US5202074A
Expired / Lapsed
US
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Method for producing injection molded multilayer articles
Assignee: Dow Chemical Co
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Filing: 1991-04-11
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Granted: 1993-04-13
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Expires: 2011-04-11
Abstract
Abstract A method of making a multilayer plastic article by forming a multilayer stream of diverse thermoplastic materials and injection molding the multilayer stream directly into the article. The multilayer stream can be formed by coextrusion of the materials or by coextrusion followed by layer multiplication in one or more interfacial surface generators/static mixers. The coextruded stream, or a multiplied stream from the one or more ISG's, can also be divided into substreams and the substreams thereafter recombined prior to being injection molded so that the layers in one such substream are angularly oriented with respect to the layers in another substream.
Inventors
- 👤 Walter J. Schrenk
- 👤 Ranganath K. Shastri
- 👤 Herbert C. Roehrs
- 👤 Ralph E. Ayres
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 08:21
CPC Classifications
B; B32; B32B; B32B37/00; B32B37/14; B32B37/15; B32B37/153; B29; B29C; B29C43/00; B29C43/02; B29C43/20; B29C43/203; B29C43/32; B29C43/36; B29C43/361; B29C45/00; B29C45/16; B29C48/00; B29C48/03; B29C48/07; B29C48/08; B29C48/16; B29C48/18; B29C48/21; B29C48/25; B29C48/255; B29C48/36; B29C48/50; B29C48/695; B29C48/70; B29C48/71; B29C49/00; B29C49/22; B29C69/00; B29C69/001; B29C69/02; B29C43/34; B29C2043/3433; B29C2043/3615; B29C2043/3618; B29C2949/00; B29C2949/07; B29C2949/081; B29C2949/0811; B29C43/16; B29C48/001; B29C48/0017; B29C48/09; B29C48/12; B29C48/22; B29C48/30; B29C48/32; B29C48/335; B29C51/00; B29C51/14; B29K; B29K2105/00; B29K2105/26; B29K2995/00; B29K2995/0037; B29K2995/0065; B29K2995/0067; B29L; B29L2031/00; B29L2031/56; B29L2031/565
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
122 words
A method of making a multilayer plastic article, consisting essentially of: coextruding a first composite stream comprised of discrete, generally planar and parallel layers of at least first and second diverse thermoplastic materials; manipulating the first composite stream to form a second composite stream having an increased number of discrete, generally planar and parallel layers of the first and second materials compared to the first composite stream; directly injection molding the second composite stream into a desired configuration; and selecting a layer thickness for the layers of the first and second materials in the second composite stream so that at least about 90 percent of the layers are substantially continuous after the second composite stream is injection molded into the desired configuration.
Claim 2
Independent Claim
122 words
A method of making a multilayer plastic article, consisting essentially of: coextruding a first composite stream comprised of discrete, generally planar and parallel layers of at least first and second diverse thermoplastic materials; manipulating the first composite stream to form a second composite stream having an increased number of discrete, generally planar and parallel layers of the first and second materials compared to the first composite stream; directly injection molding the second composite stream into a desired configuration; and selecting a layer thickness for the layers of the first and second materials in the second composite stream so that at least about 90 percent of the layers are substantially continuous after the second composite stream is injection molded into the desired configuration.
Claim 3
Dependent Claim
60 words
A method as defined in claim 1, wherein the step of manipulating the first composite stream to form the second composite stream comprises: dividing the first composite stream to form a plurality of substreams collectively comprising an increased number of discrete, generally planar layers of the first and second materials compared to the first composite stream; and stacking the substreams.
Claim 4
Dependent Claim
36 words
A method as defined in claim 1, wherein the step of manipulating the first composite stream to form the second composite stream consists of passing the first composite stream through one or more interfacial surface generators.
Claim 5
Dependent Claim
35 words
A method as defined in claim 1, wherein the discrete and substantially continuous layers of the first and second materials are substantially evenly distributed across a cross-section of the desired configuration adjacent the critical surface.
Claim 6
Dependent Claim
43 words
A method as defined in claim 1, wherein no more than about 10 percent of the layers of the first and second materials adjacent the critical surface have an interfacial surface area to unit thickness ratio of less than about 10 to 1.
