected from the group consisting of an organopolysiloxane having hydrogen atoms bonded directly to silicon atoms, an organosilane having hydrogen atoms bonded directly to silicon atoms and which is capable of being condensed to form organosiloxanes and mixtures thereof, with a compound selected from the group consisting of alkenes, alkynes and mixtures thereof having mesogenic groups which comprises reacting the organosilicon compound in a first step with a compound selected from the group consisting of an alkene, alkyne and mixtures thereof having at least one-non-enolic hydroxyl group protected by a protective group, and in a second step removing the protective group and esterifying the free hydroxyl group with a compound selected from the group consisting of (meth)-acrylic acid, esters, anhydrides, halides thereof, and mixtures thereof with the proviso that if the organosilicon compound is an organosilane, then the organosilane is condensed to an organosiloxane.

Claim 3

The process of claim 1, wherein the organosiloxane having hydrogen atoms bonded directly to silicon atoms has units of the formula (I): R.sub.p H.sub.q SiO.sub.(4-p-q)/2 (I) where R is selected from the group consisting of C 1 to C 18 hydrocarbon radicals and substituted C 1 to C 18 hydrocarbon radicals; p is an integer having a value of from 0 to 3, with an average value of 1.8 to 2.2; q is an integer having a value of from 0 to 3, with an average value such that at least three hydrogen atoms are bonded directly to silicon atoms per molecule, and the sum of p and q is a maximum of 3.

Claim 4

The process of claim 1, wherein the organosilane having hydrogen atoms bonded directly to silicon atoms and is condensable to organosiloxanes is represented by formula (VI) R.sub.r H.sub.s SiY.sub.(4-r-s) (VI) where R is selected from the group consisting of C 1 to C 18 hydrocarbon radicals and substituted C 1 to C 18 hydrocarbon radicals; Y represents a condensable group; r represents an integer with a value of 0 or 1; s represents an integer having a value of from 0 to 3, with an average value of at least 0.1 and the sum of r and s is a maximum of 3.

Claim 5

The process or claim 1, wherein the organosilicon compound is a mixture of an organosiloxane having hydrogen atoms bonded directly to silicon atoms with units of formula (I) R.sub.p H.sub.q SiO.sub.(4-p-q)/2 (I) and an organosilane having hydrogen atoms bonded directly to silicon atoms and is condensable to organosiloxanes is represented by formula (VI) R.sub.r H.sub.s SiY.sub.(4-r-s) (VI) where R is selected from the group consisting of C 1 to C 18 hydrocarbon radicals and substituted C 1 to C 18 hydrocarbon radicals; p is an integer having a value of from 0 to 3, with an average value of 1.8 to 2.2; q is an integer having a value of from 0 to 3, with an average value such that at least three hydrogen atoms are bonded directly to silicon atoms per molecule, and the sum of p and q is a maximum of 3; Y represents a condensable group; r represents an integer with a value of 0 or 1; s represents an integer having a value of from 0 to 3, with an average value of at least 0.1 and the sum of r and s is a maximum of 3.

Claim 6

The process of claim 1, wherein the alkenes or alkynes having mesogenic groups are represented by formula (VII) C.sub.n H.sub.m --(X.sup.1.sub.a --A.sup.1.sub.b --A.sup.2.sub.c).sub.d --Z.sub.e --(--X.sup.2.sub.f --A.sup.3.sub.g --A.sup.4.sub.h --).sub.i --A.sup.5.sub.k (VII), where n represents an integer having a value of from 1 to 20; m has a value of 2n -1 , with the proviso that if n is 2, then m can have a value of (2n-3); X 1 and X 2 represents divalent radicals selected from the group consisting of --O--, --COO--, --CONH--, --CO--, --S--, --C≡C--, --CH═CH--, --CH═N--, --N═N-- and --N═N(O)--; A 1 , A 2 , A 3 and A 4 represent divalent radicals selected from the group consisting of 1,4-phenylene 1,4-cyclohexylene radicals, substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having from 1 to 10 carbon atoms; Z represents divalent to tetravalent radicals selected from the group consisting of benzene, cyclohexane and cyclopentane radicals; A 5 is selected from the group consisting of saturated alkyl, alkoxy and cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile and trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms; a, b, c, d, f, g, h, i and k each represents integers having a value of from 0 to 3, e is a number having a value of 0 or 1, the sum of a+b+c+d+f+g+h+i+k is at least 2 and the sum of d and i is a maximum of 4.

