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US5200359A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of decreasing contact resistance between a lower elevation aluminum layer and a higher elevation electrically conductive layer

Assignee: Micron Technology Inc
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Filing: 1991-10-03
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Granted: 1993-04-06
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Expires: 2011-10-03
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Abstract

Abstract A semiconductor processing method for decreasing electrical contact resistance between different elevation electrically conductive layers is disclosed. The method includes applying an aluminum layer atop a partially processed semiconductor wafer, with the aluminum layer having a defined upper surface. The semiconductor wafer with applied aluminum layer is exposed to an oxidizing atmosphere, forming an electrically resistive aluminum oxide at the upper surface of the aluminum layer. An interlayer insulating dielectric material is applied atop the aluminum layer. It is selectively patterned and etched to define a contact opening to the aluminum layer. A layer of titanium metal is applied atop the patterned and etched interlayer dielectric to a preselected thickness. The titanium metal contacts the upper aluminum oxide surface of the aluminum layer within the contact opening. The titanium metal is reacted with the aluminum oxide in the contact to transform aluminum oxide into a less electrically resistive titanium oxide. After application of the titanium metal, a layer of conductive material is applied atop the wafer and thereafter selectively patterned and etched to form a desired the conductive runner.

Inventors

  • 👤 Leslie A. Pearey
  • 👤 Timothy P. O'Brien
  • 👤 John E. Knudson
  • 👤 Thomas N. Melody
  • 👤 Russell C. Zahorik

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 10:39
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/064

