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US5169708A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat shrinkable, elastic, glueable polyethylene and ethylene vinyl acetate film

Assignee: JPMorgan Chase Bank NA
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Filing: 1992-04-16
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Granted: 1992-12-08
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Expires: 2012-04-16
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Abstract

Abstract A process is provided for producing a novel two layered or three-layered film of polyethylene and ethylene vinyl acetate copolymer which is heat shrinkable, and after heat shrinking, is elastic and glueable. The process involves uniaxially stretching under controlled, relatively low temperature conditions.

Inventors

  • 👤 Everson Amaral
  • 👤 Ralf Korpman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 13:12
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24967; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31928

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 369 words
A multi-layered film structure having a pair of opposed outside layers and consisting of at least two interbonded layers and not more than three interbonded layers, one said layer thereof being comprised on a 100 weight percent layer basis of: about 50 to about 100 weight percent of a polyethylene polymer selected from the group consisting of low density polyethylene and linear low density polyethylene, 0 to about 50 weight percent of an ethylene/vinyl acetate copolymer having a molecular weight in the range of about 10,000 to about 75,000 and comprised on a 100 weight percent copolymer basis of about 72 to about 91 weight percent ethylene, and correspondingly about 9 to about 28 weight percent of vinyl acetate, and 0to about 10 weight percent of a filler-based antiblocking agent, and a second said layer thereof being comprised of said ethylene/vinyl acetate copolymer, and when said film structure contains a third said layer, said third layer is comprised of said polyethylene polymer, and said second layer is positioned between said first layer and said third layer, and wherein the ratio of the thickness of each one said first layer and of said third layer when present to said second layer is in the range of about 1:5 to about 1:20; said film structure being further characterized by having been uniaxially stretched to a stretch ratio in the range of about 3:1 to 6:1 while maintaining a temperature in the range of about 20° to about 50° C., a uniaxial heat shrinkability ratio in the range of about 1.5:1 to about 4:1 at a temperature in the range of about 40° to about 80° C., an elastic recovery, after said so stretched film structure has been so heat shrunk at a temperature in said range, of at least about 75 percent after being elongated at ambient temperature in the direction of said heat shrinking to about twice its heat shrunk length; and an adherability bond strength for each of said outer layers to a polyethylene film, after said so stretched film structure has been so heat shrunk at a temperature in said range, of at least about 5 ounces per inch, such bonding being achieved with a polystyrene-polyisoprene-polystyrene adhesive composition.
Claim 2
Dependent Claim 369 words
A multi-layered film structure having a pair of opposed outside layers and consisting of at least two interbonded layers and not more than three interbonded layers, one said layer thereof being comprised on a 100 weight percent layer basis of: about 50 to about 100 weight percent of a polyethylene polymer selected from the group consisting of low density polyethylene and linear low density polyethylene, 0 to about 50 weight percent of an ethylene/vinyl acetate copolymer having a molecular weight in the range of about 10,000 to about 75,000 and comprised on a 100 weight percent copolymer basis of about 72 to about 91 weight percent ethylene, and correspondingly about 9 to about 28 weight percent of vinyl acetate, and 0to about 10 weight percent of a filler-based antiblocking agent, and a second said layer thereof being comprised of said ethylene/vinyl acetate copolymer, and when said film structure contains a third said layer, said third layer is comprised of said polyethylene polymer, and said second layer is positioned between said first layer and said third layer, and wherein the ratio of the thickness of each one said first layer and of said third layer when present to said second layer is in the range of about 1:5 to about 1:20; said film structure being further characterized by having been uniaxially stretched to a stretch ratio in the range of about 3:1 to 6:1 while maintaining a temperature in the range of about 20° to about 50° C., a uniaxial heat shrinkability ratio in the range of about 1.5:1 to about 4:1 at a temperature in the range of about 40° to about 80° C., an elastic recovery, after said so stretched film structure has been so heat shrunk at a temperature in said range, of at least about 75 percent after being elongated at ambient temperature in the direction of said heat shrinking to about twice its heat shrunk length; and an adherability bond strength for each of said outer layers to a polyethylene film, after said so stretched film structure has been so heat shrunk at a temperature in said range, of at least about 5 ounces per inch, such bonding being achieved with a polystyrene-polyisoprene-polystyrene adhesive composition.
Claim 3
Dependent Claim 30 words
The film structure of claim 1 wherein, after said uniaxial stretching, said film structure is heat set at a temperature in the range of about 38° to about 55° C.
Claim 4
Dependent Claim 36 words
The film structure of claim 2 which is comprised of three said layers and which is in the form of a generally rectangular strip, and said strip is so uniaxially heat shrinkable in its longitudinal direction.
Claim 5
Dependent Claim 28 words
The film structure of claim 2 which is comprised of three said layers and which has a thickness in the range of about 1 to about 2.5 mils.

References Cited (Backward Citations)

US4399180A Cited
US4364981A Cited
US4399173A Cited
US4579696A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-12-08 1996-06-08 1996-12-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-12-08 2000-06-08 2000-12-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-12-08 2004-06-08 2004-12-08 $7700.00 Window Closed / Lapsed

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