Claim 7

The process of claim 2, wherein the alkenes or alkynes having mesogenic groups are represented by formula (VII) C.sub.n H.sub.m --(X.sup.1 a--A.sup.1.sub.b --A.sup.2.sub.c).sub.d --Z--(--X.sup.2.sub.f --A.sup.3.sub.g --A.sup.4.sub.h --).sub.i --A.sup.5.sub.k (VII), where n represents an integer having a value of from 1 to 20; m has a value of 2n -1 , with the proviso that if n is 2, then m can have a value of (2n-3); X 1 and X 2 represent divalent radicals selected from the group consisting of --O--, --COO--, --CONH--, --CO--, --S--, --C≡C--, --CH═CH--, --CH═N, --N═N-- and --N═N(O)--; A 1 , A 2 , A 3 and A 4 represent divalent radicals selected from the group consisting of 1,4-phenylene, 1,4-cyclohexylene radicals, substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having from 1 to 10 carbon atoms; Z represents divalent to tetravalent radicals selected from the group consisting of benzene, cyclohexane and cyclopentane radicals; A 5 is selected from the group consisting of alkyl, alkoxy and cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile and trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms; a, b, c, d, f, g, h, i and k each represent integers having a value of from 0 to 3, e is a number having a value of 0 to 1, the sum of a+b+c+d+f+g+h+i+k is at least 2 and the sum of d and i is a maximum of 4.

Claim 8

The process of claim 3, wherein the alkenes or alkynes, having mesogenic groups are represented by formula (VII), C.sub.n H.sub.m --(X.sup.1.sub.a --A.sup.1.sub.b --A.sup.2.sub.c).sub.d --Z.sub.e --(--X.sup.2.sub.f --A.sup.3.sub.g --A.sup.4.sub.h --).sub.i --A.sup.5.sub.k (VII), where n represents an integer having a value of from 1 to 20; m has a value of 2n -1 , with the proviso that if n is 2, then m can have a value of (2n-3); X 1 and X 2 represent divalent radicals selected from the group consisting of --O--, --COO--, --CONH--, --CO--, --S--, --C≡C--, --CH═CH--, --CH═N--, --N═N-- and --N═N(O)--; A 1 , A 2 , A 3 and A 4 represent divalent radicals selected from the group consisting of 1,4-phenylene and 1,4-cyclohexylene radicals, substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having from 1 to 10 carbon atoms; Z represents divalent to tetravalent radicals selected from the group consisting of benzene cyclohexane and cyclopentane radicals; A 5 is selected from the group consisting of saturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon toms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile and trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms; a, b, c, d, f, g, h, i and k each represent integers having a value of from 0 to 3, e is a number having a value of 0 or 1, the sum of a+b+c+d+f+g+h+i+k is at least 2 and the sum of d and i is a maximum of 4.

Claim 9

The process of claim 4, wherein the alkenes or alkynes having mesogenic groups are represented by formula (VII) C.sub.n H.sub.m '(X.sup.1.sub.a --A.sup.1.sub.b --A.sup.2.sub.c).sub.d --Z.sub.e --(--X.sup.2.sub.f --A.sup.3.sub.g --A.sup.4.sub.h --).sub.i --A.sup.5.sub.k (VII), where n represents an integer having a value of from 1 to 20; m has a value of 2n -1 , with the proviso that if n is 2, then m can have a value of (2n-3); X 1 and X 2 represent divalent radicals selected from the group consisting of --O--, --COO--, --CONH--, --CO--, --S--, --C≡C--, --CH═CH--, --CH═N--, --N═N-- and --N═N(O)--; A 1 , A 2 , A 3 and A 4 represent divalent radicals, selected from the group consisting of 1,4-phenylene and 1,4-cyclohexylene radicals, substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having 1 to 10 carbon atoms; Z represents divalent to tetravalent radicals selected from the group consisting of benzene, cyclohexane and cyclopentane radicals; A 5 is selected from the group consisting of alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile and trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms; a, b, c, d, f, g, h, i and k each represent integers having a value of from 0 to 3, e is a number having a value of 0 or 1, the sum of a+b+c+d+f+g+h+i+k is at least 2 and the sum of d and i is a maximum of 4.

Claim 10

The process of claim 1, wherein the alkenes have at least one non-enolic hydroxyl group protected by a protective group and have up to 30 carbon atoms, which in addition to carbon atoms and hydrogen atoms, may also contain oxygen atoms, which may interrupt the carbon chain in the form of an ether linkage.

Claim 11

The process of claim 2, wherein the alkenes have at least one non-enolic hydroxyl group protected by a protective group and have up to 30 carbon atoms, which in addition to carbon atoms and hydrogen atoms, may also contain oxygen atoms, which may interrupt the carbon chain in the form of an ether linkage or ester linkage.

