US5208133A
Expired / Lapsed
US
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Photosensitive resin composition
Assignee: Sony Corp
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Filing: 1991-05-15
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Granted: 1993-05-04
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Expires: 2011-05-15
Abstract
Abstract A photosensitive resin composition, which is a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, is disclosed. The photoreactive acid catalyst generator contains tetrakis-1,2,4,5-(polyhalomethyl)benzene or tris(polyhalomethyl)benzene. The composition is a so-called three-component chemically amplified photoresist. When irradiated with an excimer laser light, the photoreactive acid generator is decomposed to yield a Lewis acid catalyst, while also yielding radicals, the photoreactive acid generator acting itself as an acid-linking auxiliary to improve the sensitivity of the photosensitive resin composition significantly. It becomes possible in this manner to form a fine resist pattern with superior resolution in the excimer laser lithography. On the other hand, the sensitivity dependency of the base resin or light transmittance may be lowered to increase the degree of freedom in material selection and designing.
Inventors
- 👤 Toshiro Tsumori
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 07:09
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/04; G03F7/0045; G03F7/038; Y; Y10; Y10S; Y10S430/00; Y10S430/146
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
94 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said base resin is any one of cresolnovolak resin, polyvinyl phenol or vinyl phenol-methyl methacrylate copolymer, and wherein the improvement resides in that said photoreactive acid catalyst generator is tetrakis-1,2,4,5-(polyhalomethyl) benzene represented by the formula I ##STR3## wherein X 1 , X 2 and X 3 each represent a halogen atom or a hydrogen atom and at least one of X 1 , X 2 or X 3 is a halogen atom.
Claim 2
Dependent Claim
94 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said base resin is any one of cresolnovolak resin, polyvinyl phenol or vinyl phenol-methyl methacrylate copolymer, and wherein the improvement resides in that said photoreactive acid catalyst generator is tetrakis-1,2,4,5-(polyhalomethyl) benzene represented by the formula I ##STR3## wherein X 1 , X 2 and X 3 each represent a halogen atom or a hydrogen atom and at least one of X 1 , X 2 or X 3 is a halogen atom.
Claim 3
Dependent Claim
42 words
The photosensitive resin composition according to claim 1 wherein said photoreactive acid catalyst generator is tetrakis-1,2,4,5-bromomethylbenzene wherein one of X 1 , X 2 or X 3 in the formula I is a bromine atom and the other two are hydrogen atoms.
Claim 4
Dependent Claim
84 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said acid cross-linking agent is hexamethoxymethylmelamine, and wherein the improvement resides in that said photoreactive acid catalyst generator is tetrakis-1,2,4,5-(polyhalomethyl) benzene represented by the formula I ##STR4## wherein X 1 , X 2 and X 3 each represent a halogen atom or a hydrogen atom and at least one of X 1 , X 2 or X 3 is a halogen atom.
Claim 5
Dependent Claim
84 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said acid cross-linking agent is hexamethoxymethylmelamine, and wherein the improvement resides in that said photoreactive acid catalyst generator is tetrakis-1,2,4,5-(polyhalomethyl) benzene represented by the formula I ##STR4## wherein X 1 , X 2 and X 3 each represent a halogen atom or a hydrogen atom and at least one of X 1 , X 2 or X 3 is a halogen atom.
Claim 6
Dependent Claim
42 words
The photosensitive resin composition of claim 3, wherein said photoreactive acid catalyst generator is tetrakis-1,2,4,5-bromomethylbenzene, wherein one of X 1 , X 2 , or X 3 in the formula (I) is a bromine atom and the other two are hydrogen atoms.
Claim 7
Dependent Claim
116 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said photoreactive acid catalyst generator and said acid cross-linking agent are contained in amounts of 0.1 to 10 parts by weight and 0.1 to 10 parts by weight, respectively, to 100 parts by weight of the base resin, and wherein the improvement resides in that said photoreactive acid catalyst generator is tetrakis-1,2,4,5-(polyhalomethyl) benzene represented by the formula I ##STR5## wherein X 1 , X 2 and X 3 each represent a halogen atom or a hydrogen atom and at least one of X 1 , X 2 or X 3 is a halogen atom.
Claim 8
Dependent Claim
116 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said photoreactive acid catalyst generator and said acid cross-linking agent are contained in amounts of 0.1 to 10 parts by weight and 0.1 to 10 parts by weight, respectively, to 100 parts by weight of the base resin, and wherein the improvement resides in that said photoreactive acid catalyst generator is tetrakis-1,2,4,5-(polyhalomethyl) benzene represented by the formula I ##STR5## wherein X 1 , X 2 and X 3 each represent a halogen atom or a hydrogen atom and at least one of X 1 , X 2 or X 3 is a halogen atom.
