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US5205974A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the preparation of continuous objects of plastics

Assignee: DSM IP Assets BV
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Filing: 1991-11-20
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Granted: 1993-04-27
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Expires: 2011-11-20
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Abstract

Abstract A process for the manufacture of filaments, tapes and films that possess a shish-kebab morphology. This is effected in that for instance UHMW PE after extrusion is stretched at a temperature between the melting temperature (Tm) and a critical temperature (Tc) and subsequently cooled in stressed condition. The stretching rate is between 0.1 and 10 [sec.]-1.

Inventors

  • 👤 Cornelis W. M. Bastiaansen
  • 👤 Henricus E. H. Meijer
  • 👤 Zaheer Bashir

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 14:50
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; B; B29; B29C; B29C55/00; B29C55/005; D; D01; D01F; D01F6/00; D01F6/02; D01F6/04; B29K; B29K2023/00; B29K2023/04; B29K2023/06; C08J2323/00; C08J2323/02; C08J2323/04

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 135 words
Process for the manufacture of continuous objects of plastic that possess a shish kebab morphology, wherein a non-oriented plastic with a relatively high weight average molecular weight (Mw) and containing chain molecules with a particular rate of relaxation is in a melt state and then converted to a continuous article, said article being cooled, the cooled article being heated to and stretched at a temperature lying between the melting temperature of the non-orientated plastic (Tm) and a certain higher temperature (Tc), in that the rate of stretching lies between a lower rate (Ve) which is higher than the rate of relaxation of the chain molecules and a higher rate which is not so high that the melt begins to show elastic behavior, and rapidly cooling the resulting stretched article, while stressed, to a continuous object.
Claim 2
Dependent Claim 135 words
Process for the manufacture of continuous objects of plastic that possess a shish kebab morphology, wherein a non-oriented plastic with a relatively high weight average molecular weight (Mw) and containing chain molecules with a particular rate of relaxation is in a melt state and then converted to a continuous article, said article being cooled, the cooled article being heated to and stretched at a temperature lying between the melting temperature of the non-orientated plastic (Tm) and a certain higher temperature (Tc), in that the rate of stretching lies between a lower rate (Ve) which is higher than the rate of relaxation of the chain molecules and a higher rate which is not so high that the melt begins to show elastic behavior, and rapidly cooling the resulting stretched article, while stressed, to a continuous object.
Claim 3
Dependent Claim 18 words
Process according to claim 1, wherein the plastic is polyethylene with an Mw between 400,000 and 1,500,000 g/mol.
Claim 4
Dependent Claim 18 words
Process according to claim 1, wherein the plastic is polyethylene with an Mw between 500,000 and 1,200,000 g/mol.
Claim 5
Dependent Claim 18 words
Process according to claim 1, wherein the plastic is polyethylene with an Mw between 800,000 and 1,000,000 g/mol.
Claim 6
Dependent Claim 19 words
Process according to claim 1, wherein the stretching takes place at a temperature between 130° C. and 160° C.
Claim 7
Dependent Claim 17 words
Process according to claim 1, wherein the stretching rate lies between 0.4 and 10 s -1 .
Claim 8
Dependent Claim 17 words
Process according to claim 1, wherein the stretching rate lies between 0.5 and 5 s -1 .
Claim 9
Dependent Claim 73 words
Process for the manufacture of continuous objects of polyethylene that possess shish-kebab morphology wherein a polyethylene having a weight average molecular weight between 400,000 and 1,500,000 g/mol, is in the melt state and then converted to a continuous object, said object being cooled, the cooled object being heated to and stretched at a temperature between 130° C. and 160° C. at a stretching rate of 0.1-10 s -1 to form the shish-kebab morphology.
Claim 10
Dependent Claim 73 words
Process for the manufacture of continuous objects of polyethylene that possess shish-kebab morphology wherein a polyethylene having a weight average molecular weight between 400,000 and 1,500,000 g/mol, is in the melt state and then converted to a continuous object, said object being cooled, the cooled object being heated to and stretched at a temperature between 130° C. and 160° C. at a stretching rate of 0.1-10 s -1 to form the shish-kebab morphology.

References Cited (Backward Citations)

US4948545A Cited
EP1513343A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-04-26 1996-10-26 1997-04-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-04-26 2000-10-26 2001-04-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-04-26 2004-10-26 2005-04-27 $7700.00 Window Closed / Lapsed

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