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US5173518A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of cellular polyurethane elastomers using polyether carbonate diols as a starting component

Assignee: BASF SE
•
Filing: 1992-01-06
•
Granted: 1992-12-22
•
Expires: 2012-01-06
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Abstract

Abstract A process for the preparation of cellular polyurethane elastomers involves reacting a) an organic and/or modified organic polyisocyanate with b) a polyether polycarbonate diol which contains bonded polyoxytetramethylene glycol radicals having a mean molecular weight Mn (number average) of from 150 to 500, and, if desired, c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of d) a blowing agent, e) a catalyst and f) if desired additives and/or assistants.

Inventors

  • 👤 Kaspar Bott
  • 👤 Horst King
  • 👤 Claudia Spang
  • 👤 Roland Minges
  • 👤 Wolfgang Straehle

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 16:22
CPC Classifications
C; C08; C08G; C08G64/00; C08G64/18; C08G64/183; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/28; C08G18/40; C08G18/42; C08G18/44; C08G18/70; C08G18/72; C08G18/74; C08G18/76; C08G18/7657; C08G18/7664; C08G18/7671; C08G18/7678; C08G2110/00; C08G2110/0041; C08G2110/0058; C08G2110/0066

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 186 words
A process for the preparation of a cellular polyurethane elastomer by reacting a) an organic and/or modified organic polyisocyanate with b) at least one relatively high-molecular-weight polyhydroxyl compound and, if desired, c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of d) a blowing agent, e) a catalyst and f) optionally additives and/or assistants, wherein the relatively high-molecular-weight polyhydroxyl compound (b) is a polyether polycarbonate diol prepared by polycondensing b1) a polyoxytetramethylene glycol having a mean molecular weight Mn (number average) of from 150 to 500 or b2) a mixture comprising b2i) at least 10 mol-% of the polyoxytetramethylene glycol (b1) and b2ii) less than 90 mol-% of at least one polyoxyalkylene diol, other than (b1), comprising an alkylene oxide having 2 to 4 carbon atoms in the alkylene radical, at least one linear or branched alkanediol having 2 to 14 carbon atoms or at least one cyclic alkanediol having 3 to 15 carbon atoms or a mixture of at least two of said diols (b2ii) with b3) phosgene, diphenyl carbonate or a dialkyl carbonate containing C 1 - to C 4 -alkyl groups.
Claim 2
Dependent Claim 186 words
A process for the preparation of a cellular polyurethane elastomer by reacting a) an organic and/or modified organic polyisocyanate with b) at least one relatively high-molecular-weight polyhydroxyl compound and, if desired, c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of d) a blowing agent, e) a catalyst and f) optionally additives and/or assistants, wherein the relatively high-molecular-weight polyhydroxyl compound (b) is a polyether polycarbonate diol prepared by polycondensing b1) a polyoxytetramethylene glycol having a mean molecular weight Mn (number average) of from 150 to 500 or b2) a mixture comprising b2i) at least 10 mol-% of the polyoxytetramethylene glycol (b1) and b2ii) less than 90 mol-% of at least one polyoxyalkylene diol, other than (b1), comprising an alkylene oxide having 2 to 4 carbon atoms in the alkylene radical, at least one linear or branched alkanediol having 2 to 14 carbon atoms or at least one cyclic alkanediol having 3 to 15 carbon atoms or a mixture of at least two of said diols (b2ii) with b3) phosgene, diphenyl carbonate or a dialkyl carbonate containing C 1 - to C 4 -alkyl groups.
Claim 3
Dependent Claim 24 words
A process as claimed in claim 1, wherein the cellular polyurethane elastomer has an overall density of from 0.1 to 0.95 g/cm 3 .
Claim 4
Dependent Claim 18 words
A process as claimed in claim 1, wherein the organic polyisocyanate (a) is 4,4'-diphenylmethane diisocyanate or 1,5-naphthylene diisocyanate.
Claim 5
Dependent Claim 22 words
A process as claimed in claim 1, wherein the polyether polycarbonate diol has a mean molecular weight of from 800 to 8000.
Claim 6
Dependent Claim 25 words
A process as claimed in claim 1, wherein the polyoxytetramethylene glycol (b1) has a mean molecular weight Mn (number average) of from 150 to 400.
Claim 7
Dependent Claim 13 words
A process as claimed in claim 1, wherein the blowing agent is water.
Claim 8
Dependent Claim 29 words
A process as claimed in claim 1, wherein the blowing agent is an alkane having 3 to 5 carbon atoms and/or a cycloalkane having 4 to 6 carbon atoms.
Claim 9
Dependent Claim 35 words
A process as claimed in claim 1, wherein, as an additive (f), crystalline, microporous molecular sieve having a cavity diameter of less than 1.3 nm and comprising a metal oxide or metal phosphate is used.
Claim 10
Dependent Claim 19 words
A process as claimed in claim 1, wherein the reaction is carried out in a closed mold with compaction.
Claim 11
Dependent Claim 19 words
A process for the production of cellular moldings, preferably shock absorbers, by a process as claimed in claim 1.

References Cited (Backward Citations)

US3764457A Cited
US4463141A Cited
US4423205A Cited
US4456745A Cited
US4510333A Cited
US4713399A Cited
US4751252A Cited
EP0335416A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-12-22 1996-06-22 1996-12-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-12-22 2000-06-22 2000-12-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-12-22 2004-06-22 2004-12-22 $7700.00 Window Closed / Lapsed

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