Claim 9
Dependent Claim
42 words
The photosensitive resin composition of claim 5, wherein said photoreactive acid catalyst generator is tetrakis-1,2,4,5-bromomethylbenzene, wherein one of X 1 , X 2 , or X 3 in the formula (I) is a bromine atom and the other two are hydrogen atoms.
Claim 10
Dependent Claim
92 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said base resin is any one of cresol-novolak resin, polyvinyl phenol or vinylphenol-methyl methacrylate copolymer, and wherein the improvement resides in that said photoreactive acid catalyst generator is tris(polyhalomethyl)benzene represented by the formula II ##STR6## wherein X 4 , X 5 and X 6 each represent a halogen atom or a hydrogen atom and at least one of X 4 , X 5 or X 6 is a halogen atom.
Claim 11
Dependent Claim
92 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said base resin is any one of cresol-novolak resin, polyvinyl phenol or vinylphenol-methyl methacrylate copolymer, and wherein the improvement resides in that said photoreactive acid catalyst generator is tris(polyhalomethyl)benzene represented by the formula II ##STR6## wherein X 4 , X 5 and X 6 each represent a halogen atom or a hydrogen atom and at least one of X 4 , X 5 or X 6 is a halogen atom.
Claim 12
Dependent Claim
43 words
The photosensitive resin composition according to claim 7 wherein said photoreactive acid catalyst generator is tris (bromomethyl)benzene wherein one of X 4 , X 5 or X 6 in the formula (II) is a bromine atom and the other two are hydrogen atoms.
Claim 13
Dependent Claim
83 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said acid cross-linking agent is hexamethoxymethylmelamine, and wherein the improvement resides in that said photoreactive acid catalyst generator is tris(polyhalomethyl)benzene represented by the formula II ##STR7## wherein X 4 , X 5 and X 6 each represent a halogen atom or a hydrogen atom and at least one of X 4 , X 5 or X 6 is a halogen atom.
Claim 14
Dependent Claim
83 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said acid cross-linking agent is hexamethoxymethylmelamine, and wherein the improvement resides in that said photoreactive acid catalyst generator is tris(polyhalomethyl)benzene represented by the formula II ##STR7## wherein X 4 , X 5 and X 6 each represent a halogen atom or a hydrogen atom and at least one of X 4 , X 5 or X 6 is a halogen atom.
Claim 15
Dependent Claim
42 words
The photosensitive resin composition of claim 9, wherein said photoreactive acid catalyst generator is tris(bromomethyl)benzene, wherein one of X 4 , X 5 , or X 6 in the formula (II) is a bromine atom and the other two are hydrogen atoms.
Claim 16
Dependent Claim
115 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said photoreactive acid catalyst generator and said acid cross-linking agent are contained in amounts of 0.1 to 10 parts by weight and 0.1 to 10 parts by weight, respectively, to 100 parts by weight of the base resin, and wherein the improvement resides in that said photoreactive acid catalyst generator is tris(polyhalomethyl)benzene represented by the formula II ##STR8## wherein X 4 , X 5 and X 6 each represent a halogen atom or a hydrogen atom and at least one of X 4 , X 5 or X 6 is a halogen atom.
Claim 17
Dependent Claim
115 words
A photosensitive resin composition, comprising a mixture of a base resin, an acid cross-linking agent and a photoreactive acid catalyst generator, wherein said photoreactive acid catalyst generator and said acid cross-linking agent are contained in amounts of 0.1 to 10 parts by weight and 0.1 to 10 parts by weight, respectively, to 100 parts by weight of the base resin, and wherein the improvement resides in that said photoreactive acid catalyst generator is tris(polyhalomethyl)benzene represented by the formula II ##STR8## wherein X 4 , X 5 and X 6 each represent a halogen atom or a hydrogen atom and at least one of X 4 , X 5 or X 6 is a halogen atom.
Claim 18
Dependent Claim
42 words
The photosensitive resin composition of claim 11, wherein said photoreactive acid catalyst generator is tris(bromomethyl)benzene, wherein one of X 4 , X 5 , or X 6 in the formula (II) is a bromine atom and the other two are hydrogen atoms.
References Cited (Backward Citations)
US3515552A
Cited
US4113497A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1996-05-03 | 1996-11-02 | 1997-05-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-05-03 | 2000-11-02 | 2001-05-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-05-03 | 2004-11-02 | 2005-05-04 | $7700.00 | Window Closed / Lapsed |