Claim 12

The process of claim 3, wherein the alkenes have at least one non-enolic hydroxyl group protected by a protective group and have up to 30 carbon atoms, which in addition to carbon atoms and hydrogen atoms, may also contain oxygen atoms, which may interrupt the carbon chain in the form of an ether linkage or ester linkage.

Claim 13

The process of claim 4, wherein the alkenes have at least one non-enolic hydroxyl group protected by a protective group and have up to 30 carbon atoms, which in addition to carbon atoms and hydrogen atoms, may also contain oxygen atoms, which may interrupt the carbon chain in the form of an ether linkage or ester linkage.

Claim 14

The process of claim 5, wherein the alkenes have at least one non-enolic hydroxyl group protected by a protective group and have up to 30 carbon atoms, which in addition to carbon atoms and hydrogen atoms, may also contain oxygen atoms, which may interrupt the carbon chain in the form of an ether linkage or ester linkage.

Claim 15

The process of claim 6, wherein the alkenes have at least one non-enolic hydroxyl group protected by a protective group and have up to 30 carbon atoms, which in addition to carbon atoms and hydrogen atoms, may also contain oxygen atoms, which may interrupt the carbon chain in the form of an ether linkage or ester linkage.

Claim 16

The process of claim 7, wherein the alkenes have at least one non-enolic hydroxyl group protected by a protective group and have up to 30 carbon atoms, which in addition to carbon atoms and hydrogen atoms, may also contain oxygen atoms, which may interrupt the carbon chain in the form of an ether linkage or ester linkage.

Claim 17

A liquid-crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 1.

Claim 18

A liquid-crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 2.

Claim 19

A liquid-crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 3.

Claim 20

A liquid-crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 4.

Claim 21

A liquid-crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 5.

Claim 22

A liquid-crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 6.

Claim 23

A liquid-crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 7.

Claim 24

A composition comprising the liquid crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 1, wherein the composition contains a compound of the formula ##STR6## where A 6 is selected from the group consisting of saturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile, trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms and a radical of the formula CH 2 ═CQ--COO--(R"") u --; Q represents a hydrogen atom or a methyl group; R"" represents divalent radicals selected from the group consisting of --CH 2 --, --O--CH 2 --, --O--CH 2 --CH 2 -- and --O--CH 2 --CH 2 --CH 2 --; u is an integer having a value of from 0 to 20; l is 0 or 1; X 1 and X 2 represent divalent radicals selected from the group consisting of --O--, --COO--, --CONH--, --CO--, --S--, --C≡C--, --CH═CH--, --CH═N--, --N═N-- and --N═N(O)--; A 3 represents divalent radicals, selected from the group consisting of 1,4-phenylene and 1,4-cyclohexylene radicals, substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having from 1 to 10 carbon atoms; f, has a value of 1, and a and g each have a value of 0 or 1.

Claim 25

A composition comprising the liquid crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 2, wherein the composition contains a compound of the formula ##STR7## where A 6 is selected from the group consisting of saturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile, trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms and a radical of the formula CH 2 ═CQ--COO--(R"") u --; Q represents a hydrogen atom or a methyl group; R"" represents divalent radicals selected from the group consisting of --CH 2 --, --O--CH 2 --, --O--CH 2 --CH 2 -- and --O--CH 2 --CH 2 --CH 2 --; u is an integer having a value of from 0 to 20; l is 0 or 1; X 1 and X 2 represent divalent radicals selected from the group consisting of --O--, --COO--, --CONH--, --CO--, --S--, --C≡C--, --CH═CH--, --CH═N--, --N═-- and 'N═N(O)--; A 3 represents divalent radicals, selected from the group consisting of 1,4-phenylene and 1,4-cyclohexylene radicals, substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having from 1 to 10 carbon atoms; f, has a value of 1, and a and g each have a value of 0 or 1.

Claim 26

A composition comprising the liquid crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 3, wherein the composition contains a compound of the formula ##STR8## where A 6 is selected from the group consisting of saturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile, trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms and a radical of the formula CH 2 ═CQ--COO--(R"") u --; Q represents a hydrogen atom or a methyl group; R"" represents divalent radicals selected from the group consisting of --CH 2 --, --O--CH 2 --, --O--CH 2 --CH 2 -- and --O--CH 2 --CH 2 --CH 2 --; u is an integer having a value of from 0 to 20; l is 0 or 1; X 1 and X 2 represent divalent radicals selected from the group consisting of --O--, --COO--, --CONH-- , --CO--, --S--, --C≡C--, --CH═CH--, --CH═N--, --N═N-- and --N═N(O)--; A 3 represents divalent radicals, selected from the group consisting of 1,4-phenylene and 1,4-cyclohexylene radicals, substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having from 1 to 10 carbon atoms; f, has a value of 1, and a and g each have a value of 0 or 1.