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 179 words
A semiconductor processing method for decreasing electrical contact resistance between different elevation electrically conductive layers, the method comprising the following steps: applying an aluminum layer atop a partially processed semiconductor wafer, the aluminum layer having an upper surface; exposing the semiconductor wafer with applied aluminum layer to an oxidizing atmosphere and forming an electrically resistive aluminum oxide at the upper surface of the aluminum layer; applying an interlayer insulating dielectric material atop the aluminum layer; selectively patterning and etching the interlayer dielectric to define a contact opening to the aluminum layer; applying a layer of titanium metal atop the patterned and etched interlayer dielectric, the titanium metal contacting the upper aluminum oxide surface of the aluminum layer within the contact opening; reacting the titanium metal with the aluminum oxide in the contact to transform aluminum oxide into a less electrically resistive titanium oxide; and after application of the titanium metal and reaction to form a titanium oxide, applying a layer of conductive material atop the wafer over the titanium oxide, and thereafter selectively patterning and etching the conductive layer.
Claim 2
Dependent Claim 179 words
A semiconductor processing method for decreasing electrical contact resistance between different elevation electrically conductive layers, the method comprising the following steps: applying an aluminum layer atop a partially processed semiconductor wafer, the aluminum layer having an upper surface; exposing the semiconductor wafer with applied aluminum layer to an oxidizing atmosphere and forming an electrically resistive aluminum oxide at the upper surface of the aluminum layer; applying an interlayer insulating dielectric material atop the aluminum layer; selectively patterning and etching the interlayer dielectric to define a contact opening to the aluminum layer; applying a layer of titanium metal atop the patterned and etched interlayer dielectric, the titanium metal contacting the upper aluminum oxide surface of the aluminum layer within the contact opening; reacting the titanium metal with the aluminum oxide in the contact to transform aluminum oxide into a less electrically resistive titanium oxide; and after application of the titanium metal and reaction to form a titanium oxide, applying a layer of conductive material atop the wafer over the titanium oxide, and thereafter selectively patterning and etching the conductive layer.
Claim 3
Dependent Claim 27 words
The semiconductor processing method of claim 1 wherein the layer of titanium metal is applied to a thickness of from about 100 Angstroms to about 1000 Angstroms.
Claim 4
Dependent Claim 22 words
The semiconductor processing method of claim 1 wherein the layer of titanium metal is applied to a thickness of about 300 Angstroms.
Claim 5
Dependent Claim 18 words
The semiconductor processing method of claim 1 wherein the titanium metal being applied consists essentially of elemental titanium.
Claim 6
Dependent Claim 35 words
The semiconductor processing method of claim 1 wherein the reacting of the titanium with the aluminum oxide occurs during the step of applying the layer of titanium metal atop the patterned and etched interlayer dielectric.
Claim 7
Dependent Claim 47 words
The semiconductor processing method of claim 1 further comprising conducting a radio frequency induced plasma etch in a non-oxidizing atmosphere after patterning and etching the interlayer dielectric to etch some of the aluminum oxide away from the upper surface of the aluminum layer within the contact opening.
Claim 8
Dependent Claim 15 words
The semiconductor processing method of claim 1 wherein the aluminum layer comprises an aluminum alloy.
Claim 9
Dependent Claim 55 words
The semiconductor processing method of claim 1 wherein the layer of titanium metal is applied to a thickness of from about 100 Angstroms to about 1000 Angstroms, and the reacting of the titanium with the aluminum oxide occurs during the step of applying the layer of titanium metal atop the patterned and etched interlayer dielectric.
Claim 10
Dependent Claim 68 words
The semiconductor processing method of claim 1 wherein the layer of titanium metal is applied to a thickness of from about 100 Angstroms to about 1000 Angstroms, and further comprising: conducting a radio frequency induced plasma etch in a non-oxidizing atmosphere after patterning and etching the interlayer dielectric to etch some of the aluminum oxide away from the upper surface of the aluminum layer within the contact opening.
Claim 11
Dependent Claim 76 words
The semiconductor processing method of claim 1 wherein the reacting of the titanium with the aluminum oxide occurs during the step of applying the layer of titanium metal atop the patterned and etched interlayer dielectric, and further comprising: conducting a radio frequency induced plasma etch in a non-oxidizing atmosphere after patterning and etching the interlayer dielectric to etch some of the aluminum oxide away from the upper surface of the aluminum layer within the contact opening.
Claim 12
Dependent Claim 95 words
The semiconductor processing method of claim 1 wherein, the layer of titanium metal is applied to a thickness of from about 100 Angstroms to about 1000 Angstroms; the reacting of the titanium with the aluminum oxide occurs during the step of applying the layer of titanium metal atop the patterned and etched interlayer dielectric; and further comprising: conducting a radio frequency induced plasma etch in a nonoxidizing atmosphere after patterning and etchng the interlayer dielectric to etch some of the aluminum oxide away from the upper surface of the aluminum layer within the contact opening.
Claim 13
Dependent Claim 38 words
The semiconductor processing method of claim 1 wherein the layer of titanium metal is applied to a thickness of from about 100 Angstroms to about 1000 Angstroms, and the titanium metal being applied consists essentially of elemental titanium.
Claim 14
Dependent Claim 46 words
The semiconductor processing method of claim 1 wherein the titanium metal being applied consists essentially of elemental titanium, and the reacting of the titanium with the aluminum oxide occurs during the step of applying the layer of titanium metal atop the patterned and etched interlayer dielectric.
Claim 15
Dependent Claim 59 words
The semiconductor processing method of claim 1 wherein the titanium metal being applied consists essentially of elemental titanium, and further comprising: conducting a radio frequency induced plasma etch in a monoxidizing atmosphere after patterning and etching the interlayer dielectric to etch some of the aluminum oxide away from the upper surface of the aluminum layer within the contact opening.
Claim 16
Dependent Claim 78 words
The semiconductor processing method of claim 1 wherein, the layer of titanium metal is applied to a thickness of from about 100 Angstroms to about 1000 Angstroms; the titanium metal being applied consists essentially of elemental titanium, and further comprising: conducting a radio frequency induced plasma etch in a monoxidizing atmosphere after patterning and etching the interlayer dielectric to etch some of the aluminum oxide away from the upper surface of the aluminum layer within the contact opening.
Claim 17
Dependent Claim 223 words
A semiconductor processing method for decreasing electrical contact resistance between different elevation electrically conductive layers, the method comprising the following steps: applying a layer of aluminum alloy atop a partially processed semiconductor wafer, the aluminum alloy layer having an upper surface; exposing the semiconductor wafer with applied aluminum alloy layer to an oxidizing atmosphere and forming aluminum oxide at the upper surface of the aluminum alloy layer; applying an interlayer insulating dielectric material atop the aluminum alloy layer; selectively patterning and etching the interlayer dielectric to define a contact opening to the aluminum alloy layer; applying a layer of elemental titanium atop the patterned and etched interlayer dielectric to a thickness of from about 100 Angstroms to about 1000 Angstroms, the elemental titanium contacting the upper aluminum oxide surface of the aluminum alloy layer within the contact opening; reacting the titanium metal with the aluminum oxide in the contact to transform aluminum oxide into a less resistive titanium oxide, the reacting of the elemental titanium with the aluminum oxide occurring during the step of applying the layer of titanium metal atop the patterned and etched interlayer dielectric; and after application of the elemental titanium metal and reaction to form titanium oxide, applying a layer of conductive material atop the wafer over the titanium oxide and thereafter selectively patterning and etching the conductive layer.
Claim 18
Dependent Claim 223 words
A semiconductor processing method for decreasing electrical contact resistance between different elevation electrically conductive layers, the method comprising the following steps: applying a layer of aluminum alloy atop a partially processed semiconductor wafer, the aluminum alloy layer having an upper surface; exposing the semiconductor wafer with applied aluminum alloy layer to an oxidizing atmosphere and forming aluminum oxide at the upper surface of the aluminum alloy layer; applying an interlayer insulating dielectric material atop the aluminum alloy layer; selectively patterning and etching the interlayer dielectric to define a contact opening to the aluminum alloy layer; applying a layer of elemental titanium atop the patterned and etched interlayer dielectric to a thickness of from about 100 Angstroms to about 1000 Angstroms, the elemental titanium contacting the upper aluminum oxide surface of the aluminum alloy layer within the contact opening; reacting the titanium metal with the aluminum oxide in the contact to transform aluminum oxide into a less resistive titanium oxide, the reacting of the elemental titanium with the aluminum oxide occurring during the step of applying the layer of titanium metal atop the patterned and etched interlayer dielectric; and after application of the elemental titanium metal and reaction to form titanium oxide, applying a layer of conductive material atop the wafer over the titanium oxide and thereafter selectively patterning and etching the conductive layer.
Claim 19
Dependent Claim 18 words
The semiconductor processing method of claim 16 wherein the thickness of the elemental titanium is about 300 Angstroms.
Claim 20
Dependent Claim 13 words
The semiconductor processing method of claim 16 wherein the conductive material comprises aluminum.
Claim 21
Dependent Claim 18 words
The semiconductor processing method of claim 18 wherein the thickness of the elemental titanium is about 300 Angstroms.
Claim 22
Dependent Claim 15 words
The semiconductor processing method of claim 16 wherein the conductive material comprises an aluminum alloy.
Claim 23
Dependent Claim 18 words
The semiconductor processing method of claim 20 wherein the thickness of the elemental titanium is about 300 Angstroms.

References Cited (Backward Citations)

US4673623A Cited
US4937652A Cited
US5081064A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-04-05 1996-10-05 1997-04-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-04-05 2000-10-05 2001-04-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-04-05 2004-10-05 2005-04-06 $7700.00 Window Closed / Lapsed

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