US5173518A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Preparation of cellular polyurethane elastomers using polyether carbonate diols as a starting component
Assignee: BASF SE
•
Filing: 1992-01-06
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Granted: 1992-12-22
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Expires: 2012-01-06
Abstract
Abstract A process for the preparation of cellular polyurethane elastomers involves reacting a) an organic and/or modified organic polyisocyanate with b) a polyether polycarbonate diol which contains bonded polyoxytetramethylene glycol radicals having a mean molecular weight Mn (number average) of from 150 to 500, and, if desired, c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of d) a blowing agent, e) a catalyst and f) if desired additives and/or assistants.
Inventors
- 👤 Kaspar Bott
- 👤 Horst King
- 👤 Claudia Spang
- 👤 Roland Minges
- 👤 Wolfgang Straehle
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 16:22
CPC Classifications
C; C08; C08G; C08G64/00; C08G64/18; C08G64/183; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/28; C08G18/40; C08G18/42; C08G18/44; C08G18/70; C08G18/72; C08G18/74; C08G18/76; C08G18/7657; C08G18/7664; C08G18/7671; C08G18/7678; C08G2110/00; C08G2110/0041; C08G2110/0058; C08G2110/0066
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
186 words
A process for the preparation of a cellular polyurethane elastomer by reacting a) an organic and/or modified organic polyisocyanate with b) at least one relatively high-molecular-weight polyhydroxyl compound and, if desired, c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of d) a blowing agent, e) a catalyst and f) optionally additives and/or assistants, wherein the relatively high-molecular-weight polyhydroxyl compound (b) is a polyether polycarbonate diol prepared by polycondensing b1) a polyoxytetramethylene glycol having a mean molecular weight Mn (number average) of from 150 to 500 or b2) a mixture comprising b2i) at least 10 mol-% of the polyoxytetramethylene glycol (b1) and b2ii) less than 90 mol-% of at least one polyoxyalkylene diol, other than (b1), comprising an alkylene oxide having 2 to 4 carbon atoms in the alkylene radical, at least one linear or branched alkanediol having 2 to 14 carbon atoms or at least one cyclic alkanediol having 3 to 15 carbon atoms or a mixture of at least two of said diols (b2ii) with b3) phosgene, diphenyl carbonate or a dialkyl carbonate containing C 1 - to C 4 -alkyl groups.
Claim 2
Dependent Claim
186 words
A process for the preparation of a cellular polyurethane elastomer by reacting a) an organic and/or modified organic polyisocyanate with b) at least one relatively high-molecular-weight polyhydroxyl compound and, if desired, c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of d) a blowing agent, e) a catalyst and f) optionally additives and/or assistants, wherein the relatively high-molecular-weight polyhydroxyl compound (b) is a polyether polycarbonate diol prepared by polycondensing b1) a polyoxytetramethylene glycol having a mean molecular weight Mn (number average) of from 150 to 500 or b2) a mixture comprising b2i) at least 10 mol-% of the polyoxytetramethylene glycol (b1) and b2ii) less than 90 mol-% of at least one polyoxyalkylene diol, other than (b1), comprising an alkylene oxide having 2 to 4 carbon atoms in the alkylene radical, at least one linear or branched alkanediol having 2 to 14 carbon atoms or at least one cyclic alkanediol having 3 to 15 carbon atoms or a mixture of at least two of said diols (b2ii) with b3) phosgene, diphenyl carbonate or a dialkyl carbonate containing C 1 - to C 4 -alkyl groups.
Claim 3
Dependent Claim
24 words
A process as claimed in claim 1, wherein the cellular polyurethane elastomer has an overall density of from 0.1 to 0.95 g/cm 3 .
Claim 4
Dependent Claim
18 words
A process as claimed in claim 1, wherein the organic polyisocyanate (a) is 4,4'-diphenylmethane diisocyanate or 1,5-naphthylene diisocyanate.
Claim 5
Dependent Claim
22 words
A process as claimed in claim 1, wherein the polyether polycarbonate diol has a mean molecular weight of from 800 to 8000.
Claim 6
Dependent Claim
25 words
A process as claimed in claim 1, wherein the polyoxytetramethylene glycol (b1) has a mean molecular weight Mn (number average) of from 150 to 400.
Claim 7
Dependent Claim
13 words
A process as claimed in claim 1, wherein the blowing agent is water.
Claim 8
Dependent Claim
29 words
A process as claimed in claim 1, wherein the blowing agent is an alkane having 3 to 5 carbon atoms and/or a cycloalkane having 4 to 6 carbon atoms.
Claim 9
Dependent Claim
35 words
A process as claimed in claim 1, wherein, as an additive (f), crystalline, microporous molecular sieve having a cavity diameter of less than 1.3 nm and comprising a metal oxide or metal phosphate is used.
Claim 10
Dependent Claim
19 words
A process as claimed in claim 1, wherein the reaction is carried out in a closed mold with compaction.
Claim 11
Dependent Claim
19 words
A process for the production of cellular moldings, preferably shock absorbers, by a process as claimed in claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-12-22 | 1996-06-22 | 1996-12-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-12-22 | 2000-06-22 | 2000-12-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-12-22 | 2004-06-22 | 2004-12-22 | $7700.00 | Window Closed / Lapsed |