US5204418A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Light-weight polyester film and process for its production
Assignee: Unitika Ltd
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Filing: 1992-01-30
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Granted: 1993-04-20
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Expires: 2012-01-30
Abstract
Abstract A light-weight polyester film which comprises (A) from 50 to 95% by weight of a crystalline polyester resin and (B) from 5 to 50% by weight of a maleimide copolymer, said maleimide copolymer being dispersed in the film in the form of particles having diameters of from 0.1 to 20 μm and fine voids being present in the film, and which has an apparent specific gravity of from 0.3 to 1.1, wherein said maleimide copolymer comprises from 30 to 50 mol % of a maleimide monomer group, from 30 to 70 mol % of an aromatic vinyl monomer group, from 0 to 40 mol % of an unsaturated dicarboxylic anhydride monomer group and from 0 to 40 mol % of other copolymerizable monomer group, and said maleimide copolymer has a glass transition temperature higher by at least 10° C. than the crystalline polyester resin.
Inventors
- 👤 Kenji Yasue
- 👤 Eiji Y. Yamamoto
- 👤 Katsuyuki Toma
- 👤 Minoru Kishida
- 👤 Yoshiaki Kozuka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 18:47
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; C08L; C08L35/00; C08L35/06; C08L67/00; C08L67/02; C08J2367/00; C08J2367/02
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
144 words
A light-weight polyester film which comprises (A) from 50 to 95% by weight of a crystalline polyester resin and (B) from 5 to 50% by weight of a maleimide copolymer, said maleimide copolymer being dispersed in the film in the form of particles having diameters of from 0.1 to 20 μm and fine voids being present in the film, and which has an apparent specific gravity of from 0.3 to 1.1, wherein said maleimide copolymer comprises from 30 to 50 mol % of a maleimide monomer group, from 30 to 70 mol % of an aromatic vinyl monomer group, from 0 to 40 mol % of an unsaturated dicarboxylic anhydride monomer group and from 0 to 50 mol % of other copolymerizable monomer group, and said maleimide copolymer has a glass transition temperature higher by at least 10° C. than the crystalline polyester resin.
Claim 2
Dependent Claim
144 words
A light-weight polyester film which comprises (A) from 50 to 95% by weight of a crystalline polyester resin and (B) from 5 to 50% by weight of a maleimide copolymer, said maleimide copolymer being dispersed in the film in the form of particles having diameters of from 0.1 to 20 μm and fine voids being present in the film, and which has an apparent specific gravity of from 0.3 to 1.1, wherein said maleimide copolymer comprises from 30 to 50 mol % of a maleimide monomer group, from 30 to 70 mol % of an aromatic vinyl monomer group, from 0 to 40 mol % of an unsaturated dicarboxylic anhydride monomer group and from 0 to 50 mol % of other copolymerizable monomer group, and said maleimide copolymer has a glass transition temperature higher by at least 10° C. than the crystalline polyester resin.
Claim 3
Dependent Claim
34 words
The light-weight polyester film according to claim 1, wherein the crystalline polyester resin comprises residues of an aromatic dicarboxylic acid and residues of an aliphatic diol or an alicyclic diol, as main constituting components.
Claim 4
Dependent Claim
49 words
The light-weight polyester film according to claim 2, wherein the aromatic dicarboxylic acid is terephthalic acid, isophthalic acid, naphthalenedicarboxylic acid or a mixture thereof; the aliphatic diol is ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, neopentyl glycol, or a mixture thereof; and the alicyclic diol is cylohexylene dimethanol.
Claim 5
Dependent Claim
26 words
The light-weight polyester film according to claim 1, wherein the crystalline polyester resin is polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polycyclohexylenedimethylene terephthalate or a mixture thereof.
Claim 6
Dependent Claim
35 words
The light-weight polyester film according to claim 1, wherein the crystalline polyester resin has an intrinsic viscosity of at least 0.4 dl/g as measured at 25° C. in a solvent mixture of phenol/tetrachloroethane=1/1 (weight ratio).
Claim 7
Dependent Claim
34 words
The light-weight polyester film according to claim 1, wherein the maleimide monomer is maleimide, N-methylmaleimide, N-ethylmaleimide, N-propylmaleimide, N-hexylmaleimide, N-cyclohexylmaleimide, N-phenylmaleimide, N-tolylmaleimide, N-(halogenated phenyl)maleimide, N-(hydroxyphenyl)maleimide, N-naphthylmaleimide, N-(hydroxyphenyl)maleimide, N-naphthylmaleimide, α-chloro-N-phenylmaleimide, α-methyl-N phenylmaleimide or a mixture thereof.
Claim 8
Dependent Claim
25 words
The light-weight polyester film according to claim 1, wherein the aromatic vinyl monomer is styrene, α-methylstyrene, vinyl toluene, t-butylstyrene, halogenated styrene or a mixture thereof.
Claim 9
Dependent Claim
29 words
The light-weight polyester film according to claim 1, wherein the unsaturated dicarboxylic anhydride monomer is maleic anhydride, methylmaleic anhydride, 1,2-dimethylmaleic anhydride, ethylmaleic anhydride, phenylmaleic anhydride or a mixture thereof.
Claim 10
Dependent Claim
38 words
The light-weight polyester film according to claim 1, wherein said other copolymerizable monomer is methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)acrylate, hexyl (meth)acrylate, cyclohexyl (meth)acrylate, decyl (meth)acrylate, octadecyl (meth)acrylate, hydroxyethyl (meth)acrylate, methoxyethyl (meth)acrylate, glycidyl (meth)acrylate or a mixture thereof.
Claim 11
Dependent Claim
83 words
A process for producing a light-weight polyester film, which comprises melt-extruding a composition comprising (A) from 50 to 95% by weight of a crystalline polyester resin and (B) from 5 to 50% by weight of a maleimide copolymer to obtain an unstretched polyester film, and at least monoaxially stretching the polyester film at least 1.5 times within a temperature range of at least the glass transition temperature of the crystalline polyester resin and at most the crystallization temperature of the crystalline polyester resin.
Claim 12
Dependent Claim
83 words
A process for producing a light-weight polyester film, which comprises melt-extruding a composition comprising (A) from 50 to 95% by weight of a crystalline polyester resin and (B) from 5 to 50% by weight of a maleimide copolymer to obtain an unstretched polyester film, and at least monoaxially stretching the polyester film at least 1.5 times within a temperature range of at least the glass transition temperature of the crystalline polyester resin and at most the crystallization temperature of the crystalline polyester resin.
References Cited (Backward Citations)
US4388446A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1996-04-19 | 1996-10-19 | 1997-04-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-04-19 | 2000-10-19 | 2001-04-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-04-19 | 2004-10-19 | 2005-04-20 | $7700.00 | Window Closed / Lapsed |