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US5200461A Expired / Lapsed US ⏱️ 0.0 years remaining

Anionic microgel particle dispersion and a coating composition therefrom

Assignee: Nippon Paint Co Ltd
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Filing: 1990-07-05
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Granted: 1993-04-06
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Expires: 2010-07-05
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Abstract

Abstract Disclosed is a micro gel particle having an anionic charge for which it is electrodepositable by itself. The present invention provides a process for preparing an anionic micro gel particle dispersion comprising: emulsifying in an aqueous medium a resin composition comprising (A) 100 parts by weight of an anionic film-forming aqueous resin, and (B) 10 to 250 parts by weight of a thermosetting crosslinking agent which is self-crosslinked or crosslinked with said aqueous resin (A) in terms of condensation or addition reaction excepting the combination of an acrylic resin and an alcoxylated methylol melamine; parts by weight being based on the solid content of the resin composition, and heating the resultant emulsion to above a crosslinkable temperature of said crosslinking agent (B).

Inventors

  • 👤 Yasuyuki Tsuchiya
  • 👤 Kenshiro Tobinaga

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 06:37
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/44; C09D5/4488; C08; C08J; C08J3/00; C08J3/24; C08J3/26; C08L; C08L13/00; C08L13/02; C09D5/4403; C09D5/4419; C09D5/443; C09D5/4453; C09D5/4484; Y; Y10; Y10S; Y10S524/00; Y10S524/901

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 171 words
A process for preparing an anionic micro gel particle dispersion comprising: (i) emulsifying in an aqueous medium a resin composition comprising (A) 100 parts by weight of an anionic film-forming aqueous resin, and (B) 10 to 250 parts by weight of a thermosetting crosslinking agent which is self-crosslinked or crosslinked with said aqueous resin (A) in terms of a condensation or addition reaction wherein the parts by weight are based on the solid content of the resin composition, provided that, when the aqueous resin (A) is selected from the group consisting of maleic natural or synthetic drying oil and maleic polybutadiene and a half-ester or half-amide thereof, the thermosetting crosslinking agent (B) is selected from the group consisting of methylolphenols, etherified methylolphenols and melamine resins, and when the aqueous resin (A) is an anionic acrylic resin, the thermosetting crosslinking agent (B) is selected from the group consisting of methylolphenols and etherified methylolphenols, (ii) and then heating the resultant emulsion to a temperature above the crosslinkable temperature of said crosslinking agent (B).
Claim 2
Dependent Claim 171 words
A process for preparing an anionic micro gel particle dispersion comprising: (i) emulsifying in an aqueous medium a resin composition comprising (A) 100 parts by weight of an anionic film-forming aqueous resin, and (B) 10 to 250 parts by weight of a thermosetting crosslinking agent which is self-crosslinked or crosslinked with said aqueous resin (A) in terms of a condensation or addition reaction wherein the parts by weight are based on the solid content of the resin composition, provided that, when the aqueous resin (A) is selected from the group consisting of maleic natural or synthetic drying oil and maleic polybutadiene and a half-ester or half-amide thereof, the thermosetting crosslinking agent (B) is selected from the group consisting of methylolphenols, etherified methylolphenols and melamine resins, and when the aqueous resin (A) is an anionic acrylic resin, the thermosetting crosslinking agent (B) is selected from the group consisting of methylolphenols and etherified methylolphenols, (ii) and then heating the resultant emulsion to a temperature above the crosslinkable temperature of said crosslinking agent (B).
Claim 3
Dependent Claim 14 words
The process according to claim 1 wherein the methylol phenols is a beta-hydroxyphenol ether.
Claim 4
Dependent Claim 14 words
The process according to claim 1 wherein the crosslinking agent (B) is tetrabromobisphenol A.
Claim 5
Dependent Claim 23 words
The process according to claim 1 wherein the emulsion additionally comprises an organic solvent which is removed before or during the heating step.
Claim 6
Dependent Claim 14 words
The process according to claim 1 wherein the emulsion further comprises a solid particle.
Claim 7
Dependent Claim 23 words
The process according to claim 5 wherein the solid particle is selected from the group consisting of a pigment and a metal particle.
Claim 8
Dependent Claim 14 words
The process according to claim 4, wherein the emulsion further comprises a solid particle.
Claim 9
Dependent Claim 11 words
A micro gel particle obtained by the process of claim 5.

References Cited (Backward Citations)

DE1929593A1 Cited
JPS4893631A Cited
US4159364A Cited
US4378450A Cited
JPS58197296A Cited
US4560714A Cited
EP0159883A2 Cited
US4968399A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-04-05 1996-10-05 1997-04-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-04-05 2000-10-05 2001-04-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-04-05 2004-10-05 2005-04-06 $7700.00 Window Closed / Lapsed

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