Claim 7
Dependent Claim
42 words
A method as defined in claim 4, wherein at least the plurality of layers of the first and second materials lying generally parallel to the critical surface have interfacial surface area to unit thickness ratios of at least about 100 to 1.
Claim 8
Dependent Claim
42 words
A method as defined in claim 6, wherein at least the plurality of layers of the first and second materials lying generally parallel to the critical surface have interfacial surface area to unit thickness ratios of at least about 1000 to 1.
Claim 9
Dependent Claim
14 words
A method as defined in claim 1, wherein the coextruding is carried out intermittently.
Claim 10
Dependent Claim
19 words
A method as defined in claim 8, wherein the coextruding is carried out by a reciprocating screw injection process.
Claim 11
Independent Claim
157 words
A method of making a multilayer plastic article, consisting essentially of the steps of: coextruding a first composite stream comprised of discrete, generally planar and parallel layers of at least first, second, and third diverse thermoplastic materials in a selected layer order, the selected layer order being characterized by the placement of a layer of the third material between any otherwise adjacent layers of the first and second materials; manipulating the first composite stream to form a second composite stream having an increased number of discrete, generally planar and parallel layers of the first, second, and third materials and retaining the selected layer order; directly injection molding the first composite stream into a desired configuration; and selecting a layer thickness for said first, second, and third materials in the first composite stream so that at least about 90 percent of the layers are substantially continuous after the second composite stream is injection molded into the desired configuration.
Claim 12
Independent Claim
157 words
A method of making a multilayer plastic article, consisting essentially of the steps of: coextruding a first composite stream comprised of discrete, generally planar and parallel layers of at least first, second, and third diverse thermoplastic materials in a selected layer order, the selected layer order being characterized by the placement of a layer of the third material between any otherwise adjacent layers of the first and second materials; manipulating the first composite stream to form a second composite stream having an increased number of discrete, generally planar and parallel layers of the first, second, and third materials and retaining the selected layer order; directly injection molding the first composite stream into a desired configuration; and selecting a layer thickness for said first, second, and third materials in the first composite stream so that at least about 90 percent of the layers are substantially continuous after the second composite stream is injection molded into the desired configuration.
Claim 13
Independent Claim
106 words
A method of making a multilayer plastic article, comprising the steps of: coextruding a first composite stream comprised of discrete, generally planar layers of at least first and second diverse thermoplastic materials; wherein at least one of the first and second materials in the first composite stream comprises less than about 15 percent by volume of the first composite stream; and injecting the first composite stream into a plurality of mold cavities possessing differing geometries as a part of a multicavity injection molding process; wherein layers of the at least one material extend fully throughout the plurality of mold cavities and the multilayer articles produced therefrom.
Claim 14
Independent Claim
106 words
A method of making a multilayer plastic article, comprising the steps of: coextruding a first composite stream comprised of discrete, generally planar layers of at least first and second diverse thermoplastic materials; wherein at least one of the first and second materials in the first composite stream comprises less than about 15 percent by volume of the first composite stream; and injecting the first composite stream into a plurality of mold cavities possessing differing geometries as a part of a multicavity injection molding process; wherein layers of the at least one material extend fully throughout the plurality of mold cavities and the multilayer articles produced therefrom.
Claim 15
Independent Claim
172 words
A method of making a multilayer plastic article, comprising the steps of: coextruding a first composite stream comprised of discrete, generally planar and parallel layers of at least first and second diverse thermoplastic materials; dividing the first composite stream into a plurality of substreams having discrete, generally planar and parallel layers of the first and second materials; combining the plurality of substreams such that a majority of the layers of the first and second materials of one such substream are generally angularly oriented with respect to a majority of the layers of the first and second materials of a second such substream; and injection molding the generally angularly oriented combined substreams into a desired configuration wherein exposed edges of layers of the first or second, or first and second, materials adjacent at least one critical surface of the article are reduced in number or in extent, or in number and extent compared to an article formed by directly injection molding the first composite stream without the forming and combining of substreams therefrom.