Claim 27

A composition comprising the liquid crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 4, wherein the composition contains a compound of the formula ##STR9## where A 6 is selected from the group consisting of saturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile, trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms and a radical of the formula CH 2 ═CQ--COO--(R"") u --; Q represents a hydrogen atom or a methyl group; R"" represents divalent radicals selected from the group consisting of --CH 2 --, --O--CH 2 --, --O--CH 2 --CH 2 -- and --O--CH 2 --CH 2 --CH 2 --; u is an integer having a value of from 0 to 20; l is 0 or 1; X 1 and X 2 represent divalent radicals selected from the group consisting of --O--, --COO--, --CONH-- , --CO--, --S--, --C≡C--, --CH═CH--, --CH═N--, --N═N-- and --N═N(O)--; A 3 represents divalent radicals, selected from the group consisting of 1,4-phenylene and 1,4-cyclohexylene radicals substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having from 1 to 10 carbon atoms; f, has a value of 1, and a and g each have a value of 0 or 1.

Claim 28

A composition comprising the liquid crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 5, wherein the composition contains a compound of the formula ##STR10## where A 6 is selected from the group consisting of saturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile, trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms and a radical of the formula CH 2 ═CQ--COO--(R"") u --; Q represents a hydrogen atom or a methyl group; R"" represents divalent radicals selected from the group consisting of --CH 2 --, --O--CH 2 --, --O--CH 2 --CH 2 -- and --O--CH 2 --CH 2 --CH 2 --; u is an integer having a value of from 0 to 20; l is 0 or 1; X 1 and X 2 represent divalent radicals selected from the group consisting of --O--, --COO--, --CONH-- , --CO--, --S--, --C≡C--, --CH═CH--, --CH═N--, --N═N-- and --N═N(O)--; A 3 represents divalent radicals, selected from the group consisting of 1,4-phenylene and 1,4-cyclohexylene radicals, substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having from 1 to 10 carbon atoms; f, has a value of 1, and a and g each have a value of 0 or 1.

Claim 29

A composition comprising the liquid crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 6, wherein the composition contains a compound of the formula ##STR11## where A 6 is selected from the group consisting of saturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile, trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms and a radical of the formula CH 2 ═CQ--COO--(R"") u --; Q represents a hydrogen atom or a methyl group; R"" represents divalent radicals selected from the group consisting of --CH 2 --, --O--CH 2 --, --O--CH 2 --CH 2 -- and --O--CH 2 --CH 2 --CH 2 --; u is an integer having a value of from 0 to 20; l is 0 or 1; X 1 and X 2 represent divalent radicals selected from the group consisting of --O--, --COO--, --CONH-- , --CO--, --S--, --C≡C--, --CH═CH--, --CH═N--, --N═N-- and --N═N(O)--; A 3 represents divalent radicals, selected from the group consisting of 1,4-phenylene and 1,4-cyclohexylene radicals, substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having from 1 to 10 carbon atoms; f, has a value of 1, and a and g each have a value of 0 or 1.

Claim 30

A composition comprising the liquid crystalline polyorganosiloxane having methacryloxy groups and/or acryloxy groups prepared in accordance with the process of claim 7, wherein the composition contains a compound of the formula ##STR12## where A 6 is selected from the group consisting of saturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, olefinically unsaturated alkyl, alkoxy or cycloalkyl radicals having from 1 to 16 carbon atoms, cholestane radicals, cholesteryl radicals, halogen atoms, hydrogen atoms, hydroxyl, nitrile, trialkylsiloxy groups in which the alkyl radicals of the trialkylsiloxy groups have from 1 to 8 carbon atoms and a radical of the formula CH 2 ═CQ--COO--(R"") u --; Q represents a hydrogen atom or a methyl group; R"" represents divalent radicals selected from the group consisting of --CH 2 --, --O--CH 2 --, --O--CH 2 --CH 2 -- and --O--CH 2 --CH 2 --CH 2 --; u is an integer having a value of from 0 to 20; l is 0 or 1; X 1 and X 2 represent divalent radicals selected from the group consisting of --O--, --COO--, --CONH-- , --CO--, --S--, --C≡C--, --CH═CH--, --CH═N--, --N═N-- and --N═N(O)--; A 3 represents divalent radicals, selected from the group consisting of 1,4-phenylene and 1,4-cyclohexylene radicals, substituted arylenes having from 1 to 10 carbon atoms, substituted cycloalkylenes having from 1 to 10 carbon atoms and heteroarylenes having 1 to 10 carbon atoms; f, has a value of 1, and a and g each have a value of 0 or 1.