Smectic liquid-crystal medium

Claim 2

A chiral, tilted smectic liquid-crystal medium comprising an achiral base material and at least one chiral doping agent, wherein said achiral base material of said medium contains at least one achiral compound having the structural unit 2,3-difluoro-1,4-phenylene, and said at least one achiral compound is a compound of formula I ##STR14## wherein R 1 and R 2 are each independently alkyl having 1 to 15 C atoms or alkenyl having 3-15 C atoms, wherein in each case a CH 2 group can be replaced by --O--, --CO--, --O--CO, --CO--O-- or --O--CO--O--; A 1 and A 2 , independently of one another, are each 1,4-phenylene wherein one or two CH groups can also be replaced by N, 1,4-cyclohexylene wherein one or two adjacent CH 2 groups can also each independently be replaced by O or S, piperidine-1,4-diyl, 1,4-bicyclo(2,2,2)-octylene, 1,3,4-thiadiazole-2,5-diyl, naphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl, each of which is unsubstituted or substituted by one or two F and/or Cl atoms and/or CH 3 groups and/or CN groups; Z 1 and Z 2 are each --CO--O--, --O--CO , --CH 2 CH 2 --, --OCH 2 --, --CH 2 O--, --C.tbd.C-- or a single bond; m and n are each 0, 1 or 2; and (m+n) is 1 or 2, subject to the proviso that one or two of the groups Z 1 and/or Z 2 present in the molecule of the formula I are --CO--O--, --O--C)--, --CH 2 CH 2 --, --OCH 2 --, --CH 2 O-- or --C.tbd.C--, if A 1 and A 2 independently of one another are each 1,4-phenylene which is unsubstituted or substituted by one or two F atoms.

Claim 3

A medium according to claim 1, wherein said medium contains 2 to 25% of said chiral doping agent.

Claim 4

A medium according to claim 2, wherein said doping agent has an S c * phase.

Claim 5

A medium according to claim 1, wherein said medium contains 8 to 50% of one or more of said compound having the structural unit 2,3-difluoro-1,4-phenylene.

Claim 6

A medium according to claim 1, wherein said medium contains one or more compounds of the formulae ##STR15## wherein R 3' and R 4' independently of one another are each alkyl having 1 to 15 C atoms, and o, p and q are each 0 are each 0 or 1.

Claim 7

In an electrooptical display element containing a dielectric, the improvement wherein said dielectric is a medium according to claim 1,

Claim 8

A medium according to claim 1, wherein said medium contains 8-50% of one or more of said compounds having a structural unit 2,3-difluoro-1,4-phenylene.

Claim 9

A medium according to claim 7, wherein said one or more compounds is of the formula ##STR16##

Claim 10

A chiral, tilted smectic liquid-crystal medium comprising an achiral base material and at least one chiral doping agent, wherein said achiral base material of said medium contains at least one achiral compound having the structural unit 2,3-difluoro-1,4-phenylene, and wherein said medium contains at least 25% of one or more compounds of formula II ##STR17## wherein R 3 and R 4 , independently of one another, ar each alkyl which has 1 to 15 C atoms or alkenyl which has 3 to 15 C atoms, each of which is unsubstituted, monosubstituted by cyano or substituted by fluorine or chlorine, wherein in each case a CH 2 group can be replaced by --O--, --CO--, --O--CO--, --CO--O , or --O--CO--O-- in each of these radicals, and Ring A is pyrimidine-2,5-diyl or pyridine-2,5-diyl; with the proviso that said at least one achiral compound is not a fluorinated oligophenyl of the formula 1 ##STR18## wherein a is 0 or 1; wherein the terminal substituents R 1 and R 2 are each independently alkyl or alkenyl having up to 15 C atoms, unsubstituted or substituted by CN or by at least one halogen atoms, and in which one or more non-adjacent CH 2 groups can be replaced by --O--, --S--, --CO--, --O--CO--, --CO--O--, --O--CO--O--, or --C.tbd.C--; one of R 1 and R 2 can also be ##STR19## wherein R 3 is alkyl or alkenyl having up to 15 C atoms, unsubstituted or substituted by CN or by at least one halogen atoms, and in which one or more nonadjacent CH 2 groups can be replaced by --O--, --S--, --CO--, --O--CO--, --CO--O--, --CO--O--, --O--CO--O-- or --C.tbd.C--; and in one of the following pairs of lateral substituents the two substituents are both fluorine; (A,B), (C,D), (C',D') and all remaining lateral substituents are hydrogen or fluorine.

Claim 11

A chiral, tilted smectic liquid-crystal medium comprising an achiral base material and at least one chiral doping agent, wherein said achiral base material of said medium contains at least one achiral compound having the structural unit 2,3-difluoro-1,4-phenylene, and wherein said medium contains at least 25% of one or more compounds of formula II ##STR17## wherein R 3 and R 4 , independently of one another, ar each alkyl which has 1 to 15 C atoms or alkenyl which has 3 to 15 C atoms, each of which is unsubstituted, monosubstituted by cyano or substituted by fluorine or chlorine, wherein in each case a CH 2 group can be replaced by --O--, --CO--, --O--CO--, --CO--O , or --O--CO--O-- in each of these radicals, and Ring A is pyrimidine-2,5-diyl or pyridine-2,5-diyl; with the proviso that said at least one achiral compound is not a fluorinated oligophenyl of the formula 1 ##STR18## wherein a is 0 or 1; wherein the terminal substituents R 1 and R 2 are each independently alkyl or alkenyl having up to 15 C atoms, unsubstituted or substituted by CN or by at least one halogen atoms, and in which one or more non-adjacent CH 2 groups can be replaced by --O--, --S--, --CO--, --O--CO--, --CO--O--, --O--CO--O--, or --C.tbd.C--; one of R 1 and R 2 can also be ##STR19## wherein R 3 is alkyl or alkenyl having up to 15 C atoms, unsubstituted or substituted by CN or by at least one halogen atoms, and in which one or more nonadjacent CH 2 groups can be replaced by --O--, --S--, --CO--, --O--CO--, --CO--O--, --CO--O--, --O--CO--O-- or --C.tbd.C--; and in one of the following pairs of lateral substituents the two substituents are both fluorine; (A,B), (C,D), (C',D') and all remaining lateral substituents are hydrogen or fluorine.

Claim 12

A medium according to claim 9, wherein said medium contains one or more compounds of formulas ##STR20## wherein R 4 and R 5 are, independently of one another, each alkyl, alkoxy, alkanoyloxy or alkoxycarbonyl having in each case 3 to 12 C atoms.

Claim 13

A medium according to claim 9, wherein said medium contains 2 to 25% of said chiral doping agent.

Claim 14

A medium according to claim 9, wherein said medium contains 8 to 50% of one or more of said compounds having the structural unit 2,3-difluoro-1,4-phenylene.

Claim 15

A medium according to claim 11, wherein said doping agent has an S C * phase.

Claim 16

In an electrooptical display element containing a dielectric, the improvement wherein said dielectric is a medium according to claim 9.