Claim 16
Independent Claim
172 words
A method of making a multilayer plastic article, comprising the steps of: coextruding a first composite stream comprised of discrete, generally planar and parallel layers of at least first and second diverse thermoplastic materials; dividing the first composite stream into a plurality of substreams having discrete, generally planar and parallel layers of the first and second materials; combining the plurality of substreams such that a majority of the layers of the first and second materials of one such substream are generally angularly oriented with respect to a majority of the layers of the first and second materials of a second such substream; and injection molding the generally angularly oriented combined substreams into a desired configuration wherein exposed edges of layers of the first or second, or first and second, materials adjacent at least one critical surface of the article are reduced in number or in extent, or in number and extent compared to an article formed by directly injection molding the first composite stream without the forming and combining of substreams therefrom.
Claim 17
Independent Claim
140 words
A method of making a multilayer plastic article, comprising the steps of: coextruding a first composite stream comprised of discrete, generally planar layers of at least first and second diverse thermoplastic materials; manipulating the first composite stream to form a second composite stream having an increased number of discrete, generally planar and parallel layers of the first and second materials compared to the first composite stream; wherein at least one of the first and second materials in the second composite stream comprises less than about 15 percent by volume of the second composite stream; and injecting the second composite stream into a plurality of mold cavities possessing different geometries as a part of a multicavity injection molding process; wherein layers of the at least one material extend fully throughout the plurality of mold cavities and the multilayer articles produced therefrom.
Claim 18
Independent Claim
140 words
A method of making a multilayer plastic article, comprising the steps of: coextruding a first composite stream comprised of discrete, generally planar layers of at least first and second diverse thermoplastic materials; manipulating the first composite stream to form a second composite stream having an increased number of discrete, generally planar and parallel layers of the first and second materials compared to the first composite stream; wherein at least one of the first and second materials in the second composite stream comprises less than about 15 percent by volume of the second composite stream; and injecting the second composite stream into a plurality of mold cavities possessing different geometries as a part of a multicavity injection molding process; wherein layers of the at least one material extend fully throughout the plurality of mold cavities and the multilayer articles produced therefrom.
Claim 19
Independent Claim
206 words
A method of making a multilayer plastic article, comprising the steps of: coextruding a first composite stream comprised of discrete, generally planar and parallel layers of at least first and second diverse thermoplastic materials; manipulating the first composite stream to form a second composite stream having an increased number of discrete, generally planar and parallel layers of the first and second materials compared to the first composite stream; dividing the second composite stream into a plurality of substreams having discrete, generally planar and parallel layers of the first and second materials; combining the plurality of substreams such that a majority of the layers of the first and second materials of one such substream are generally angularly oriented with respect to a majority of the layers of the first and second materials of a second such substream; and injection molding the generally angularly oriented combined substreams into a desired configuration wherein exposed edges of layers of the first or second, or first and second, materials adjacent at least one critical surface of the article are reduced in number or in extent, or in number and extent compared to an article formed by directly injection molding the second composite stream without the forming and combining of substreams therefrom.
Claim 20
Independent Claim
206 words
A method of making a multilayer plastic article, comprising the steps of: coextruding a first composite stream comprised of discrete, generally planar and parallel layers of at least first and second diverse thermoplastic materials; manipulating the first composite stream to form a second composite stream having an increased number of discrete, generally planar and parallel layers of the first and second materials compared to the first composite stream; dividing the second composite stream into a plurality of substreams having discrete, generally planar and parallel layers of the first and second materials; combining the plurality of substreams such that a majority of the layers of the first and second materials of one such substream are generally angularly oriented with respect to a majority of the layers of the first and second materials of a second such substream; and injection molding the generally angularly oriented combined substreams into a desired configuration wherein exposed edges of layers of the first or second, or first and second, materials adjacent at least one critical surface of the article are reduced in number or in extent, or in number and extent compared to an article formed by directly injection molding the second composite stream without the forming and combining of substreams therefrom.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-04-12 | 1996-10-12 | 1997-04-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-04-12 | 2000-10-12 | 2001-04-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-04-12 | 2004-10-12 | 2005-04-13 | $7700.00 | Window Closed / Lapsed |